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    • 1. 发明授权
    • Method and apparatus for conducting electrochemiluminescent measurements
    • 用于进行电化学发光测量的方法和装置
    • US5247243A
    • 1993-09-21
    • US744890
    • 1991-08-14
    • Lee O. HallGlenn ZoskiSurendera K. Tyagi
    • Lee O. HallGlenn ZoskiSurendera K. Tyagi
    • G01N21/66G01N27/48H03K4/02
    • H03K4/026G01N21/66G01N27/48
    • A method and apparatus for triggering and measuring electrochemiluminescent phenomena using a voltage waveform applied at the voltammetric working electrode which improves the precision and accuracy of measurements. This waveform has a decreasing scan rate in the range of voltages for which electrochemiluminescence is triggered and is substantially sinusoidal in shape in this range. The waveform results from locating the reference electrode of a potentiostat in close potential proximity to its counter electrode, and applying a uniform scanning voltage waveform at the reference electrode. The waveform also can be synthesized digitally, converted to analog form, and applied directly to the working electrode with the reference electrode in close potential proximity to the working electrode.
    • 一种使用在伏安作业电极上施加的电压波形来触发和测量电化学发光现象的方法和装置,其提高测量的精度和精度。 该波形在触发电化学发光的电压范围内具有降低的扫描速率,并且在该范围内基本上呈正弦形。 该波形是通过将恒电位仪的参考电极定位在靠近其对电极的近电位,并在参考电极上施加均匀的扫描电压波形。 波形也可以数字地合成,转换为模拟形式,并直接施加到工作电极,参考电极与工作电极接近。