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1. 发明授权

US5061770A Aromatic dicarboxylic acid diallyl ester derivative, prepolymer derived from the derivative and curable resin composition containing the derivative 失效
标题翻译：衍生自衍生物和可固化树脂组合物衍生物的芳族二羧酸二异氰酸酯衍生物
公开(公告)号：US5061770A
公开(公告)日：1991-10-29
申请号：US338835
申请日：1989-04-14
申请人： Sinji Tamaru , Motonobu Kubo
发明人： Sinji Tamaru , Motonobu Kubo
IPC分类号： C08F18/16 , C08F290/04 , C08F291/00
CPC分类号： C08F290/046 , C08F18/16 , C08F291/00
摘要： A diallyl aromatic dicarboxylate derivative of the formula ##STR1## wherein Y is hydrogen atom or perfluoroalkenyl group having 6 to 14 carbon atoms, is a novel compound. The compound (1) is a starting material for a prepolymer containing a repeating unit derived from diallyl aromatic fluorine-containing dicarboxylate and represented by the formula ##STR2## wherein X is prefluoroalkenyl group having 6 to 14 carbon atoms. Further, the present invention provides a curable resin composition which comprises a prepolymer having at least one carbon-carbon double bond in the molecule and diallyl aromatic fluorine-containing dicarboxylate represented by the formula ##STR3##

2. 发明授权

US4587165A Films of a copolymer of an ester derived from a fluorine-containing alcohol 失效
标题翻译：由含氟醇衍生的酯的共聚物膜
公开(公告)号：US4587165A
公开(公告)日：1986-05-06
申请号：US639855
申请日：1984-08-13
申请人： Akira Ohmori , Nobuyuki Tomihashi , Sinji Tamaru
发明人： Akira Ohmori , Nobuyuki Tomihashi , Sinji Tamaru
IPC分类号： B41N1/00 , C07C43/11 , C07C43/13 , C08F20/28 , C08G65/00 , C08G65/332 , G03F7/004 , G03G13/28 , C08F14/18
CPC分类号： C08F20/28 , B41N1/003 , C07C43/11 , C07C43/137 , C08G65/007 , C08G65/3322 , G03F7/0046 , G03G13/286 , Y10T428/263 , Y10T428/3154
摘要： An original plate for dry offset printing comprising a substrate suitable for preparation of an offset printing plate and a film formed on the substrate. The film consists essentially of a copolymer formed from at least 40% of a monomer of the formula: ##STR1## wherein n is an integer of 2 to 7 and R is hydrogen or methyl; and at least one other ethylenically unsaturated monomer.
摘要翻译：一种用于干胶版印刷的原版，其包括适于制备胶印板的基材和形成在基材上的膜。该膜基本上由由至少40％下式的单体形成的共聚物：其中n是2至7的整数，R是氢或甲基; 和至少一种其它烯属不饱和单体。

3. 发明授权

US4529783A Novel copolymer and photosensitive material containing the same 失效
标题翻译：共聚物和含有它的感光材料
公开(公告)号：US4529783A
公开(公告)日：1985-07-16
申请号：US502750
申请日：1983-06-09
申请人： Takahiro Tsunoda , Tsuguo Yamaoka , Akira Ohmori , Nobuyuki Tomihashi , Sinji Tamaru
发明人： Takahiro Tsunoda , Tsuguo Yamaoka , Akira Ohmori , Nobuyuki Tomihashi , Sinji Tamaru
IPC分类号： C08F2/00 , C08F2/48 , C08F20/00 , C08F20/10 , C08F20/22 , C08F220/28 , G03F7/004 , G03F7/027 , C08F214/18
CPC分类号： C08F220/28 , G03F7/0046 , Y10S522/904 , Y10S522/905
摘要： A copolymer comprising (a) units of a fluorine-containing acrylic monomer having a general formula ##STR1## wherein X is F or CF.sub.3, Y is H or CH.sub.3, n is an integer of 2 to 7, and (b) units of an ethylenically unsaturated monomer having a photosensitive group. The copolymer has an excellent photosensitivity and excellent water and oil repellent properties, and is useful for example as a photosensitive material for dry offset printing plate or resist and as a photo-curable, water and oil repelling coating material.
摘要翻译：一种共聚物，其包含（a）具有通式“IMAGE”的含氟丙烯酸类单体的单元，其中X为F或CF 3，Y为H或CH 3，n为2至7的整数，和（b）具有感光性基团的烯属不饱和单体。该共聚物具有优异的光敏性和优异的耐油和拒油性能，并且可用作例如干胶版印刷版或抗蚀剂的光敏材料以及可光固化的防油斥油涂料。

4. 发明授权

US5175207A Aromatic dicarboxylic acid diallyl ester derivatives, prepolymer derived from the derivative and curable resin composition containing the derivative 失效
标题翻译：芳族二羧酸二烯丙基酯衍生物，衍生自衍生物的预聚物和含有该衍生物的固化性树脂组合物
公开(公告)号：US5175207A
公开(公告)日：1992-12-29
申请号：US606982
申请日：1990-10-31
申请人： Sinji Tamaru , Motonobu Kubo
发明人： Sinji Tamaru , Motonobu Kubo
IPC分类号： C08F18/16 , C08F290/04 , C08F291/00
CPC分类号： C08F290/046 , C08F18/16 , C08F291/00
摘要： A diallyl aromatic dicarboxylate derivative of the formula ##STR1## wherein Y is hydrogen atom or perfluoroalkenyl group having 6 to 14 carbon atoms, is a novel compound. The compound (1) is a starting material for a prepolymer containing a repeating unit derived from diallyl aromatic fluorine-containing dicarboxylate and represented by the formula ##STR2## wherein X is perfluoroalkenyl group having 6 to 14 carbon atoms. Further, the present invention provides a curable resin composition which comprises a prepolymer having at least one carbon-carbon double bond in the molecule and diallyl aromatic fluorine-containing dicarboxylate represented by the formula ##STR3##
摘要翻译：式（1）的二烯丙基芳族二羧酸酯衍生物，其中Y是氢原子或具有6-14个碳原子的全氟链烯基，是一种新型化合物。化合物（1）是含有源自二烯丙基芳族含氟二羧酸酯的重复单元的预聚物的原料，由式（6）表示，其中X是具有6-14个碳原子的全氟链烯基。此外，本发明提供一种固化性树脂组合物，其含有分子中具有至少一个碳 - 碳双键的预聚物和由式（3）表示的二烯丙基芳族含氟二羧酸酯，

5. 发明授权

US4877859A Fluorine-containing novolak resin and derivative thereof 失效
标题翻译：含氟酚醛清漆树脂及其衍生物
公开(公告)号：US4877859A
公开(公告)日：1989-10-31
申请号：US171126
申请日：1988-03-21
申请人： Sinji Tamaru , Motonobu Kubo , Masato Kashiwagi
发明人： Sinji Tamaru , Motonobu Kubo , Masato Kashiwagi
IPC分类号： C08G8/08 , C08G59/08 , C08G59/32
CPC分类号： C08G59/08 , C08G59/3218 , C08G59/3254 , C08G8/08
摘要： The present invention provides a fluroine-containing novolak resin or its derivative having a repeating unit of the formula ##STR1## wherein R.sup.1 is hydrogen atom, OH or ##STR2## R.sup.2 is hydrogen atom or alkyl group having 1 to 4 carbon atoms, X is fluorine-containing monovalent organic group having 2 to 20 carbon atoms.The present invention also provides a perfluoroalkenyloxphenol or its derivative of the formula ##STR3## wherein R.sup.10 is OH or ##STR4## R.sup.11 is H, OH, alkyl group having 1 to 4 carbon atoms or ##STR5## Y is perfluoroalkenyl group having 6 to 14 carbon atoms.

6. 发明授权

US4841093A Aromatic dicarboxylic acid diallyl ester derivative, prepolymer derived from the derivative and curable resin composition containing the derivative 失效
标题翻译：芳族二羧酸二烯丙基酯衍生物，衍生自该衍生物的预聚物和含有该衍生物的固化性树脂组合物
公开(公告)号：US4841093A
公开(公告)日：1989-06-20
申请号：US109413
申请日：1987-10-19
申请人： Sinji Tamaru , Motonobu Kubo
发明人： Sinji Tamaru , Motonobu Kubo
IPC分类号： C08F18/16 , C08F290/04 , C08F291/00
CPC分类号： C08F290/046 , C08F18/16 , C08F291/00
摘要： A diallyl aromatic dicarboxylate derivative of the formula ##STR1## wherein Y is hydrogen atom or perfluoroalkenyl group having 6 to 14 carbon atoms, is a novel compound. The compound (1) is a starting material for a prepolymer containing a repeating unit derived from diallyl aromatic fluorine-containing dicarboxylate and represented by the formula ##STR2## wherein X is prefluoroalkenyl group having 6 to 14 carbon atoms. Further, the present invention provides a curable resin composition which comprises a prepolymer having at least one carbon-carbon double bond in the molecule and diallyl aromatic fluorine-containing dicarboxylate represented by the formula ##STR3##
摘要翻译：式（1）的二烯丙基芳族二羧酸酯衍生物，其中Y是氢原子或具有6-14个碳原子的全氟链烯基，是一种新型化合物。化合物（1）是含有衍生自二烯丙基芳族含氟二羧酸酯的重复单元的预聚物的原料，由式（6）表示，其中X是具有6至14个碳原子的前氟烯基。此外，本发明提供一种固化性树脂组合物，其含有分子中具有至少一个碳 - 碳双键的预聚物和由式（3）表示的二烯丙基芳族含氟二羧酸酯，

7. 发明授权

US4725375A Etchant composition 失效
标题翻译：蚀刻剂组成
公开(公告)号：US4725375A
公开(公告)日：1988-02-16
申请号：US908943
申请日：1986-09-16
申请人： Tsuneo Fujii , Takayuki Deguchi , Sinji Tamaru
发明人： Tsuneo Fujii , Takayuki Deguchi , Sinji Tamaru
IPC分类号： C09K13/12 , C23F1/26 , C23F1/02 , B44C1/22 , C03C15/00 , C03C25/06
CPC分类号： C09K13/12 , C23F1/26
摘要： An etchant composition comprising(a) a cerium (IV) salt,(b) a nonionic or anionic fluorine-containing surfactant,(c) water, and(d) optionally, at least one compound selected from the group consisting of perchloric acid, acetic acid, sulfuric acid, nitric acid and hydrochloric acid and salts thereof, which can homogeneously etch a resist pattern having thin gaps as well as wide gaps on a chrome layer.
摘要翻译：一种蚀刻剂组合物，其包含（a）铈（IV）盐，（b）非离子或阴离子含氟表面活性剂，（c）水和（d）任选的至少一种选自高氯酸，乙酸，硫酸，硝酸和盐酸及其盐，其可以均匀地蚀刻具有薄间隙的抗蚀剂图案以及铬层上的宽间隙。

8. 发明授权

US4673243A Branch structures for rod-type optical transmission lines 失效
标题翻译：棒式光传输线的分支结构
公开(公告)号：US4673243A
公开(公告)日：1987-06-16
申请号：US705790
申请日：1985-02-26
申请人： Hiroshi Yamashita , Kanenaga Fujii , Junji Hayakawa , Toru Komiyama , Sinji Tamaru
发明人： Hiroshi Yamashita , Kanenaga Fujii , Junji Hayakawa , Toru Komiyama , Sinji Tamaru
IPC分类号： G02B6/28 , G02B6/38 , G02B6/26 , G02B6/42
CPC分类号： G02B6/2821 , G02B6/2804 , G02B6/3801
摘要： This invention provides a branch structure for a rod-type optical transmission line having a quartz rod core, characterized in that two quartz rod branch members bent to a substantially L-shaped form and having a circular cross section are combined together with the axes of longitudinal portions of the members in parallel and with the horizontal portions thereof bifurcated, the combined longitudinal portions being ground to a planar surface each at the opposed faces thereof so as to conjointly form a circular cross section in a predetermined cross sectional area ratio, the combined longitudinal portions being adhered together at the ground planar surfaces, conjointly having the same diameter as the quartz rod core and being coaxially connected to the core at a straight portion of the transmission line. The branch structure of the present invention can divide light for transmission into a branch line at a desired ratio with a reduced transmission loss.
摘要翻译：本发明提供了一种具有石英杆芯的棒式光传输线的分支结构，其特征在于两个石英杆分支部件弯曲成大致L形并具有圆形横截面，与纵向轴线构件的平行部分和水平部分分叉，组合的纵向部分在其相对的面上分别被研磨成平面，从而以预定的横截面积比结合形成圆形横截面，组合纵向部分在接地平面上粘合在一起，共同地具有与石英棒芯相同的直径，并且在传输线的直线部分同轴地连接到芯。本发明的分支结构可以以传输损耗降低的方式将发送光以期望的比例分散到支线中。

9. 发明授权

US4365049A Fluoroalkyl acrylate copolymer and composition containing the same 失效
标题翻译：氟烷基丙烯酸酯共聚物和含有它们的组合物
公开(公告)号：US4365049A
公开(公告)日：1982-12-21
申请号：US246156
申请日：1981-03-23
申请人： Takahiro Tsunoda , Tsuguo Yamaoka , Sinji Tamaru
发明人： Takahiro Tsunoda , Tsuguo Yamaoka , Sinji Tamaru
IPC分类号： C08F220/22 , C08F20/00 , C08F20/22 , C08F20/34 , C08F220/24 , C08F220/36 , G03F7/004 , G03F7/039
CPC分类号： C08F220/24 , G03F7/0046
摘要： A fluoroalkyl acrylate copolymer comprising recurring units of the general formula (I): ##STR1## wherein R.sub.1 is hydrogen atom or methyl group, R.sub.2 is a bivalent hydrocarbon group and R.sub.f is a C.sub.2 to C.sub.6 straight or branched perfluoroalkyl group or a C.sub.2 to C.sub.6 straight or branched fluoroalkyl group having hydrogen atoms of not less than one and of not more than half of the number of the carbon atoms,and recurring units of the general formula (II): ##STR2## wherein R.sub.3 is hydrogen atom or methyl group and R.sub.4 is a bivalent hydrocarbon group or a mono-substituted bivalent hydrocarbon group with hydroxyl group or a halogen except fluorine. The copolymer is curable with light and energy rays, and is suitable as a material sensitive thereto for use in resist, dry lithographic printing plate and paint.
摘要翻译：包含通式（I）的重复单元的氟代烷基丙烯酸酯共聚物：其中R 1是氢原子或甲基，R 2是二价烃基，R f是C 2至C 6直链或支链全氟烷基或具有不少于1个碳原子数不超过一个且不超过一半的C 2 -C 6直链或支链氟代烷基，以及通式（II）的重复单元：其中R 3为氢原子或甲基，R4是具有羟基的二价烃基或单取代的二价烃基或氟以外的卤素。共聚物可用光和能量射线固化，并且适合作为敏感材料用于抗蚀剂，干版印刷版和油漆。

10. 发明授权

US4841005A Tricyclodecane derivative 失效
标题翻译：三环癸烷衍生物
公开(公告)号：US4841005A
公开(公告)日：1989-06-20
申请号：US155608
申请日：1988-02-12
申请人： Sinji Tamaru , Motonobu Kubo
发明人： Sinji Tamaru , Motonobu Kubo
IPC分类号： C07C35/52 , C07C69/65 , C07C69/653
CPC分类号： C07C69/65 , C07C35/52 , C07C69/653
摘要： A tricyclodecane derivative represented by formula (I): ##STR1## wherein R.sup.1 represents a group X.sup.1 O-- or a hydrogen atom;R.sup.2 represents a hydrogen atom when R.sup.1 represents a group X.sup.1 O--, or R.sup.2 represents a group X.sup.1 O-- when R.sup.1 represents a hydrogen atom;wherein X.sup.1 represents a group ##STR2## or a hydrogen atom, wherein X.sup.2 represents a hydrogen atom, a methyl group, or a trifluoromethyl group;R.sup.3 represents a fluoroalkyl group containing from 1 to 21 carbon atoms, an iodine atom, or a hydrogen atom; andR.sup.4 represents an iodine atom or a hydrogen atom when R.sup.3 represents a fluoroalkyl group containing from 1 to 21 carbon atoms, or R.sup.4 represents a fluoroalkyl group containing from 1 to 21 carbon atoms when R.sup.3 represents an iodine atom or a hydrogen atom.
摘要翻译：由式（I）表示的三环癸烷衍生物：其中R1表示基团X1O-或氢原子; 当R1表示一个基团X1O-时，R2表示氢原子，或当R1表示氢原子时R2表示基团X1O-; 其中X1表示基团或氢原子，其中X2表示氢原子，甲基或三氟甲基; R3表示含有1至21个碳原子的氟代烷基，碘原子或氢原子; R 3表示含有1〜21个碳原子的氟烷基时，R 4表示碘原子或氢原子，R 3表示R 3表示碘原子或氢原子时，R 4表示碳原子数1〜21的氟代烷基。

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