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    • 1. 发明授权
    • Coating film-forming method
    • 涂膜成型方法
    • US06582575B2
    • 2003-06-24
    • US09934565
    • 2001-08-23
    • Shinji MiyatakeAkira TominagaHidehiko Haneishi
    • Shinji MiyatakeAkira TominagaHidehiko Haneishi
    • C25D1312
    • B05D7/577B05D5/068B05D7/587
    • A coating film-forming method that includes a first step that involves coating a cationic electrodeposition coating composition (A) containing an electrically conducting agent, followed by washing with water and heat curing and drying to form a cured cationic electrodeposition coating film. A second step that involves coating such an anionic electrodeposition coating composition (B). The coating film formed therefrom has a chromatic color or a white color as an achromatic color onto the cured cationic electrodeposition coating film. This is followed by washing with water, and removing water by preheating or air blowing to form a non-cured anionic electrodeposition coating film. A third step that involves coating a topcoating composition (C) thereonto to form a non-cured topcoating film, and heat curing and drying a resulting laminated coating film simultaneously.
    • 一种涂膜形成方法,其包括第一步骤,其包括涂布含有导电剂的阳离子电沉积涂料组合物(A),然后用水洗涤并热固化和干燥以形成固化的阳离子电沉积涂膜。 涉及涂覆这种阴离子电沉积涂料组合物(B)的第二步。 由此形成的涂膜在固化的阳离子电沉积涂膜上具有作为无色的彩色或白色。 然后用水洗涤,并通过预热或吹风除去水以形成未固化的阴离子电沉积涂膜。 包括在其上涂覆表面涂层组合物(C)以形成未固化的表面涂层的第三步骤,并且同时热固化和干燥所得层压涂膜。
    • 3. 发明授权
    • Cationic electrodeposition coating composition
    • 阳离子电沉积涂料组合物
    • US06333367B1
    • 2001-12-25
    • US09549717
    • 2000-04-14
    • Akiko KatoShigeo NishiguchiReijiro NishidaShinji MiyatakeHidehiko Haneishi
    • Akiko KatoShigeo NishiguchiReijiro NishidaShinji MiyatakeHidehiko Haneishi
    • C08K320
    • C09D5/4473C08G18/4063C08G18/8077
    • A cationic electrodeposition coating composition containing (A) an acrylic resin obtained by subjecting a mixture of 10 to 60% by weight of a hydroxyl group-containing acrylic monomer (a), 5 to 35% by weight of an amino group-containing acrylic monomer (b), 5 to 55% by weight of an aromatic vinyl monomer (c) and optionally another acrylic monomer (d) to a radical copolymerization reaction; (B) a hydroxyl group-containing acrylic resin-modified epoxy resin obtained by reacting 65 to 95% by weight of a resin composition consisting of 10 to 90% by weight of an epoxy resin (e) and 90 to 10% by weight of a hydroxyl group-containing acrylic resin (f) with 5 to 35% by weight of an amine compound (g); (C) a aliphatic and/or alicyclic blocked polyisocyanate compound, and (D) a bismuth compound component, a mixing ratio of the components (A), (B) and (C) being such that the component (A) is in the range of 40 to 90% by weight, the component (B) is in the range of 5 to 55% by weight and the component (C) is in the range of 5 to 40% by weight based on a total weight of solid contents in the components (A), (B) and (C), the component (D) being contained in such an amount as to be in the range of 0.01 to 10 parts by weight as a bismuth content per 100 parts by weight of a resin solid content in the electrodeposition coating composition.
    • 一种阳离子电沉积涂料组合物,其包含(A)通过将10至60重量%的含羟基的丙烯酸单体(a),5至35重量%的含氨基的丙烯酸单体 (b),5〜55重量%的芳族乙烯基单体(c)和任选的另一种丙烯酸单体(d)进行自由基共聚反应; (B)通过使65〜95重量%的由10〜90重量%的环氧树脂(e)和90〜10重量%的环氧树脂(e)组成的树脂组合物反应得到的含羟基的丙烯酸树脂改性环氧树脂, 含有5〜35重量%的胺化合物(g)的含羟基的丙烯酸树脂(f) (C)脂肪族和/或脂环族封端多异氰酸酯化合物,(D)铋化合物成分,成分(A),(B)和(C)的混合比例使成分(A)成分 范围为40〜90重量%,成分(B)为5〜55重量%,成分(C)为固体成分总重量的5〜40重量% 在组分(A),(B)和(C)中,组分(D)的含量为每100重量份的铋含量为0.01至10重量份 电沉积涂料组合物中的树脂固体含量。