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    • 3. 发明授权
    • Acrylic fiber having excellent durability and dyeability and process for
preparation thereof
    • 丙烯酸纤维具有优异的耐久性和染色性及其制备方法
    • US4663232A
    • 1987-05-05
    • US728276
    • 1985-04-29
    • Kenji KamideYutaka HondaShuji Kajita
    • Kenji KamideYutaka HondaShuji Kajita
    • D01F6/40D01D5/06D01F6/18D01F6/38D02J1/22D02G3/00
    • D01F6/18Y10T428/2978Y10T428/298
    • Disclosed is an acrylic fiber composed of an acrylonitrile homopolymer or copolymer whose surface consists of particulate and/or microfibrillar structures having a width of 0.01 to 0.5 .mu.m and a length of 0.05 to 10 .mu.m and fibrillar structures formed by aggregation of the particulate and/or microfibrillar structures and having a width of 0.1 to 10 .mu.m and a length of at least 50 .mu.m. The fiber is prepared by spinning a dope of an acrylonitrile homopolymer or copolymer in a solvent at a draft ratio of at least 5 into a coagulating bath comprising a solvent and a coagulant and having a composition such that a skin layer is not formed on the coagulated fiber; taking up the coagulated fiber from the coagulating bath so that the retention time in the coagulating bath is within 60 seconds; and then drawing the fiber in a drawing bath comprising a solvent and a coagulant and having a coagulating property to the dope and a composition such that a skin layer is not formed on the fiber.
    • 公开了由丙烯腈均聚物或共聚物组成的丙烯酸纤维,其表面由宽度为0.01至0.5μm和长度为0.05至10μm的颗粒和/或微原纤维结构组成,并且通过颗粒和 /或微原纤维结构,宽度为0.1〜10μm,长度为50μm以上。 纤维通过将丙烯腈均聚物或共聚物的涂料在溶剂中以至少5的牵伸比纺丝到包含溶剂和凝结剂的凝结浴中并具有使得在凝固物上不形成表皮层的组合物来制备 纤维; 从凝固浴中吸收凝固纤维,使得凝固浴中的停留时间在60秒以内; 然后在包含溶剂和凝结剂的拉伸浴中将纤维拉伸到涂料上并具有凝胶性的组合物,使得在纤维上不形成表皮层。