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    • 1. 发明申请
    • SELF-CLEANING COATING COMPOSITION
    • 自清洁涂料组合物
    • US20120118318A1
    • 2012-05-17
    • US13140088
    • 2009-12-16
    • Soren Hillebrandt PoulsenPer MollerSverrir Grimur Gunnarsson
    • Soren Hillebrandt PoulsenPer MollerSverrir Grimur Gunnarsson
    • C09D7/12C09D175/04B08B7/04C09D167/03
    • C03C11/002B01J21/08B01J35/004B01J35/08B01J37/0209B01J37/0215B01J37/0219B01J37/0221C01P2002/72C01P2004/03C01P2004/32C01P2004/34C03C12/02C03C17/256C03C2217/212C03C2217/71C03C2218/111C03C2218/113C08K7/28C08K9/02C09C1/30C09C3/063C09D5/16C09D5/1606C09D5/1687C09D7/62C09D7/68C09D7/69
    • The present invention relates to compositions with self-cleaning properties. More particularly, the invention concerns coatings or paints comprising particles coated with a catalytically active composition. In particular, a self-cleaning coating composition (paint) is provided, comprising micro-sized particles coated with a functional layer, wherein the micro-sized particles are hollow or solid beads, or any combination/ratio of hollow and solid beads, wherein the beads comprise one or more material(s) selected from ceramic material(s); polymeric material(s); cermet material(s); metallic material(s); pigmented material(s); light-absorbing and/or light reflecting material(s); including any combination thereof, wherein said layer is covalently bound to said particles, wherein the photocatalytic layer comprises TiO2 in the crystal form of anatase; and wherein the coating composition (paint) comprises less than 0.1 anatase particles derived/released from the micro-sized beads, determined as weight/weight of released anatase/total amount of anatase. The invention provides paint essentially without presence of unbound anatase crystals which is highly undesired, as it is believed that their presence has a negative influence on essential components of the paint, such as binder, pigment and/or additives and furthermore, anatase may cause eye, skin, and respiratory tract irritation.
    • 本发明涉及具有自清洁性质的组合物。 更具体地,本发明涉及包含用催化活性组合物涂覆的颗粒的涂料或涂料。 特别地,提供了一种自清洁涂料组合物(涂料),其包含涂覆有功能层的微尺寸颗粒,其中微尺寸颗粒是中空或固体珠粒,或中空和固体珠粒的任何组合/比例,其中 珠粒包含一种或多种选自陶瓷材料的材料; 聚合物材料; 金属陶瓷材料; 金属材料; 着色材料; 光吸收和/或光反射材料; 包括其任何组合,其中所述层共价结合到所述颗粒,其中所述光催化层包含锐钛矿晶体形式的TiO 2; 并且其中所述涂料组合物(涂料)包含从所述微尺寸珠粒衍生/释放的少于0.1个锐钛矿颗粒,其确定为所释放的锐钛矿的重量/重量/锐钛酸的总量。 本发明提供基本上不存在未结合的锐钛矿晶体的涂料,这是非常不期望的,因为它们的存在对涂料的基本组分如粘合剂,颜料和/或添加剂具有负面影响,此外,锐钛矿可能引起眼睛 ,皮肤和呼吸道刺激。