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    • 1. 发明授权
    • Method for optimization of process by adjustment of initiator in polymerization system
    • 通过调节聚合体系中引发剂优化工艺的方法
    • US07786228B2
    • 2010-08-31
    • US11655150
    • 2007-01-19
    • Hokyung LeeSujin LeeSeungyoung ParkJongku Lee
    • Hokyung LeeSujin LeeSeungyoung ParkJongku Lee
    • C08F2/00B01J19/00
    • B01J19/0013B01J2219/0006B01J2219/00094B01J2219/00101B01J2219/00186B01J2219/00204B01J2219/00216B01J2219/00231C08F10/00C08F2400/02C08F2/00
    • Disclosed herein is an optimization method in a polymerization system in which heat is generated during the polymerization with an initiator. The optimization method includes the steps of measuring the heat generation amount based on the composition of the initiator in the polymerization system to previously set the relationship between the initiator composition and the heat generation amount, measuring the heat removal amount based on the temperature of a coolant in a cooling system of the polymerization system to previously set the relationship between the coolant temperature and the heat removal amount, calculating the initiator composition allowable at a predetermined coolant temperature to previously set the relationship between the coolant temperature and the initiator composition, and measuring the temperature of the coolant before and/or during the polymerization to adjust the composition of the initiator added at the measured temperature to the optimum condition, thereby decreasing the reaction time, and therefore, improving the productivity.
    • 本文公开了在与引发剂聚合期间产生热量的聚合体系中的优化方法。 优化方法包括以下步骤:基于聚合体系中引发剂的组成来测定发热量,以预先设定引发剂组合物与发热量之间的关系,基于冷却剂的温度测量除热量 在聚合系统的冷却系统中,预先设定冷却剂温度和除热量之间的关系,计算在预定冷却剂温度下允许的引发剂组合物,以预先设定冷却剂温度和引发剂组合物之间的关系,并测量 在聚合之前和/或聚合期间冷却剂的温度将调节在测量温度下加入的引发剂的组成调节到最佳条件,由此减少反应时间,从而提高生产率。