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1. 发明授权

US06998499B2 Process for the preparation of secondary and tertiary amino-functional silanes, iminoorganosilanes and/or imidoorganosilanes 有权
公开(公告)号：US06998499B2
公开(公告)日：2006-02-14
申请号：US10458036
申请日：2003-06-10
申请人： Steven C. Gedon , Andrea Trotto
发明人： Steven C. Gedon , Andrea Trotto
IPC分类号： C07F7/02
CPC分类号： C07F7/1892 , C07F7/1804
摘要： Iminoorganosilanes may be prepared by reacting aminoorganosilanes with organoimines by an amine exchange reaction. The resultant iminoorganosilanes can then be catalytically reduced to produce secondary and tertiary amino silanes. Imidoorganosilanes can be prepared by a similar amine reaction between aminoorganosilanes and organoimides. The imidoorganosilanes can also be reacted to produce tertiary amines. Water-sensitive silane reactants may be employed to yield water-sensitive imino, imido, or amino silane products.

2. 发明授权

US5580911A Aliphatic-aromatic copolyesters and cellulose ester/polymer blends 失效
公开(公告)号：US5580911A
公开(公告)日：1996-12-03
申请号：US428979
申请日：1995-04-26
申请人： Charles M. Buchanan , Robert M. Gardner , Matthew D. Wood , Alan W. White , Steven C. Gedon , Fred D. Barlow, Jr.
发明人： Charles M. Buchanan , Robert M. Gardner , Matthew D. Wood , Alan W. White , Steven C. Gedon , Fred D. Barlow, Jr.
IPC分类号： C08G63/02 , A61L15/22 , B29C55/02 , B29K67/00 , B29L7/00 , C08G63/00 , C08G63/16 , C08G63/181 , C08J5/18 , C08K5/10 , C08L1/00 , C08L1/02 , C08L1/08 , C08L1/10 , C08L1/12 , C08L1/14 , C08L3/02 , C08L29/04 , C08L31/04 , C08L33/00 , C08L33/04 , C08L33/12 , C08L67/00 , C08L67/02 , C08L67/04 , C08L69/00 , C08L91/08 , C08L101/00 , C08L101/16 , D01F2/28 , D01F6/84 , D01F6/92 , C08G63/183
CPC分类号： C08L67/00 , A61L15/225 , C08G63/16 , C08L1/10 , C08L1/14 , C08L67/02 , C08L67/04 , C08L2201/06 , Y10S428/91 , Y10T428/31786
摘要： This invention relates to binary blends of cellulose esters and aliphatic-aromatic copolyesters, cellulose esters and aliphatic polyesters as well as ternary blends of cellulose esters and/or aliphatic polyesters and/or aliphatic-aromatic copolyesters and/or polymeric compounds as well as fibers, molded objects, and films prepared therefrom.

3. 发明授权

US06673954B1 Process for the preparation of N-silylorganocarbamates 有权
标题翻译： N-甲硅烷基有机碳酸酯的制备方法
公开(公告)号：US06673954B1
公开(公告)日：2004-01-06
申请号：US10368830
申请日：2003-02-19
申请人： Steven C. Gedon , Melinda B. Jackson , R. Shawn Childress
发明人： Steven C. Gedon , Melinda B. Jackson , R. Shawn Childress
IPC分类号： C07F710
CPC分类号： C07F7/1892
摘要： A process is provided for preparing an N-silylorganocarbamate, which comprises: providing a mixture of aminoorganosilane and a catalytically effective amount of basic catalyst and; combining the mixture of aminoorganosilane and basic catalyst with an organocarbonate ester the mixture of aminoorganosilane and basic catalyst, the organocarbonate ester or both being at elevated temperature at the time of their being combined.
摘要翻译：提供了制备N-甲硅烷基有机氨基甲酸酯的方法，其包括：提供氨基有机硅烷和催化有效量的碱性催化剂的混合物; 将氨基有机硅烷和碱性催化剂的混合物与有机碳酸酯组合，氨基有机硅烷和碱性催化剂的混合物，有机碳酸酯或两者在组合时处于升高的温度。

4. 发明授权

US06448425B1 Preparation of N-substituted aminoorganosilanes 有权
标题翻译： N-取代氨基有机硅烷的制备
公开(公告)号：US06448425B1
公开(公告)日：2002-09-10
申请号：US10076378
申请日：2002-02-19
申请人： Steven C. Gedon , Melinda Hale
发明人： Steven C. Gedon , Melinda Hale
IPC分类号： C09F710
CPC分类号： C07F7/1892
摘要： A process is disclosed for the synthesis of N-cycloalkylaminoalkylsilanes, wherein the process comprises hydrogenating the corresponding N-arylaminoalkylsilanes in the presence of a catalytically effective amount of a supported or unsupported catalyst selected from the group consisting of palladium, platinum, nickel, rhenium, rhodium, ruthenium, copper chromite, and mixtures of the foregoing.
摘要翻译：公开了用于合成N-环烷基氨基烷基硅烷的方法，其中该方法包括在催化有效量的负载或未负载的催化剂的存在下氢化相应的N-芳基氨基烷基硅烷，所述载体或非载体催化剂选自钯，铂，镍，铼，铑，钌，亚铬酸铜，以及上述的混合物。

5. 发明授权

US5900322A Aliphatic-aromatic copolyesters and cellulose ester/polymer blends 失效
公开(公告)号：US5900322A
公开(公告)日：1999-05-04
申请号：US763562
申请日：1996-12-10
申请人： Charles M. Buchanan , Robert M. Gardner , Matthew D. Wood , Alan W. White , Steven C. Gedon , Fred D. Barlow, Jr.
发明人： Charles M. Buchanan , Robert M. Gardner , Matthew D. Wood , Alan W. White , Steven C. Gedon , Fred D. Barlow, Jr.
IPC分类号： C08G63/02 , A61L15/22 , B29C55/02 , B29K67/00 , B29L7/00 , C08G63/00 , C08G63/16 , C08G63/181 , C08J5/18 , C08K5/10 , C08L1/00 , C08L1/02 , C08L1/08 , C08L1/10 , C08L1/12 , C08L1/14 , C08L3/02 , C08L29/04 , C08L31/04 , C08L33/00 , C08L33/04 , C08L33/12 , C08L67/00 , C08L67/02 , C08L67/04 , C08L69/00 , C08L91/08 , C08L101/00 , C08L101/16 , D01F2/28 , D01F6/84 , D01F6/92 , B32B27/36 , C08G63/18
CPC分类号： C08L67/00 , A61L15/225 , C08G63/16 , C08L1/10 , C08L1/14 , C08L67/02 , C08L67/04 , C08L2201/06 , Y10S428/91 , Y10T428/31786
摘要： This invention relates to binary blends of cellulose esters and aliphatic-aromatic copolyesters, cellulose esters and aliphatic polyesters as well as ternary blends of cellulose esters and/or aliphatic polyesters and/or aliphatic-aromatic copolyesters and/or polymeric compounds as well as fibers, molded objects, and films prepared therefrom.

6. 发明授权

US5599858A Aliphatic-aromatic copolyesters and cellulose ester/polymer blends 失效
标题翻译：脂肪族 - 芳族共聚酯和纤维素酯/聚合物共混物
公开(公告)号：US5599858A
公开(公告)日：1997-02-04
申请号：US427944
申请日：1995-04-26
申请人： Charles M. Buchanan , Robert M. Gardner , Matthew D. Wood , Alan W. White , Steven C. Gedon , Fred D. Barlow, Jr.
发明人： Charles M. Buchanan , Robert M. Gardner , Matthew D. Wood , Alan W. White , Steven C. Gedon , Fred D. Barlow, Jr.
IPC分类号： C08G63/02 , A61L15/22 , B29C55/02 , B29K67/00 , B29L7/00 , C08G63/00 , C08G63/16 , C08G63/181 , C08J5/18 , C08K5/10 , C08L1/00 , C08L1/02 , C08L1/08 , C08L1/10 , C08L1/12 , C08L1/14 , C08L3/02 , C08L29/04 , C08L31/04 , C08L33/00 , C08L33/04 , C08L33/12 , C08L67/00 , C08L67/02 , C08L67/04 , C08L69/00 , C08L91/08 , C08L101/00 , C08L101/16 , D01F2/28 , D01F6/84 , D01F6/92 , C08G63/183 , C08G63/672
CPC分类号： C08L67/00 , A61L15/225 , C08G63/16 , C08L1/10 , C08L1/14 , C08L67/02 , C08L67/04 , C08L2201/06 , Y10S428/91 , Y10T428/31786
摘要： This invention relates to binary blends of cellulose esters and aliphatic-aromatic copolyesters, cellulose esters and aliphatic polyesters as well as ternary blends of cellulose esters and/or aliphatic polyesters and/or aliphatic-aromatic copolyesters and/or polymeric compounds as well as fibers, molded objects, and films prepared therefrom.
摘要翻译：本发明涉及纤维素酯和脂族 - 芳族共聚酯，纤维素酯和脂族聚酯以及纤维素酯和/或脂族聚酯和/或脂族 - 芳族共聚酯和/或聚合物以及纤维的三元共混物的二元共混物，成型物品和由其制备的膜。

7. 发明授权

US5292783A Aliphatic-aromatic copolyesters and cellulose ester/polymer blends 失效
标题翻译：脂肪族 - 芳族共聚酯和纤维素酯/聚合物共混物
公开(公告)号：US5292783A
公开(公告)日：1994-03-08
申请号：US797512
申请日：1991-11-21
申请人： Charles M. Buchanan , Robert M. Gardner , Matthew D. Wood , Alan W. White , Steven C. Gedon , Fred D. Barlow, Jr.
发明人： Charles M. Buchanan , Robert M. Gardner , Matthew D. Wood , Alan W. White , Steven C. Gedon , Fred D. Barlow, Jr.
IPC分类号： C08G63/02 , A61L15/22 , B29C55/02 , B29K67/00 , B29L7/00 , C08G63/00 , C08G63/16 , C08G63/181 , C08G63/672 , C08J5/18 , C08K5/10 , C08L20060101 , C08L1/00 , C08L1/02 , C08L1/08 , C08L1/10 , C08L1/12 , C08L1/14 , C08L3/02 , C08L29/04 , C08L31/04 , C08L33/00 , C08L33/04 , C08L33/12 , C08L67/00 , C08L67/02 , C08L67/04 , C08L69/00 , C08L91/08 , C08L101/00 , C08L101/16 , D01F2/28 , D01F6/84 , D01F6/92
CPC分类号： C08L67/00 , A61L15/225 , C08G63/16 , C08G63/672 , C08L1/10 , C08L1/14 , C08L3/02 , C08L67/02 , C08L67/04 , C08L2201/06
摘要： This invention relates to binary blends of cellulose esters and aliphatic-aromatic copolyesters, cellulose esters and aliphatic polyesters as well as ternary blends of cellulose esters and/or aliphatic polyesters and/or aliphatic aromatic copolyesters and/or polymeric compounds as well as fibers, molded objects, and films prepared therefrom.
摘要翻译：本发明涉及纤维素酯和脂族 - 芳族共聚酯，纤维素酯和脂族聚酯以及纤维素酯和/或脂族聚酯和/或脂族芳族共聚酯和/或聚合物以及纤维的三元共混物的二元共混物，物件和电影。

8. 发明授权

US06586612B2 Process for the preparation of secondary and tertiary amino-functional silanes, iminoorganosilanes and/or imidoorganosilanes 有权
标题翻译：用于制备仲和叔氨基官能的硅烷，亚氨基有机硅烷和/或亚氨基有机硅烷的方法
公开(公告)号：US06586612B2
公开(公告)日：2003-07-01
申请号：US09990959
申请日：2001-11-16
申请人： Steven C. Gedon , Andrea Trotto
发明人： Steven C. Gedon , Andrea Trotto
IPC分类号： C07F702
CPC分类号： C07F7/1892 , C07F7/1804
摘要： Iminoorganosilanes may be prepared by reacting aminoorganosilanes with organoimines by an amine exchange reaction. The resultant iminoorganosilanes can then be catalytically reduced to produce secondary and tertiary amino silanes. Imidoorganosilanes can be prepared by a similar amine reaction between aminoorganosilanes and organoimides. The imidoorganosilanes can also be reacted to produce tertiary amines. Water-sensitive silane reactants may be employed to yield water-sensitive imino, imido, or amino silane products.
摘要翻译：亚氨基有机硅烷可以通过胺交换反应使氨基有机硅烷与有机亚胺反应来制备。然后可以催化还原所得的亚氨基有机硅烷以产生仲和叔氨基硅烷。亚氨基有机硅烷可以通过氨基有机硅烷和有机酰亚胺之间的类似的胺反应来制备。也可以将亚氨基有机硅烷反应生成叔胺。可以使用水敏性硅烷反应物来产生水敏感的亚氨基，亚氨基或氨基硅烷产物。

9. 发明授权

US06433206B1 Process for preparing silylorganomercaptans 有权
标题翻译：制备甲硅烷基有机硫醇的方法
公开(公告)号：US06433206B1
公开(公告)日：2002-08-13
申请号：US10012286
申请日：2001-11-15
申请人： Steven C. Gedon , Melinda Hale
发明人： Steven C. Gedon , Melinda Hale
IPC分类号： C07R708
CPC分类号： C07F7/1892
摘要： A process for preparing an organomercaptan is provided which comprises reacting a sulfide of the general formula (I) ((R1)3—Si—R2—S&Parenclosest;2Sm (I) in which each R1 is the same or different alkyl group of up to about 6 carbon atoms, aryl group of up to about 10 carbon atoms or alkoxy group of up to about 6 carbon atoms, or at least two of R1 and the silicon atom to which they are bonded form a ring system having up to about 12 ring members with no ethylenic unsaturation and optionally containing one or more heteroatoms selected from the group consisting of oxygen, sulfur and nitrogen, each R2 is the same or different divalent hydrocarbon group containing no ethylenic unsaturation and having up to about 20 carbon atoms and m is 0 to about 8, with hydrogen under hydrogenolysis conditions in the presence of a catalytically effective amount of Group VIII metal catalyst and in the presence of a catalyst poisoning inhibiting amount of a catalyst poisoning inhibitory agent selected from the group consisting of water, except where the mercaptan product contains at least one hydrolyzable silane group, alkanol of from 1 to about 6 carbon atoms, hydrogen sulfide and mixtures thereof to provide organomercaptan product of the general formula (II) in which R1 and R2 each has one of the aforestated meanings.
摘要翻译：提供一种制备有机巯基的方法，其包括使通式（I）的硫化物与其中每个R 1相同或不同的最多约6个碳原子的烷基，至多约10个碳原子的芳基或烷氧基至多约6个碳原子，或至少两个R 1与它们所键合的硅原子形成具有至多约12个环成员的环系统，其中没有烯属不饱和度，并且任选地含有一个或多个选自下组的杂原子由氧，硫和氮组成，每个R2是相同或不同的不含烯属不饱和基团并且具有至多约20个碳原子且m为0至约8的二价烃基，在氢解条件下，在催化有效量的VIII族金属催化剂，并且在催化剂中毒抑制量的情况下存在催化剂中毒抑制剂，所述催化剂中毒抑制剂选自水，除了其中硫醇产物含有至少一个可水解硅烷基团，1至约6个碳原子的链烷醇，硫化氢及其混合物，以提供通式（II）的有机巯基丁酸产物，其中R 1和R 2各自具有上述含义之一。

10. 发明授权

US06417381B1 Process for preparing bis(silylorgano)amines 有权
标题翻译：制备二（甲硅烷基有机）胺的方法
公开(公告)号：US06417381B1
公开(公告)日：2002-07-09
申请号：US10003849
申请日：2001-11-15
申请人： Steven C. Gedon , Melinda Hale , Michael P. Reynolds , Russell E. Malz, Jr.
发明人： Steven C. Gedon , Melinda Hale , Michael P. Reynolds , Russell E. Malz, Jr.
IPC分类号： C07F710
CPC分类号： C07F7/083 , C07F7/1892
摘要： A process is provided for preparing a bis(silylorgano)amine in which a cyanoorganosilane is reacted with hydrogen under hydrogenation conditions in the presence of a catalytically effective amount of hydrogenation catalyst selected from the group consisting of rhodium, ruthenium, palladium and platinum to produce the secondary aminoorganosilane.
摘要翻译：提供了一种制备双（甲硅烷基有机）胺的方法，其中氰化有机硅烷在氢化条件下，在催化有效量的选自铑，钌，钯和铂的氢化催化剂的存在下，与氢反应，生成仲氨基有机硅烷。

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