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    • 2. 发明授权
    • Process for purifying ionic liquids
    • 离子液体净化方法
    • US08927737B2
    • 2015-01-06
    • US13570539
    • 2012-08-09
    • Michael SiemerMichael KleinSunghee SonKlemens MassonneUwe Vagt
    • Michael SiemerMichael KleinSunghee SonKlemens MassonneUwe Vagt
    • C07D233/58
    • C07D233/58
    • The present process purifies a salt Cat+X−, where Cat+ is any cation and X− is an organic anion having at least 6 carbon atoms. The salt is an impurity in a composition comprising a water-soluble salt (Cat+)nYn−, where Yn− is an inorganic anion or an organic anion, different from X−, with at most 10 carbon atoms. The process involves converting X− into an acid HX by adding an acid (H+)mZm−, forming two phases: an organic phase comprising HX and an aqueous phase comprising the water-soluble salts (Cat+)mZm− and (Cat+)nYn− or acids (H+)nYn−. The organic phase is separated and the aqueous phase passes over a basic anion exchanger which binds Zm− and Yn− and liberates OH−, giving an aqueous mixture comprising Cat+OH−. The organic phase and the aqueous mixture are converted into Cat+X− and H2O, optionally with addition of further HX.
    • 本发明方法纯化了Cat + X-盐,其中Cat +是任何阳离子,X-是具有至少6个碳原子的有机阴离子。 该盐是包含水溶性盐(Cat +)nYn-的组合物中的杂质,其中Yn-是不同于X的至多10个碳原子的无机阴离子或有机阴离子。 该方法包括通过加入形成两相的酸(H +)mZm-来将X转化成酸HX:包含HX的有机相和包含水溶性盐(Cat +)mZm-和(Cat +)nYn- 或酸(H +)nYn-。 分离有机相,水相通过结合Zm-和Yn-并释放OH-的碱性阴离子交换剂,得到包含Cat + OH-的含水混合物。 将有机相和含水混合物转化为Cat + X-和H 2 O,任选地加入另外的HX。
    • 3. 发明申请
    • PROCESS FOR PURIFYING IONIC LIQUIDS
    • 净化离子液体的方法
    • US20130041159A1
    • 2013-02-14
    • US13570539
    • 2012-08-09
    • Michael SiemerMichael KleinSunghee SonKlemens MassonneUwe Vagt
    • Michael SiemerMichael KleinSunghee SonKlemens MassonneUwe Vagt
    • C07D233/58
    • C07D233/58
    • The present process purifies a salt Cat+X−, where Cat+ is any cation and X− is an organic anion having at least 6 carbon atoms. The salt is an impurity in a composition comprising a water-soluble salt (Cat+)nYn−, where Yn− is an inorganic anion or an organic anion, different from X−, with at most 10 carbon atoms. The process involves converting X− into an acid HX by adding an acid (H+)mZm−, forming two phases: an organic phase comprising HX and an aqueous phase comprising the water-soluble salts (Cat+)mZm− and (Cat+)nYn− or acids (H+)nYn−. The organic phase is separated and the aqueous phase passes over a basic anion exchanger which binds Zm− and Yn− and liberates OH−, giving an aqueous mixture comprising Cat+OH−. The organic phase and the aqueous mixture are converted into Cat+X− and H2O, optionally with addition of further HX.
    • 本发明方法纯化了Cat + X-盐,其中Cat +是任何阳离子,X-是具有至少6个碳原子的有机阴离子。 该盐是包含水溶性盐(Cat +)nYn-的组合物中的杂质,其中Yn-是不同于X的至多10个碳原子的无机阴离子或有机阴离子。 该方法包括通过加入形成两相的酸(H +)mZm-来将X转化成酸HX:包含HX的有机相和包含水溶性盐(Cat +)mZm-和(Cat +)nYn- 或酸(H +)nYn-。 分离有机相,水相通过结合Zm-和Yn-并释放OH-的碱性阴离子交换剂,得到包含Cat + OH-的含水混合物。 将有机相和含水混合物转化为Cat + X-和H 2 O,任选地加入另外的HX。