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1. 发明授权

US5410045A Rubyrin and related expanded porphyrins 失效
标题翻译： Rubyrin和相关的扩展卟啉
公开(公告)号：US5410045A
公开(公告)日：1995-04-25
申请号：US15208
申请日：1993-02-09
申请人： Jonathan L. Sessler , Takashi Morishima , Steven J. Weghorn
发明人： Jonathan L. Sessler , Takashi Morishima , Steven J. Weghorn
IPC分类号： C07D487/22 , C07D519/00 , C07H15/26 , C07H19/16
CPC分类号： C07H19/16 , C07D487/22 , C07D519/00 , C07H15/26
摘要： The present invention is directed to the synthesis and use of novel macrocyclic compounds, based upon a new class of expanded porphyrins, termed rubyrins. Disclosed herein is the structure and synthesis of a prototypical rubyrin and various substituted rubyrin analogues, conjugates and compositions. Rubyrin itself is characterized by the presence of six pyrrolic subunits contained within a fully aromatic 26 .pi.-electron macrocyclic framework and by UV/VIS absorption bands that are very red-shifted as compared to those of other porphyrins or pentapyrrolic expanded porphyrins. The rubyrin-type class of compounds is further characterized by an ability to undergo facile protonation at the pyrrolic nitrogens and, once protonated, by an ability to form complexes with anions such as nucleotide-containing compounds. Rubyrin-based compounds are useful as, for example, anion chelators and receptors and as transporters for various anionic compounds including antiviral agents. In addition to the 26 .pi.-electron target system, the present invention concerns other oxidation states bearing the same connectivity and the same total number of non-hydrogen atoms, and various analogues in which different substituents are present at the various meso and/or .beta.-pyrrolic positions or in which furan and/or thiophene moieties replace one or more of the six pyrrolic subunits.
摘要翻译：本发明涉及新型大环化合物的合成和应用，其基于新类型的称为红宝石的扩展卟啉。本文公开了原型红宝石和各种取代的rubyrin类似物，缀合物和组合物的结构和合成。 Rubyrin本身的特征在于含有完全芳香族26电子大环框架中的六个吡咯亚基和与其它卟啉或五吡咯基扩展的卟啉相比非常红移的UV / VIS吸收带。红霉素类化合物的进一步特征在于能够在吡咯氮下进行容易的质子化，并且一旦被质子化，就可以通过与阴离子如含核苷酸的化合物形成络合物的能力。基于Rubyrin的化合物可用作例如阴离子螯合剂和受体以及作为包括抗病毒剂的各种阴离子化合物的转运蛋白。除了26p1电子靶系统之外，本发明涉及具有相同连接性和相同总数的非氢原子的其它氧化态，以及各种不同取代基存在于各种中和和/或β的各种类似物呋喃和/或噻吩部分取代六个吡咯亚基中的一个或多个。

2. 发明授权

US5246911A Thermal transfer recording sheet and ink composition for producing the same 失效
标题翻译：热转印记录纸及其制造用油墨组合物
公开(公告)号：US5246911A
公开(公告)日：1993-09-21
申请号：US981089
申请日：1992-11-24
申请人： Yukichi Murata , Mio Nakamura , Takashi Morishima
发明人： Yukichi Murata , Mio Nakamura , Takashi Morishima
IPC分类号： B41M5/035 , B41M5/388
CPC分类号： B41M5/388 , Y10S428/913 , Y10S428/914 , Y10T428/31786
摘要： A thermal transfer recording sheet comprising a substrate having thereon a colorant layer, the colorant layer comprising a binder and a pyridone-type azo dyestuff represented by the following general formula (I): ##STR1## wherein R represents a hydrogen atom, an alkyl group having 2 or more carbon atoms, a substituted alkyl group, a cycloalkyl group, an allyl group, or a substituted or unsubstituted phenyl group is disclosed. A thermal transfer recording ink composition for use in forming the colorant layer on a substrate is also disclosed.
摘要翻译：一种热转印记录纸，其包含其上具有着色剂层的基材，所述着色剂层包含粘合剂和由以下通式（I）表示的吡啶酮型偶氮染料：其中R表示氢原子，公开了具有2个以上碳原子的烷基，取代的烷基，环烷基，烯丙基或取代或未取代的苯基。还公开了一种用于在基材上形成着色剂层的热转印记录油墨组合物。

3. 发明授权

US5916842A Thermal dye transfer sheet and method for thermal dye recording 失效
标题翻译：热染料转印片和热染料记录方法
公开(公告)号：US5916842A
公开(公告)日：1999-06-29
申请号：US839804
申请日：1997-04-18
申请人： Tatsuya Morimitsu , Kenjiro Kuroda , Osamu Ito , Takashi Morishima
发明人： Tatsuya Morimitsu , Kenjiro Kuroda , Osamu Ito , Takashi Morishima
IPC分类号： B41M5/035 , B41M5/385 , B41M5/388 , B41M5/39 , B41M5/38
CPC分类号： B41M5/3854 , B41M2205/02 , B41M5/385 , B41M5/3858 , B41M5/388 , B41M5/39 , Y10S428/913 , Y10S428/914
摘要： A thermal dye transfer sheet having a dye layer provided on at least one side of a substrate, which is used for thermal dye transfer recording system carrying out recording by transferring a dye or dyes in the dye layer to a dye-receiving material by heating means, wherein the dye layer contains a pyrazolonemethine type dye of the following formula: ##STR1## wherein R.sup.1 and R.sup.2 can be respectively independently selected and are a lower alkyl group which may be substituted, a lower alkenyl group which may be substituted or an aryl group which may be substituted; andR.sup.3 and R.sup.4 can be respectively independently selected and are a lower alkyl group which may be substituted, a dialkylamino group, a --COOR.sup.5 group or a --CONR.sup.6 R.sup.7 group, in which R.sup.5 is a lower alkyl group which may be substituted, a lower alkenyl group which may be substituted or an aryl group which may be substituted and R.sup.6 and R.sup.7 can be respectively independently selected and are a hydrogen atom, a lower alkyl group which may be substituted, a lower alkenyl group which may be substituted or an aryl group which may be substituted.
摘要翻译：一种具有设置在基材的至少一侧的染料层的热染料转印片，其用于通过将染料层中的染料或染料转移到染料接收材料的加热装置进行记录的热染料转印记录系统其中染料层含有下式的吡唑啉酮类染料：其中R1和R2可以分别独立选择，可以被取代的低级烷基，可被取代的低级烯基或可以被取代的芳基取代 R 3和R 4可分别独立选择，可以被取代的低级烷基，二烷基氨基，-COOR 5基或-CONR 6 R 7基，其中R 5为可被取代的低级烷基，低级烯基可以被取代的基团或可以被取代的芳基，R 6和R 7可以分别独立地选择并且是氢原子，可被取代的低级烷基，可被取代的低级烯基或芳基，可以被替代。

4. 发明授权

US5622945A Rubyrin macrocycles 失效
标题翻译： Rubyrin大环
公开(公告)号：US5622945A
公开(公告)日：1997-04-22
申请号：US368336
申请日：1995-01-04
申请人： Jonathan L. Sessler , Takashi Morishima , Steven J. Weghorn
发明人： Jonathan L. Sessler , Takashi Morishima , Steven J. Weghorn
IPC分类号： C07D487/22 , C07D519/00 , C07H15/26 , C07H19/16 , A61K31/395
CPC分类号： C07H19/16 , C07D487/22 , C07D519/00 , C07H15/26
摘要： The present invention is directed to the synthesis and use of novel macrocyclic compounds, based upon a new class of expanded porphyrins, termed rubyrins. Disclosed herein is the structure and synthesis of a prototypical rubyrin and various substituted rubyrin analogues, conjugates and compositions. Rubyrin itself is characterized by the presence of six pyrrolic subunits contained within a fully aromatic 26 .pi.-electron macrocyclic framework and by UV/VIS absorption bands that are very red-shifted as compared to those of other porphyrins or pentapyrrolic expanded porphyrins. The rubyrin-type class of compounds is further characterized by an ability to undergo facile protonation at the pyrrolic nitrogens and, once protonated, by an ability to form complexes with anions such as nucleotide-containing compounds. Rubyrin-based compounds are useful as, for example, anion chelators and receptors and as transporters for various anionic compounds including antiviral agents. In addition to the 26 .pi.-electron target system, the present invention concerns other oxidation states bearing the same connectivity and the same total number of non-hydrogen atoms, and various analogues in which different substituents are present at the various meso and/or .beta.-pyrrolic positions or in which furan and/or thiophene moieties replace one or more of the six pyrrolic subunits.
摘要翻译：本发明涉及新型大环化合物的合成和应用，其基于新类型的称为红宝石的扩展卟啉。本文公开了原型红宝石和各种取代的rubyrin类似物，缀合物和组合物的结构和合成。 Rubyrin本身的特征在于含有完全芳香族26电子大环框架中的六个吡咯亚基和与其它卟啉或五吡咯基扩展的卟啉相比非常红移的UV / VIS吸收带。红霉素类化合物的进一步特征在于能够在吡咯氮下进行容易的质子化，并且一旦被质子化，就可以通过与阴离子如含核苷酸的化合物形成络合物的能力。基于Rubyrin的化合物可用作例如阴离子螯合剂和受体以及作为包括抗病毒剂的各种阴离子化合物的转运蛋白。除了26p1电子靶系统之外，本发明涉及具有相同连接性和相同总数的非氢原子的其它氧化态，以及各种不同取代基存在于各种中和和/或β的各种类似物呋喃和/或噻吩部分取代六个吡咯亚基中的一个或多个。

5. 发明授权

US5529973A Thermal transfer recording sheet 失效
标题翻译：热转印记录纸
公开(公告)号：US5529973A
公开(公告)日：1996-06-25
申请号：US240104
申请日：1994-05-09
申请人： Hideo Shinohara , Tsutomu Taki , Katsuhiko Kuroda , Takashi Morishima
发明人： Hideo Shinohara , Tsutomu Taki , Katsuhiko Kuroda , Takashi Morishima
IPC分类号： B41M5/40 , B41M5/42 , B41M5/44 , B41M5/035 , B41M5/38
CPC分类号： B41M5/443 , B41M5/426 , B41M5/44 , Y10S428/913 , Y10S428/914 , Y10T428/25 , Y10T428/254 , Y10T428/256 , Y10T428/259 , Y10T428/31507 , Y10T428/31663 , Y10T428/31786 , Y10T428/31855 , Y10T428/31935
摘要： The disclosure describes a thermal transfer recording sheet comprising a base film, a colorant layer provided on one side of said base film and containing a heat-transferable dye, and a heat-resistant lubricating layer provided on the other side of said base film and containing a thermoplastic resin having a glass transition point of not less than 50.degree. C., an amino-modified silicone oil and a carboxy-modified silicone oil.
摘要翻译：本发明公开了一种热转印记录纸，其包括基膜，在所述基膜的一侧上设置有含有可转印染料的着色层，以及设置在所述基膜的另一侧上的耐热润滑层，玻璃化转变点不低于50℃的热塑性树脂，氨基改性的硅油和羧基改性的硅油。

6. 外观设计

USD370639S Wrist watch 失效
公开(公告)号：USD370639S
公开(公告)日：1996-06-11
申请号：US38258
申请日：1995-05-02
申请人： Takashi Morishima , Hirohito Tagawa
设计人： Takashi Morishima , Hirohito Tagawa

7. 外观设计

USD364817S Wrist watch 失效
公开(公告)号：USD364817S
公开(公告)日：1995-12-05
申请号：US34261
申请日：1995-01-30
申请人： Takashi Morishima
设计人： Takashi Morishima

8. 外观设计

USD363234S Wrist watch 失效
公开(公告)号：USD363234S
公开(公告)日：1995-10-17
申请号：US31450
申请日：1994-11-28
申请人： Takashi Morishima , Hirohito Tagawa
设计人： Takashi Morishima , Hirohito Tagawa

9. 外观设计

USD339530S Wrist watch 失效
公开(公告)号：USD339530S
公开(公告)日：1993-09-21
申请号：US812230
申请日：1991-12-23
申请人： Takashi Morishima
设计人： Takashi Morishima

10. 外观设计

USD339301S Wrist watch 失效
公开(公告)号：USD339301S
公开(公告)日：1993-09-14
申请号：US812366
申请日：1991-12-23
申请人： Takashi Morishima
设计人： Takashi Morishima

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