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    • 1. 发明授权
    • Nonohmic ZnO ceramics including Bi.sub.2 O.sub.3, CoO, MnO, Sb.sub.2 O.sub.
3
    • 包括Bi(hd 2 {b O {HD 3 {B,CoO,MnO,Sb(hd 2 {b O {HD 3 {B,和硼硅酸盐Pb和/或Zn玻璃组分
    • US4147670A
    • 1979-04-03
    • US746425
    • 1976-12-01
    • Nobuaki ShohataTomeji OhnoShigeru IkedaTakaki FukushimaRyuji IgarashiJyun-Ichiro Yoshida
    • Nobuaki ShohataTomeji OhnoShigeru IkedaTakaki FukushimaRyuji IgarashiJyun-Ichiro Yoshida
    • C04B35/453H01C7/112H01B1/08
    • H01C7/112C04B35/453
    • Nonohmic ZnO ceramics including the following additives have the voltage nonlinear exponent .alpha. of 30 or more, the dielectric constant .epsilon. of about 1000 or less, the loss factor (tan .delta.) of less than 10%, and small variations caused in the breakdown voltage V.sub.i by load and large current pulses. The additives listed by molecular formulae are given in % by mol. The glass components are given for Nos. 1 through 4 in % by weight, symbols of elements being representative of borosilicate lead and/or zinc glass.______________________________________ No. Bi.sub.2 O.sub.3 CoO MnO Sb.sub.2 O.sub.3 Glass Component ______________________________________ 1. 0.1-10 0.05-10 0.25-4 0.05-6 0.1-10 (Pb-Zn) 2. 0.1-6 0.05-10 0.25-10 0.1-10 0.1-10 (Zn) 3. 0.1-6 0.05-10 0.23-4 0.05-6 0.1-3 (Pb) 4. 0.1-6 0.05-10 0.2-10 0.1-6 0.1-10 (Zn and others) ______________________________________ As a fifth embodiment, the oxides corresponding or equivalent to a lead-borosilicate glass (PbO, B.sub.2 O.sub.3 and SiO.sub.2) may be included in certain amounts with varying amounts of zinc oxide as a major component along with Bi.sub.2 O.sub.3, CoO, MnO and Sb.sub.2 O.sub.3.
    • 包括以下添加剂的非欧姆ZnO陶瓷的电压非线性指数α为30以上,介电常数ε为约1000以下,损耗因子(tanδ)小于10%,以及击穿电压Vi 通过负载和大电流脉冲。 分子式列出的添加剂以摩尔%计。 玻璃组分以重量%计为1至4,元素符号代表硼硅酸铅和/或锌玻璃。 }没有。 Bi2O3 CoO MnO Sb2O3玻璃成分} 1。 0.1-10 0.05-10 0.25-4 0.05-6 0.1-10(Pb-Zn)} 2。 0.1-6 0.05-10 0.25-10 0.1-10 0.1-10(Zn)} 3。 0.1-6 0.05-10 0.23-4 0.05-6 0.1-3(Pb)} 4。 0.1-6 0.05-10 0.2-10 0.1-6 0.1-10(Zn等)}作为第五个实施方案,可以以一定量包含与硼硅酸铅玻璃(PbO,B2O3和SiO2)相当或相当的氧化物 随着Bi2O3,CoO,MnO和Sb2O3的含量不同,氧化锌为主要成分。