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    • 3. 发明申请
    • Antifreeze Concentrate, Coolant Composition, and Preparation Thereof
    • 防冻浓缩物,冷却剂组合物及其制备方法
    • US20110006250A1
    • 2011-01-13
    • US12852847
    • 2010-08-09
    • Serge S. LievensJurgen P. DeKimpe
    • Serge S. LievensJurgen P. DeKimpe
    • C09K5/00
    • C09K5/20C23F11/08C23F11/10C23F11/124C23F11/126
    • An antifreeze composition having improved thermal stability is provided. In one embodiment, the antifreeze concentrate composition comprises from 50 to 99.8 wt. % of a glycol-based freezing point depressant selected from the group of: alkylene glycols, glycol monoethers, glycerins, and mixtures thereof; 0.01 to 10 wt. % of at least one of a 2-ethylhexanoic acid, isononanoic acid and 3,5,5-trimethylhexanoic acid; and 0.01 to 5 wt. % of at least one of octanoic acid, nonanoic acid, decanoic acid, undecanoic acid, dodecanoic acid, neodecanoic acid, benzoic acid, 2-hydroxybenzoic acid, p-terbutylbenzoic acid, and mixtures thereof. In one embodiment, the composition is employed as a concentrate in admixture with 10 to 90 wt. % water. In one embodiment no more than one dicarboxylic acid is used as an additive. In another embodiment no dicarboxylic acid is present.
    • 提供了具有改善的热稳定性的防冻剂组合物。 在一个实施方案中,防冻浓缩物组合物包含50至99.8wt。 %的基于二醇的凝固点抑制剂,选自:亚烷基二醇,二醇单醚,甘油及其混合物; 0.01〜10重量% %的2-乙基己酸,异壬酸和3,5,5-三甲基己酸中的至少一种; 和0.01〜5wt。 辛酸,壬酸,癸酸,十一烷酸,十二烷酸,新癸酸,苯甲酸,2-羟基苯甲酸,对叔丁基苯甲酸及其混合物中的至少一种的%。 在一个实施方案中,将组合物作为浓缩物与10至90wt。 % 水。 在一个实施方案中,不超过一个二羧酸用作添加剂。 在另一个实施方案中,不存在二羧酸。
    • 4. 发明授权
    • Antifreeze concentrate and coolant compositions and preparation thereof
    • 防冻浓缩物和冷却剂组合物及其制备
    • US07790054B2
    • 2010-09-07
    • US11769943
    • 2007-06-28
    • Serge S. LievensJurgen P. DeKimpe
    • Serge S. LievensJurgen P. DeKimpe
    • C09K5/00
    • C23F11/124C09K5/20C23F11/08C23F11/10C23F11/126
    • An antifreeze composition having improved thermal stability is provided. In one embodiment, the antifreeze concentrate composition comprises from 50 to 99 wt. % of a glycol-based freezing point depressant selected from the group of: alkylene glycols, glycol monoethers, glycerins, and mixtures thereof; 0.01 to 10 wt. % of at least one of a 2-ethylhexanoic acid, isononanoic acid and 3,5,5-trimethylhexanoic acid; and 0.01 to 5 wt. % of at least one of octanoic acid, nonanoic acid, decanoic acid, undecanoic acid, dodecanoic acid, neodecanoic acid, benzoic acid, 2-hydroxybenzoic acid, p-terbutylbenzoic acid, and mixtures thereof. In one embodiment, the composition is employed as a concentrate in admixture with 10 to 90 wt. % water.
    • 提供了具有改善的热稳定性的防冻剂组合物。 在一个实施方案中,防冻浓缩物组合物包含50至99wt。 %的基于二醇的凝固点抑制剂,选自:亚烷基二醇,二醇单醚,甘油及其混合物; 0.01〜10重量% %的2-乙基己酸,异壬酸和3,5,5-三甲基己酸中的至少一种; 和0.01〜5wt。 辛酸,壬酸,癸酸,十一烷酸,十二烷酸,新癸酸,苯甲酸,2-羟基苯甲酸,对叔丁基苯甲酸及其混合物中的至少一种的%。 在一个实施方案中,将组合物作为浓缩物与10至90wt。 % 水。
    • 5. 发明申请
    • Antifreeze Concentrate and Coolant Compositions and Preparation Thereof
    • 防冻精华及冷却液组合物及其制备方法
    • US20090001313A1
    • 2009-01-01
    • US11769960
    • 2007-06-28
    • Serge S. LievensJurgen P. DeKimpe
    • Serge S. LievensJurgen P. DeKimpe
    • C09K3/18
    • A toxicological friendly antifreeze composition having improved thermal stability is provided. In one embodiment, the antifreeze composition comprises from 5 to 80 wt. % of an aqueous freezing point depressant selected from alkali metal salts of acetates, formates, proprionates, adipiates, and succinates, and mixtures thereof; 0.1 to 10 wt. % of at least one of a 2-ethylhexanoic acid, isononanoic acid and 3,5,5-trimethylhexanoic acid; and 0.1 to 10 wt. % of at least one of octanoic acid, nonanoic acid, decanoic acid, undecanoic acid, dodecanoic acid, neodecanoic acid, benzoic acid, 2-hydroxybenzoic acid, p-terbutylbenzoic acid, and mixtures thereof. In one embodiment, the composition is employed as a concentrate in admixture with 10 to 90 wt. % water.
    • 提供了具有改善的热稳定性的毒理学友好的防冻组合物。 在一个实施方案中,防冻组合物包含5-80wt。 %的含水凝固点抑制剂,其选自乙酸盐,甲酸盐,丙酸盐,己二酸盐和琥珀酸盐的碱金属盐,及其混合物; 0.1〜10重量% %的2-乙基己酸,异壬酸和3,5,5-三甲基己酸中的至少一种; 和0.1〜10wt。 辛酸,壬酸,癸酸,十一烷酸,十二烷酸,新癸酸,苯甲酸,2-羟基苯甲酸,对叔丁基苯甲酸及其混合物中的至少一种的%。 在一个实施方案中,将组合物作为浓缩物与10至90wt。 % 水。
    • 8. 发明授权
    • Antifreeze concentrate and coolant compositions and preparation thereof
    • 防冻浓缩物和冷却剂组合物及其制备
    • US08057695B2
    • 2011-11-15
    • US12868920
    • 2010-08-26
    • Serge S. LievensJurgen P. De Kimpe
    • Serge S. LievensJurgen P. De Kimpe
    • C09K5/00
    • C09K5/20C09K3/185C23F11/08C23F11/124C23F11/126
    • A toxicological friendly antifreeze composition having improved thermal stability is provided. In one embodiment, the antifreeze composition comprises from 5 to 80 wt. % of an aqueous freezing point depressant selected from alkali metal salts of acetates, formates, proprionates, adipiates, and succinates, and mixtures thereof; 0.1 to 10 wt. % of at least one of a 2-ethylhexanoic acid, isononanoic acid and 3,5,5-trimethylhexanoic acid; and 0.1 to 10 wt. % of at least one of octanoic acid, nonanoic acid, decanoic acid, undecanoic acid, dodecanoic acid, neodecanoic acid, benzoic acid, 2-hydroxybenzoic acid, p-terbutylbenzoic acid, and mixtures thereof. In one embodiment, the composition is employed as a concentrate in admixture with 10 to 90 wt. % water. The composition may be totally free of glycol, or, in an alternate embodiment, possess a glycol:non-glycol base ratio of 1:2 to 1:20.
    • 提供了具有改善的热稳定性的毒理学友好的防冻组合物。 在一个实施方案中,防冻组合物包含5-80wt。 %的含水凝固点抑制剂,其选自乙酸盐,甲酸盐,丙酸盐,己二酸盐和琥珀酸盐的碱金属盐,及其混合物; 0.1〜10重量% %的2-乙基己酸,异壬酸和3,5,5-三甲基己酸中的至少一种; 和0.1〜10wt。 辛酸,壬酸,癸酸,十一烷酸,十二烷酸,新癸酸,苯甲酸,2-羟基苯甲酸,对叔丁基苯甲酸及其混合物中的至少一种的%。 在一个实施方案中,将组合物作为浓缩物与10至90wt。 % 水。 组合物可以完全不含二醇,或者在另一个实施方案中,其乙二醇:非乙二醇基比例为1:2至1:20。
    • 9. 发明申请
    • Molybdate-Free Antifreeze Concentrate and Coolant Compositions and Preparation Thereof
    • 不含钼酸盐的防冻剂浓缩物和冷却剂组合物及其制备方法
    • US20100283002A1
    • 2010-11-11
    • US12832810
    • 2010-07-08
    • Serge S. LievensJurgen P. DeKimpe
    • Serge S. LievensJurgen P. DeKimpe
    • C09K5/20
    • C09K5/20C23F11/08C23F11/10C23F11/124C23F11/126
    • A molybdate-free antifreeze composition having improved thermal stability is provided. In one embodiment, the antifreeze concentrate composition comprises from 50 to 99 wt. % of a glycol-based freezing point depressant selected from the group of: alkylene glycols, glycol monoethers, glycerins, and mixtures thereof; 0.01 to 10 wt. % of at least one of a 2-ethylhexanoic acid, isononanoic acid and 3,5,5-trimethylhexanoic acid; and 0.01 to 5 wt. % of at least one of heptanoic acid, octanoic acid, nonanoic acid, decanoic acid, undecanoic acid, dodecanoic acid, neodecanoic acid, 2-hydroxybenzoic acid, p-terbutylbenzoic acid, and mixtures thereof. In one embodiment, the composition is employed as a concentrate in admixture with 10 to 90 wt. % water.
    • 提供了具有改善的热稳定性的不含钼酸盐的防冻组合物。 在一个实施方案中,防冻浓缩物组合物包含50至99wt。 %的基于二醇的凝固点抑制剂,选自:亚烷基二醇,二醇单醚,甘油及其混合物; 0.01〜10重量% %的2-乙基己酸,异壬酸和3,5,5-三甲基己酸中的至少一种; 和0.01〜5wt。 庚酸,辛酸,壬酸,癸酸,十一烷酸,十二烷酸,新癸酸,2-羟基苯甲酸,对叔丁基苯甲酸及其混合物中的至少一种的%。 在一个实施方案中,将组合物作为浓缩物与10至90wt。 % 水。