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1. 发明授权

US06277303B1 Conductive polymer composite materials and methods of making same 失效
标题翻译：导电聚合物复合材料及其制备方法
公开(公告)号：US06277303B1
公开(公告)日：2001-08-21
申请号：US09113963
申请日：1998-07-10
申请人： Stephen H. Foulger
发明人： Stephen H. Foulger
IPC分类号： H01B100
CPC分类号： H01B1/20 , C08K3/04 , C08K3/08 , C08K7/06 , H01B1/22 , H01B1/24
摘要： A conductive polymer composite material comprises: a minor phase material comprising a semicrystalline polymer; a conductive filler material dispersed in said minor phase material in an amount sufficient to be equal to or greater than an amount required to generate a continuous conductive network in said minor phase material; and a major phase material, said major phase material being a polymer which when mixed with said minor phase material will not engage in electrostatic interactions that promote miscibility, said major phase material having said minor phase material dispersed therein in an amount sufficient to be equal to or greater than an amount required to generate a continuous conductive network in said major phase material, forming a (semi)conductive ternary composite having distinct co-continuous phases.
摘要翻译：导电聚合物复合材料包括：包含半结晶聚合物的次相材料; 分散在所述次相材料中的导电填料，其量足以等于或大于在所述次相材料中产生连续导电网络所需的量; 所述主相材料是聚合物，当与所述次相材料混合时，聚合物不会引起促进混溶性的静电相互作用，所述主相材料具有分散在其中的足够量的量的所述次相材料或大于在所述主相材料中产生连续导电网络所需的量，形成具有不同共连续相的（半）导电三元复合材料。

2. 发明授权

US06514608B1 Semiconductive jacket for cable and cable jacketed therewith 失效
标题翻译：用于电缆和电缆夹套的半导体护套
公开(公告)号：US06514608B1
公开(公告)日：2003-02-04
申请号：US09113914
申请日：1998-07-10
申请人： Stephen H. Foulger
发明人： Stephen H. Foulger
IPC分类号： D02G300
CPC分类号： H01B1/22 , H01B1/24 , Y10T428/2927 , Y10T428/294 , Y10T428/2947
摘要： A semiconductive jacket material for jacketing a cable comprising a minor phase material which is a semicrystalline polymer; a conductive filler material dispersed in the minor phase material in an amount sufficient to be equal to or greater than an amount required to generate a continuous conductive network in the minor phase material; and a major phase material which is a polymer which when mixed with the minor phase material will not engage in electrostatic interactions that promote miscibility. The major phase material has the minor phase material dispersed therein in an amount sufficient to be equal to or greater than an amount required to generate a continuous conductive network in the major phase material, forming a semiconductive jacket material of a ternary composite having distinct co-continuous phases.
摘要翻译：一种用于护套的半导体护套材料，其包含作为半结晶聚合物的次相材料; 分散在次相材料中的导电填料材料，其量足以等于或大于在次相材料中产生连续导电网络所需的量; 以及作为聚合物的主相材料，当与次相材料混合时不会引起促进混溶性的静电相互作用。主相材料具有分散在其中的少量相材料，其量足以等于或大于在主相材料中产生连续导电网络所需的量，形成具有不同共晶的三元复合材料的半导体护套材料，连续阶段

3. 发明授权

US06506492B1 Semiconductive jacket for cable and cable jacketed therewith 有权
标题翻译：用于电缆和电缆夹套的半导体护套
公开(公告)号：US06506492B1
公开(公告)日：2003-01-14
申请号：US09306735
申请日：1999-05-07
申请人： Stephen H. Foulger
发明人： Stephen H. Foulger
IPC分类号： D02G300
CPC分类号： H01B1/22 , H01B1/24 , Y10T428/2927 , Y10T428/294 , Y10T428/2947
摘要： A conductive polymer composite material for semiconductive jackets for cables which has a significant reduction in conductive filler content while maintaining the required conductivity and mechanical properties specified by industry. Materials and processing approaches are selected to reduce the percolation threshold of the conductive filler in the composite, while balancing the material selection with the industry-required mechanical properties of the semiconductive jacket. The semiconductive jacket material comprises a minor phase material which is a semicrystalline polymer; a conductive filler material dispersed in the minor phase material in an amount sufficient to be equal to or greater than an amount required to generate a continuous conductive network in the minor phase material; and a major phase material which is a polymer which when mixed with the minor phase material will not engage in electrostatic interactions that promote miscibility. The major phase material has the minor phase material dispersed therein in an amount sufficient to be equal to or greater than an amount required to generate a continuous conductive network in the major phase material, forming a semiconductive jacket material of a ternary composite having distinct co-continuous phases.
摘要翻译：一种用于电缆的半导体套管的导电聚合物复合材料，其具有显着降低导电填料含量，同时保持工业规定的所需导电性和机械性能。选择材料和处理方法以减少复合材料中导电填料的渗透阈值，同时平衡材料选择与半导体护套的工业要求的机械性能。所述半导体护套材料包括作为半结晶聚合物的次相材料; 分散在次相材料中的导电填料材料，其量足以等于或大于在次相材料中产生连续导电网络所需的量; 以及作为聚合物的主相材料，当与次相材料混合时不会引起促进混溶性的静电相互作用。主相材料具有分散在其中的少量相材料，其量足以等于或大于在主相材料中产生连续导电网络所需的量，形成具有不同共晶的三元复合材料的半导体护套材料，连续阶段

4. 发明授权

US06946086B2 Chemical compositions comprising crystalline colloidal arrays 失效
标题翻译：包含结晶胶体阵列的化学组合物
公开(公告)号：US06946086B2
公开(公告)日：2005-09-20
申请号：US09998922
申请日：2001-11-30
申请人： Stephen H. Foulger , Ping Jiang , Amanda C. Lattam , Travis Baughman , John Ballato , Dennis W. Smith
发明人： Stephen H. Foulger , Ping Jiang , Amanda C. Lattam , Travis Baughman , John Ballato , Dennis W. Smith
IPC分类号： G01N33/543 , G01N33/545 , G02B5/23 , A61K49/00 , B01D21/01 , G01D21/00 , G01N33/00
CPC分类号： G01N33/54313 , B01J2219/005 , B01J2219/00576 , B01J2219/00702 , G01N33/54373 , G01N33/545 , Y10T436/177692
摘要： Crystalline colloidal arrays (CCA) which have been encapsulated in a polymer matrix to produce more robust polymerized crystalline colloidal arrays (PCCA) are provided. The PCCA's of the present invention can be in the form of a hydrogel which can be compatible for use with a biological system. The polymer matrix of the PCCA is formed of polymerized poly(ethylene glycol) based monomer units which can provide a desired functionality to the PCCA. The PCCA can be formed to exhibit a photonic bandgap at a certain wavelength. The photonic bandgap can be capable of shifting upon some form of environmental stimulation rendering the PCCA suitable for many optical applications, including active photonic switching and sensory applications.
摘要翻译：提供已经封装在聚合物基质中以产生更坚固的聚合晶体胶体阵列（PCCA）的结晶胶体阵列（CCA）。本发明的PCCA可以是能够与生物系统一起使用的水凝胶的形式。 PCCA的聚合物基质由聚合的基于聚（乙二醇）的单体单元形成，其可以为PCCA提供期望的功能。可以形成PCCA以在一定波长处展现光子带隙。光子带隙能够在某种形式的环境刺激下转变，使得PCCA适用于许多光学应用，包括有源光子切换和感官应用。

5. 发明授权

US06331353B1 Stranded conductor filling compound and cables using same 有权
标题翻译：绞线导体填充复合物和电缆使用相同
公开(公告)号：US06331353B1
公开(公告)日：2001-12-18
申请号：US09375717
申请日：1999-08-17
申请人： Stephen H. Foulger
发明人： Stephen H. Foulger
IPC分类号： B32B1500
CPC分类号： H01B7/288 , H01B7/285 , Y02A30/14 , Y10T428/2927 , Y10T428/294 , Y10T428/2947
摘要： A strand filling compound for electrical cables, and cables including such a compound, which prevents migration of water lengthwise of the stranded wires of the conductor of the cable. The strand filling compound has a low conductive filler content without reducing the level of conductivity of the compound and is readily pumpable at temperatures above about 100° C. The strand filling compound is provided by employing an immiscible polymer blend containing conductive filler located primarily in one phase, the immiscible polymer blend being comprised of a low molecular weight polymer and a second polymer, preferably an adhesive EVA. Preferably an adhesive extender which is miscible with the low molecular weight polymer, and fine particles of a material admixed with the filling compound and/or provided as a thin layer of fine particles of a material applied over the filling compound which swells when it absorbs water are also included in the filling compound.
摘要翻译：用于电缆的线束填充化合物，以及包括这种化合物的电缆，其防止长度方向的水的电缆的导体的绞合线的迁移。线填充化合物具有低的导电填料含量，而不降低化合物的导电性，并且在高于约100℃的温度下容易泵送。通过使用含有主要位于一个中的导电填料的不混溶聚合物共混物来提供线填充化合物不相混合的聚合物共混物由低分子量聚合物和第二聚合物，优选粘合剂EVA组成。优选地，与低分子量聚合物混溶的粘合剂增量剂和与填充化合物混合的材料的细颗粒和/或作为涂覆在填充化合物上的材料的细颗粒的薄层提供，其在吸收水时膨胀也包括在填充化合物中。

6. 发明授权

US07208682B2 Electrical cable with foamed semiconductive insulation shield 失效
标题翻译：电缆带泡沫半导体绝缘护罩
公开(公告)号：US07208682B2
公开(公告)日：2007-04-24
申请号：US10537707
申请日：2002-12-11
申请人： Frank L. Kuchta , Stephen H. Foulger , Jason Carden , Chengjun Liu , Andrew Maunder , Alberto Bareggi , Luca Balconi , Cristiana Scelza
发明人： Frank L. Kuchta , Stephen H. Foulger , Jason Carden , Chengjun Liu , Andrew Maunder , Alberto Bareggi , Luca Balconi , Cristiana Scelza
IPC分类号： H01B7/00
CPC分类号： H01B13/14 , H01B3/446 , H01B7/189 , H01B9/027
摘要： An electrical power cable with a foamed, compressible, semiconductive insulation shield which serves as both a cushioning layer and an electrical shield.
摘要翻译：一种具有泡沫，可压缩，半导体绝缘护罩的电力电缆，既用作缓冲层，又用作电屏蔽。

7. 发明授权

US06197219B1 Conductive polymer composite materials and methods of making same 有权
公开(公告)号：US06197219B1
公开(公告)日：2001-03-06
申请号：US09307057
申请日：1999-05-07
申请人： Stephen H. Foulger
发明人： Stephen H. Foulger
IPC分类号： H01B106
CPC分类号： H01B1/20 , C08K3/04 , C08K3/08 , C08K7/06 , H01B1/22 , H01B1/24
摘要： A conductive polymer composite material comprises: a minor phase material comprising a semicrystalline polymer; a conductive filler material dispersed in said minor phase material in an amount sufficient to be equal to or greater than an amount required to generate a continuous conductive network in said minor phase material; and a major phase material, said major phase material being a polymer which when mixed with said minor phase material will not engage in electrostatic interactions that promote miscibility, said major phase material having said minor phase material dispersed therein in an amount sufficient to be equal to or greater than an amount required to generate a continuous conductive network in said major phase material, forming a (semi)conductive ternary composite having distinct co-continuous phases.

8. 发明授权

US08691116B2 Conducting polymer ink 有权
标题翻译：导电聚合物油墨
公开(公告)号：US08691116B2
公开(公告)日：2014-04-08
申请号：US12293826
申请日：2007-03-23
申请人： Moon Gyu Han , Jay K. Sperry , Samuel T. Ingram , Stephen H. Foulger
发明人： Moon Gyu Han , Jay K. Sperry , Samuel T. Ingram , Stephen H. Foulger
IPC分类号： H01B1/00 , B32B5/16
CPC分类号： C09D11/52 , Y10T428/2998
摘要： Disclosed are conductive polymer inks and methods for forming the inks. The disclosed inks include a dispersion of conductive core/shell nanoparticles. The core/shell nanoparticles include a polymeric core and a shell formed of a conducting polymer. The inks can include a dispersion of the core/shell nanoparticles in a liquid carrier, such as an alcohol. The disclosed inks can be formulated to high viscosities and can be utilized in high-speed printing processes including rotogravure and flexographic printing processes. Products encompassed by the disclosure include polymer devices such as sensors, OFETs, RFID tags, printed circuit board, electrochromic devices, non-volatile memory devices, photovoltaics, and the like.
摘要翻译：公开了导电聚合物油墨和用于形成油墨的方法。所公开的油墨包括导电核/壳纳米颗粒的分散体。核/壳纳米颗粒包括聚合物芯和由导电聚合物形成的壳。油墨可以包括核/壳纳米颗粒在液体载体如醇中的分散体。所公开的油墨可以配制成高粘度，并且可以用于包括轮转凹版印刷和柔性版印刷工艺的高速印刷工艺中。由本公开包含的产品包括诸如传感器，OFET，RFID标签，印刷电路板，电致变色器件，非易失性存储器件，光伏等的聚合物器件。

9. 发明授权

US07785496B1 Electrochromic inks including conducting polymer colloidal nanocomposites, devices including the electrochromic inks and methods of forming same 有权
标题翻译：包括导电聚合物胶体纳米复合材料的电致变色油墨，包括电致变色油墨的装置及其形成方法
公开(公告)号：US07785496B1
公开(公告)日：2010-08-31
申请号：US12019084
申请日：2008-01-24
申请人： Goo Hwan Shim , Moon Gyu Han , Stephen H. Foulger
发明人： Goo Hwan Shim , Moon Gyu Han , Stephen H. Foulger
IPC分类号： H01B1/00 , B05D5/12
CPC分类号： C09K9/02 , C09D5/24 , C09D11/32 , C09D11/38 , G02F1/1521 , H01B1/127 , H01B1/128
摘要： Disclosed are electrochromic inks and devices incorporating the inks as well as methods for forming the inks and the devices. The disclosed inks include a dispersion of colloidal nanocomposite particles in a liquid carrier. The colloidal nanocomposites of the disclosed inks include nanoparticle templates, e.g., silica nanoparticles, and an intrinsically conductive polymer polymerized at the template nanoparticles. The inks can include a dispersion of the colloidal nanocomposites in a liquid carrier such as an aprotic polar organic solvent. The disclosed inks can be formulated to be utilized in any desired printing process such as inkjet printing processes. Products encompassed by the invention include all-polymer electronic, optic, photonic, electro-optic, and energy devices such as sensors, OFETs, RFID tags, printed circuit board, electrochromic devices, non-volatile memory devices, photovoltaics, and the like.
摘要翻译：公开了电致变色油墨和结合油墨的装置以及用于形成油墨和装置的方法。所公开的油墨包括胶体纳米复合颗粒在液体载体中的分散体。所公开的油墨的胶体纳米复合材料包括纳米颗粒模板，例如二氧化硅纳米颗粒，以及在模板纳米颗粒聚合的固有导电聚合物。油墨可以包括胶体纳米复合材料在液体载体如非质子极性有机溶剂中的分散体。所公开的油墨可以配制成用于任何所需的印刷工艺，如喷墨印刷工艺。本发明所涵盖的产品包括全聚合物电子，光学，光子，电光和能量设备，例如传感器，OFET，RFID标签，印刷电路板，电致变色器件，非易失性存储器件，光伏等。

10. 发明授权

US07582231B2 Essentially water-free polymerized crystalline colloidal array composites having tunable radiation diffracting properties 失效
$Essentially water-free polymerized crystalline colloidal array composites having tunable radiation diffracting properties$
标题翻译：基本上无水聚合的结晶胶体阵列复合材料具有可调辐射衍射性能
公开(公告)号：US07582231B2
公开(公告)日：2009-09-01
申请号：US11228143
申请日：2005-09-16
申请人： Stephen H. Foulger , Ping Jiang
发明人： Stephen H. Foulger , Ping Jiang
IPC分类号： G02B26/00 , G02B5/20 , G02F1/01 , F21V9/10 , B01J13/00
CPC分类号： B82Y20/00 , C30B5/00 , C30B29/60 , G02B6/1225 , G02F1/21 , G02F2201/307 , G02F2202/32
摘要： The present invention is directed to a composite having tunable radiation diffracting properties which includes a flexible, water-free polymeric matrix and a crystalline colloidal array of particles having a lattice spacing, the array being embedded in the polymeric matrix and the lattice spacing changing responsive to stress applied to the polymeric matrix, thereby causing the radiation diffracting properties to change, wherein the polymeric matrix, the lattice spacing and the radiation diffracting properties all return to their original state essentially immediately upon removal of the stress. The present inventive composite is preferably made by a process, which involves forming a preliminary hydrogel polymerized crystalline colloidal array (PCCA), dehydrating the PCCA, and then forming a final, encapsulating polymeric matrix.
摘要翻译：本发明涉及具有可调辐射衍射性质的复合材料，其包括柔性的无水聚合物基质和具有晶格间距的颗粒的晶体胶体阵列，所述阵列嵌入聚合物基质中，并且晶格间距响应于施加到聚合物基质上的应力，从而导致辐射衍射性能改变，其中聚合物基体，晶格间距和辐射衍射性质在去除应力时基本上立即恢复到其初始状态。本发明的复合材料优选通过一种方法制备，该方法包括形成预先水凝胶聚合的结晶胶体阵列（PCCA），使PCCA脱水，然后形成最终的包封聚合物基质。

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