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1. 发明申请

US20080021125A1 Emulsion Composition For Silicone Rubber Sponge, Process For Producing The Same, And Process For Producing Silicone Rubber Sponge 有权
标题翻译：硅橡胶海绵乳液组合物及其生产工艺及生产硅橡胶海绵的工艺
公开(公告)号：US20080021125A1
公开(公告)日：2008-01-24
申请号：US10598523
申请日：2004-03-05
申请人： Shinya Shirasaki , Tadanori Fukamachi , Mitsuo Hamada
发明人： Shinya Shirasaki , Tadanori Fukamachi , Mitsuo Hamada
IPC分类号： C08L83/07 , C08J9/28 , C08L83/05
CPC分类号： C08J9/28 , C08G77/12 , C08G77/20 , C08J2201/0504 , C08J2383/04 , C08K3/36 , C08K5/56 , C08L83/04 , C08L83/00 , C08L2666/28 , C08L2666/54
摘要： A silicone rubber sponge emulsion composition comprising (A) (a) a liquid diorganopolysiloxane having at least two alkenyl groups per molecule, or a paste-like mixture of (a) a liquid diorganopolysiloxane having at least two alkenyl groups per molecule and (d) a reinforcing filler, (b) an organopolysiloxane having at least two silicon-bonded hydrogen atoms per molecule, and (c) a platinum catalyst, (B) an aqueous solution of a water-soluble polymer, and (C) an emulsifying agent; its production; and production of silicone rubber sponge, wherein silicone rubber sponge is obtained by curing the composition into a molding and heating the molding.
摘要翻译：一种硅橡胶海绵乳液组合物，其包含（a）（a）每分子具有至少两个烯基的液体二有机聚硅氧烷或（a）每分子具有至少两个烯基的液体二有机聚硅氧烷的糊状混合物，（d）增强填料，（b）每分子具有至少两个与硅键合的氢原子的有机聚硅氧烷，（c）铂催化剂，（B）水溶性聚合物的水溶液和（C）乳化剂; 其生产; 和硅橡胶海绵的制造，其中通过将组合物固化成模并获得模制品而获得硅橡胶海绵。

2. 发明授权

US07732519B2 Emulsion composition for silicone rubber, process for producing the same, and process for producing silicone rubber 有权
标题翻译：硅橡胶用乳液组合物及其制造方法以及硅橡胶的制造方法
公开(公告)号：US07732519B2
公开(公告)日：2010-06-08
申请号：US12536702
申请日：2009-08-06
申请人： Shinya Shirasaki , Tadanori Fukamachi , Mitsuo Hamada
发明人： Shinya Shirasaki , Tadanori Fukamachi , Mitsuo Hamada
IPC分类号： C08K3/34 , C08G77/04 , C08G77/12
CPC分类号： C08J3/03 , C08G77/06 , C08G77/12 , C08G77/20 , C08J2383/04 , C08L83/04 , C08L83/00 , C08L2666/54
摘要： A silicone rubber emulsion composition comprising (A) 100 parts diorganopolysiloxane having at least two silicon-bonded alkenyl groups, (E) 0 to 60 parts reinforcing silica filler, (B) 10 to 250 parts water containing a smectite clay, (C) 0.1 to 15 parts emulsifier, and (D) a cross-linking agent (e.g., an organohydrogenpolysiloxane) in an amount sufficient for cross-linking component (A) and a catalyst (e.g., a platinum-type catalyst). A method for preparing the aforementioned emulsion composition comprising mixing components (A) and (E) with other components in a high-speed stirrer-equipped mixer. A method of manufacturing a silicone rubber comprising either heating and dehydrating the aforementioned emulsion composition.
摘要翻译：一种硅橡胶乳液组合物，其包含（A）100份具有至少两个与硅键合的烯基的二有机聚硅氧烷，（E）0至60份增强二氧化硅填料，（B）10至250份含有蒙脱石粘土的水，（C）0.1 至（15）份的乳化剂和（D）交联剂（例如，有机氢聚硅氧烷），其量足以使交联组分（A）和催化剂（例如，铂型催化剂）。一种制备上述乳液组合物的方法，包括在具有高速搅拌器的混合器中将组分（A）和（E）与其它组分混合。包括加热和脱水上述乳液组合物的硅橡胶的制造方法。

3. 发明申请

US20090292056A1 Emulsion Composition For Silicone Rubber, Process For Producing The Same, And Process For Producing Silicone Rubber 有权
标题翻译：硅橡胶的乳液组合物，其生产方法和生产硅橡胶的方法
公开(公告)号：US20090292056A1
公开(公告)日：2009-11-26
申请号：US12536702
申请日：2009-08-06
申请人： Shinya Shirasaki , Tadanori Fukamachi , Mitsuo Hamada
发明人： Shinya Shirasaki , Tadanori Fukamachi , Mitsuo Hamada
IPC分类号： C08K3/34
CPC分类号： C08J3/03 , C08G77/06 , C08G77/12 , C08G77/20 , C08J2383/04 , C08L83/04 , C08L83/00 , C08L2666/54
摘要： A silicone rubber emulsion composition comprising (A) 100 parts diorganopolysiloxane having at least two silicon-bonded alkenyl groups, (E) 0 to 60 parts reinforcing silica filler, (B) 10 to 250 parts water containing a smectite clay, (C) 0.1 to 15 parts emulsifier, and (D) a cross-linking agent (e.g., an organohydrogenpolysiloxane) in an amount sufficient for cross-linking component (A) and a catalyst (e.g., a platinum-type catalyst). A method for preparing the aforementioned emulsion composition comprising mixing components (A) and (E) with other components in a high-speed stirrer-equipped mixer. A method of manufacturing a silicone rubber comprising either heating and dehydrating the aforementioned emulsion composition.
摘要翻译：一种硅橡胶乳液组合物，其包含（A）100份具有至少两个与硅键合的烯基的二有机聚硅氧烷，（E）0至60份增强二氧化硅填料，（B）10至250份含有蒙脱石粘土的水，（C）0.1 至（15）份的乳化剂和（D）交联剂（例如，有机氢聚硅氧烷），其量足以使交联组分（A）和催化剂（例如铂型催化剂）。一种制备上述乳液组合物的方法，包括在具有高速搅拌器的混合器中将组分（A）和（E）与其它组分混合。包括加热和脱水上述乳液组合物的硅橡胶的制造方法。

4. 发明授权

US08227520B2 Emulsion composition for silicone rubber sponge, process for producing the same, and process for producing silicone rubber sponge 有权
标题翻译：硅橡胶海绵的乳液组合物及其制造方法，以及生产硅橡胶海绵的方法
公开(公告)号：US08227520B2
公开(公告)日：2012-07-24
申请号：US10598523
申请日：2004-03-05
申请人： Shinya Shirasaki , Tadanori Fukamachi , Mitsuo Hamada
发明人： Shinya Shirasaki , Tadanori Fukamachi , Mitsuo Hamada
IPC分类号： C08J9/00
CPC分类号： C08J9/28 , C08G77/12 , C08G77/20 , C08J2201/0504 , C08J2383/04 , C08K3/36 , C08K5/56 , C08L83/04 , C08L83/00 , C08L2666/28 , C08L2666/54
摘要： A silicone rubber sponge emulsion composition comprising (A) (a) a liquid diorganopolysiloxane having at least two alkenyl groups per molecule, or a paste-like mixture of (a) a liquid diorganopolysiloxane having at least two alkenyl groups per molecule and (d) a reinforcing filler, (b) an organopolysiloxane having at least two silicon-bonded hydrogen atoms per molecule, and (c) a platinum catalyst, (B) an aqueous solution of a water-soluble polymer, and (C) an emulsifying agent; its production; and production of silicone rubber sponge, wherein silicone rubber sponge is obtained by curing the composition into a molding and heating the molding.
摘要翻译：一种硅橡胶海绵乳液组合物，其包含（a）（a）每分子具有至少两个烯基的液体二有机聚硅氧烷或（a）每分子具有至少两个烯基的液体二有机聚硅氧烷的糊状混合物，（d）增强填料，（b）每分子具有至少两个与硅键合的氢原子的有机聚硅氧烷，（c）铂催化剂，（B）水溶性聚合物的水溶液和（C）乳化剂; 其生产; 和硅橡胶海绵的制造，其中通过将组合物固化成模并获得模制品而获得硅橡胶海绵。

5. 发明授权

US07687563B2 Emulsion composition for silicone rubber, process for producing the same, and process for producing silicone rubber 有权
公开(公告)号：US07687563B2
公开(公告)日：2010-03-30
申请号：US10558167
申请日：2004-05-21
申请人： Shinya Shirasaki , Tadanori Fukamachi , Mitsuo Hamada
发明人： Shinya Shirasaki , Tadanori Fukamachi , Mitsuo Hamada
IPC分类号： D21H19/58
CPC分类号： C08J3/03 , C08G77/06 , C08G77/12 , C08G77/20 , C08J2383/04 , C08L83/04 , C08L83/00 , C08L2666/54
摘要： A silicone rubber emulsion composition comprising (A) 100 parts diorganopolysiloxane having at least two silicon-bonded alkenyl groups, (E) 0 to 60 parts reinforcing silica filler, (B) 10 to 250 parts water containing a smectite clay, (C) 0.1 to 15 parts emulsifier, and (D) a cross-linking agent (e.g., an organohydrogenpolysiloxane) in an amount sufficient for cross-linking component (A) and a catalyst (e.g., a platinum-type catalyst). A method for preparing the aforementioned emulsion composition comprising mixing components (A) and (E) with other components in a high-speed stirrer-equipped mixer. A method of manufacturing a silicone rubber comprising either heating and dehydrating the aforementioned emulsion composition.

6. 发明申请

US20070123628A1 Emulsion composition for silicone rubber, process for producing the same, and process for producing silicone rubber 有权
标题翻译：硅橡胶用乳液组合物及其制造方法以及硅橡胶的制造方法
公开(公告)号：US20070123628A1
公开(公告)日：2007-05-31
申请号：US10558167
申请日：2004-05-21
申请人： Shinya Shirasaki , Tadanori Fukamachi , Mitsuo Hamada
发明人： Shinya Shirasaki , Tadanori Fukamachi , Mitsuo Hamada
IPC分类号： C08K9/04 , B60C1/00
CPC分类号： C08J3/03 , C08G77/06 , C08G77/12 , C08G77/20 , C08J2383/04 , C08L83/04 , C08L83/00 , C08L2666/54
摘要： A silicone rubber emulsion composition comprising (A) 100 parts diorganopolysiloxane having at least two silicon-bonded alkenyl groups, (E) 0 to 60 parts reinforcing silica filler, (B) 10 to 250 parts water containing a smectite clay, (C) 0.1 to 15 parts emulsifier, and (D) a cross-linking agent (e.g., an organohydrogenpolysiloxane) in an amount sufficient for cross-linking component (A) and a catalyst (e.g., a platinum-type catalyst). A method for preparing the aforementioned emulsion composition comprising mixing components (A) and (E) with other components in a high-speed stirrer-equipped mixer. A method of manufacturing a silicone rubber comprising either heating and dehydrating the aforementioned emulsion composition.
摘要翻译：一种硅橡胶乳液组合物，其包含（A）100份具有至少两个与硅键合的烯基的二有机聚硅氧烷，（E）0至60份增强二氧化硅填料，（B）10至250份含有蒙脱石粘土的水，（C）0.1 至（15）份的乳化剂和（D）交联剂（例如，有机氢聚硅氧烷），其量足以使交联组分（A）和催化剂（例如，铂型催化剂）。一种制备上述乳液组合物的方法，包括在具有高速搅拌器的混合器中将组分（A）和（E）与其它组分混合。包括加热和脱水上述乳液组合物的硅橡胶的制造方法。

7. 发明申请

US20110319510A1 Silicone Rubber Sponge-Forming Emulsion Composition And Method For Manufacturing Silicone Rubber Sponge 审中-公开
标题翻译：硅橡胶海绵成型乳液组合物及制造硅橡胶海绵的方法
公开(公告)号：US20110319510A1
公开(公告)日：2011-12-29
申请号：US13141789
申请日：2009-12-24
申请人： Kota Tsuchiyama , Shinya Shirasaki , Mitsuo Hamada
发明人： Kota Tsuchiyama , Shinya Shirasaki , Mitsuo Hamada
IPC分类号： C08L47/00 , C08J9/00 , C08K13/02
CPC分类号： C08G77/04 , C08G77/12 , C08G77/20 , C08J9/0023 , C08J9/0066 , C08J9/28 , C08J2201/0504 , C08J2383/04 , C08K3/36 , C08K5/10 , C08L83/00 , C08L83/04
摘要： A silicone rubber sponge-forming emulsion composition is provided that, even when the quantity of reinforcing silica filler is increased, does not exhibit a decline in emulsion stability, avoids defects in cell morphology of the sponge, and avoids a substantial increase in hardness of the sponge. A method of producing a silicone rubber sponge from this composition is also provided. The A silicone rubber sponge-forming emulsion composition comprises (A) 100 weight parts of a liquid diorganopolysiloxane that has at least two silicon-bonded alkenyl groups in each molecule, (B) 1 to 50 weight parts of a reinforcing silica filler comprising (b1) a fumed silica and (b2) a precipitated silica in a (b1)/(b2) weight ratio of 0.01/1 to 30/1, (C) 50 to 250 weight parts of water that contains (c) a smectite clay, (D) 0.1 to 7 weight parts of a sorbitan fatty acid ester, (E) 0 to 10 weight parts of an isononanoic acid ester, (F) 0 to 10 weight parts of a Guerbet alcohol, and (G) a curing agent in a quantity sufficient to crosslink and cure component (A).
摘要翻译：提供了一种硅橡胶海绵形成用乳液组合物，即使增加二氧化硅填料的量增加，也不会使乳液稳定性下降，避免海绵细胞形态的缺陷，避免了硬度的显着增加海绵。还提供了从该组合物制备硅橡胶海绵的方法。 A型硅橡胶海绵形成用乳液组合物包含（A）100重量份在每个分子中具有至少两个硅键合的烯基的液体二有机聚硅氧烷，（B）1至50重量份的增强二氧化硅填料，其包含（b1 ）煅烧二氧化硅和（b2）（b1）/（b2）重量比为0.01 / 1〜30/1的沉淀二氧化硅，（C）50〜250重量份含有（c）蒙脱石粘土的水，（D）0.1〜7重量份脱水山梨糖醇脂肪酸酯，（E）0〜10重量份的异壬酸酯，（F）0〜10重量份的格伯特醇，（G）足以使组分（A）交联和固化的量。

8. 发明授权

US07683125B2 Method for producing silicone rubber, aqueous emulsion for silicone rubber, and method for producing same 有权
标题翻译：硅橡胶的制造方法，硅橡胶的水性乳液及其制造方法
公开(公告)号：US07683125B2
公开(公告)日：2010-03-23
申请号：US10546746
申请日：2004-02-24
申请人： Shinya Shirasaki , Tadanori Fukamachi , Mitsuo Hamada
发明人： Shinya Shirasaki , Tadanori Fukamachi , Mitsuo Hamada
IPC分类号： D21H19/32
CPC分类号： C08J3/03 , C08J3/20 , C08J2383/04
摘要： A method of manufacturing a silicone rubber comprises a first stage and a second stage. The first stage comprises (1-1) the step of preparing an aqueous dispersion composed of water that contains a water-soluble polymer (E), a finely powdered silica filler (B), a conductive filler (C), and a non-conductive inorganic filler (D) and (1-2) the step of preparing an aqueous emulsion by stirring and mixing the obtained aqueous dispersion with the following components: an organopolysiloxane (A) that contains silicon-bonded alkenyl groups, an emulsification agent (F), and a curing agent (G). The second stage obtains the silicon rubber either (2-1) by curing the aqueous emulsion prepared in the aforementioned first stage, forming a wet silicone-rubber like cured body, and then removing water from the aforementioned wet silicone-rubber like cured body; or (2-2) by dehydrating and curing the aqueous emulsion prepared in the aforementioned first stage.
摘要翻译：制造硅橡胶的方法包括第一阶段和第二阶段。第一阶段包括（1-1）制备含有水溶性聚合物（E），细粉状二氧化硅填料（B），导电填料（C）和非水溶性聚合物（E）的水组成的水性分散体的步骤，导电无机填料（D）和（1-2）通过将得到的水性分散体与以下成分搅拌混合来制备水性乳液的步骤：含有硅键合的烯基的有机聚硅氧烷（A），乳化剂（F ）和固化剂（G）。第二阶段通过固化上述第一阶段制备的水性乳液得到硅橡胶（2-1），形成湿硅橡胶状固化体，然后从上述湿硅橡胶状固化体中除去水分; 或（2-2）通过使在上述第一阶段中制备的水性乳液脱水和固化。

9. 发明申请

US20070015868A1 Method for producing silicone rubber, aqueous emulsion for silicone rubber, and method for producing same 有权
标题翻译：硅橡胶的制造方法，硅橡胶的水性乳液及其制造方法
公开(公告)号：US20070015868A1
公开(公告)日：2007-01-18
申请号：US10546746
申请日：2004-02-24
申请人： Shinya Shirasaki , Tadanori Fukamachi , Mitsuo Hamada
发明人： Shinya Shirasaki , Tadanori Fukamachi , Mitsuo Hamada
IPC分类号： C08G77/06 , C08L83/04
CPC分类号： C08J3/03 , C08J3/20 , C08J2383/04
摘要： A method of manufacturing a silicone rubber comprises a first stage and a second stage. The first stage comprises (1-1) the step of preparing an aqueous dispersion composed of water that contains a water-soluble polymer (E), a finely powdered silica filler (B), a conductive filler (C), and a non-conductive inorganic filler (D) and (1-2) the step of preparing an aqueous emulsion by stirring and mixing the obtained aqueous dispersion with the following components: an organopolysiloxane (A) that contains silicon-bonded alkenyl groups, an emulsification agent (F), and a curing agent (G). The second stage obtains the silicon rubber either (2-1) by curing the aqueous emulsion prepared in the aforementioned first stage, forming a wet silicone-rubber like cured body, and then removing water from the aforementioned wet silicone-rubber like cured body; or (2-2) by dehydrating and curing the aqueous emulsion prepared in the aforementioned first stage.
摘要翻译：制造硅橡胶的方法包括第一阶段和第二阶段。第一阶段包括（1-1）制备含有水溶性聚合物（E），细粉状二氧化硅填料（B），导电填料（C）和非水溶性聚合物（E）的水组成的水性分散体的步骤，导电无机填料（D）和（1-2）通过将得到的水性分散体与以下成分搅拌混合来制备水性乳液的步骤：含有硅键合的烯基的有机聚硅氧烷（A），乳化剂（F ）和固化剂（G）。第二阶段通过固化上述第一阶段制备的水性乳液得到硅橡胶（2-1），形成湿硅橡胶状固化体，然后从上述湿硅橡胶状固化体中除去水分; 或（2-2）通过使在上述第一阶段中制备的水性乳液脱水和固化。

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