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    • 1. 发明授权
    • Co-oligomers and copolymers having dispersant activity
    • 具有分散剂活性的共低聚物和共聚物
    • US5712359A
    • 1998-01-27
    • US813292
    • 1997-03-10
    • Clemens AuschraHorst PennewissSusanne Graner
    • Clemens AuschraHorst PennewissSusanne Graner
    • C08F210/02B01F17/52C08F210/00C08F220/10C08F220/16C08F220/18C08F290/06
    • C08F220/18C08F290/062
    • Co-oligomers and copolymers having dispersant activity and usable as emulsifiers are based on esters of (meth)acrylic acid; where the co-oligomers and copolymers are comprised of the following components: (A) 60-95 wt. % of at least one (meth)acrylic acid ester of formula I ##STR1## where R represents hydrogen or methyl, and R.sub.1 represents a (possibly branched) alkyl group or a cycloalkyl group with 4-32 carbon atoms in the alkyl group; and (B) 5-40 wt. % of a (meth)acrylic acid ester of formula II ##STR2## where R' represents hydrogen or methyl, R.sub.2 represents an alkyl or aryl group with 1-50 carbon atoms, where R.sub.2 itself may be substituted with nitrogen or sulfur, n may be a number from 5 to 100, and m may be a number from 0 to 100; and, in the amount of 0-90 mol % of the monomer(s) of formula II, a hydroxyalkyl ester of (meth)acrylic acid, of formula III: ##STR3## where R" represents hydrogen or methyl, and R.sub.3 represents an alkyl group substituted with at least one hydroxyl group and having 2-30 carbon atoms; with the proviso that (A) and (B) together make 100 wt. %; and (C) an additional 0-75 wt. %, based on the weight of (A)+(B), of at least one 1-alkene having 4-42 carbon atoms.
    • 具有分散剂活性并可用作乳化剂的共低聚物和共聚物基于(甲基)丙烯酸的酯; 其中共低聚物和共聚物由以下组分组成:(A)60-95重量% %的至少一种式I的(甲基)丙烯酸酯其中R表示氢或甲基,R1表示(可能是支链的)烷基或在烷基中具有4-32个碳原子的环烷基 组; 和(B)5-40重量% %的式II(甲基)丙烯酸酯其中R'表示氢或甲基,R 2表示具有1-50个碳原子的烷基或芳基,其中R2本身可被氮或硫取代 n可以是5〜100的数,m可以是0〜100的数; (III)的(甲基)丙烯酸的羟烷基酯,其中R“表示氢或甲基,并且以0-90摩尔%的式II的单体的量, R3表示被至少一个羟基取代并具有2-30个碳原子的烷基; 条件是(A)和(B)共同制得100重量% %; 和(C)另外的0-75wt。 基于(A)+(B)的重量,至少一种具有4-42个碳原子的1-烯烃。