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    • 1. 发明授权
    • Optical molding material, and optical disk substrate and production method thereof
    • 光学成型材料,光盘基板及其制造方法
    • US06447868B1
    • 2002-09-10
    • US09617810
    • 2000-07-17
    • Masayuki SekiguchiToshihiro OhtsukiTakatoshi IshigakiTatsuya Hirono
    • Masayuki SekiguchiToshihiro OhtsukiTakatoshi IshigakiTatsuya Hirono
    • B32B302
    • G11B7/2538G11B7/2534G11B7/2542G11B7/2548G11B7/2585G11B7/2595G11B2007/24304G11B2007/2571G11B2007/25713Y10T428/21
    • Provided is an optical molding material comprising a cyclic polyolefin resin having a glass transition temperature (Tg) of 120° C. to 170° C., wherein the melt viscosity of the resin at 260° C. is 5,000 to 50,000 poises as measured at a shear rate of 10 sec−1 and 200 to 1,000 poises at a shear rate of 10,000 sec−1, and the melt viscosity of the resin at 320° C. is 500 to 5,000 poises at a shear rate of 10 sec−1 and 100 to 800 poises at a shear rate of 10,000 sec−1. An optical molding material comprising a cyclic polyolefin resin, an optical molded product and an optical disk substrate, wherein a variation range of retardation of the resin is within ±10% of the retardation at 590 nm when the wavelength is changed from 400 nm to 830 nm, are provided. The material is molded into, for example, the optical disk substrate. A method for producing an optical disk substrate comprises injection-molding a thermoplastic resin comprising a cyclic polyolefin resin under conditions of a resin temperature of (Tg+100)° C. to 400° C., a mold temperature of (Tg−100)° C. to (Tg−5)° C., a shear rate of 4×104 to 1×106 sec−1 and average residence time of the resin in a molding machine of 5 to 200 seconds. The cyclic polyolefin resin is preferably composed of a norbornene derivative.
    • 提供了一种光学成型材料,其包含玻璃化转变温度(Tg)为120℃至170℃的环状聚烯烃树脂,其中在260℃下树脂的熔体粘度为5000至50,000泊, 在10,000秒-1的剪切速率下的剪切速率为10秒-1和200至1,000泊,而在320℃下的树脂的熔体粘度在10秒-1的剪切速率下为500至5000泊, 100至800泊,剪切速率为10,000秒-1。 一种包含环状聚烯烃树脂,光学模制产品和光盘基片的光学模塑材料,其中当波长从400nm变化到830时,树脂延迟的变化范围在590nm处的延迟的±10%以内 nm。 将该材料成型为例如光盘基板。 制造光盘基板的方法包括在(Tg + 100)℃至400℃的树脂温度,(Tg-100)℃的模具温度条件下,将包含环状聚烯烃树脂的热塑性树脂注塑成型, ℃至(Tg-5)℃,剪切速率为4×10 4至1​​×10 6秒-1,树脂在成型机中的平均停留时间为5至200秒。 环状聚烯烃树脂优选由降冰片烯衍生物构成。