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    • 5. 发明授权
    • Olefin polymerization catalyst system
    • 烯烃聚合催化剂体系
    • US6063725A
    • 2000-05-16
    • US743374
    • 1996-11-04
    • Tadahiro SunagaYukio IshiiTadashi Asanuma
    • Tadahiro SunagaYukio IshiiTadashi Asanuma
    • C08F4/02C08F4/602C08F4/642C08F4/659C08F4/6592C08F10/00C08F110/06B01J31/00
    • C08F10/00C08F110/06C08F4/65912C08F4/65916C08F4/65922
    • An olefin polymerization catalyst system comprising an organic transition metal compound and a support, wherein an organic transition metal compound is soluble in an inert organic solvent and a support which is insoluble in the inert organic solvent, and the support comprises an organic high molecular weight compound which contains a specific carbonyl-containing group. The catalyst system can polymerize an olefin in a high activity, provides polymer with high stereoregularity, prevents adhesion or fouling of the polymer generated in the course of polymerization or an organic aluminum oxy compound on the inner wall of the reactor, leads to high bulk density of the polymer and very reduced level of fisheye and/or gel generation on the processed item, can maintain high productivity, can manufacture high quality product, and thus provides extremely high contribution in industry.
    • 一种包含有机过渡金属化合物和载体的烯烃聚合催化剂体系,其中有机过渡金属化合物可溶于惰性有机溶剂和不溶于惰性有机溶剂的载体,载体包含有机高分子量化合物 其含有特定的含羰基。 催化剂体系可以以高活性聚合烯烃,提供具有高立构规整性的聚合物,防止在聚合过程中产生的聚合物的粘附或结垢或反应器内壁上的有机铝氧化合物导致高堆积密度 的聚合物,并且处理物品上的鱼眼和/或凝胶生成水平非常降低,可以保持高生产率,可以制造高品质的产品,从而在工业中提供极高的贡献。
    • 9. 发明授权
    • Polymerization catalysts for unsaturated monomers, novel transition metal compounds, polymerization processes using same, and copolymers
    • 不饱和单体的聚合催化剂,新型过渡金属化合物,使用它们的聚合方法和共聚物
    • US06703459B1
    • 2004-03-09
    • US09701631
    • 2000-12-01
    • Tadahiro SunagaHiroshi Kouno
    • Tadahiro SunagaHiroshi Kouno
    • C08F444
    • C08F4/52
    • This invention relates to polymerization catalysts for unsaturated monomers which are represented by the following general formula [1]: MR1kR2mR3nQh  [1] wherein R1 is selected from ligands having at least one nitrogen, sulfur, phosphorus or oxygen atom; R2 is selected from ligands comprising cyclic hydrocarbons having &pgr;-electrons, and R1 and R2 may be crosslinked with each other; R3 is selected from ligands comprising a hydrogen atom, alkyl groups, aryl groups, silicon-containing alkyl groups and silicon-containing aryl groups; M is a metal selected from the metals of group III of the periodic table; Q is selected from halogen atoms and electron-donating ligands, where Q may be the same or different if h is more than one; k is an integer of 1 to 4; and m, n and h are each 0 or an integer of 1 to 4.
    • 本发明涉及由以下通式[1]表示的不饱和单体聚合催化剂:其中R 1选自具有至少一个氮,硫,磷或氧原子的配体; R 2选自包含具有π电子的环状烃的配体,并且R 1和R 2可以彼此交联; R 3选自包含氢原子,烷基,芳基,含硅烷基和含硅芳基的配体; M是选自周期表第III族金属的金属; Q选自卤素原子和给电子配体,其中如果h大于1,Q可以相同或不同; k为1〜4的整数, m,n和h各自为0或1〜4的整数。