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1. 发明授权

US5902859A Elastic fluorohydrocarbon resin and method of producing same 失效
标题翻译：弹性氟代烃树脂及其制备方法
公开(公告)号：US5902859A
公开(公告)日：1999-05-11
申请号：US880545
申请日：1997-06-23
申请人： Chikashi Kawashima , Akira Ishihara , Katunori Kawamura , Seiiti Minegishi
发明人： Chikashi Kawashima , Akira Ishihara , Katunori Kawamura , Seiiti Minegishi
IPC分类号： C08F2/00 , C08F259/08 , C08L51/00
CPC分类号： C08L51/00 , C08F259/08
摘要： The invention relates to an elastic fluorohydrocarbon resin. This resin is obtained by graft copolymerization of a first segment which is one of fluorine-containing elastomeric and crystalline polymers with a second segment which is the other of these polymers. The first segment is prepared by copolymerizing at least one first unsaturated monomer that has peroxy bond with at least one second fluorine-containing monomer. When the first monomer is dissolved in a first solvent prior to the copolymerization, the copolymerization can be safely conducted with higher yield. This first solvent is selected from a carboxylic ester of t-butanol, methylene chloride, 1,1,1-trichloroethane, and first, second, third and fourth compounds which are respectively represented by R.sup.1 COOR.sup.2, C.sub.2 H.sub.x Cl.sub.y F.sub.z, C.sub.3 H.sub.x Cl.sub.y F.sub.z, and C.sub.4 H.sub.x Cl.sub.y F.sub.z. When the fluorine-containing elastomeric copolymer as the first segment is purified by contact with a barium salt prior to the graft copolymerization, the elastic fluorohydrocarbon resin becomes improved in thermal stability. When the fluorine-containing elastomeric copolymer having a water content of 0.1-50 wt % as the first segment is dispersed in a liquid medium containing t-butanol and water, it becomes unnecessary to dry this elastomeric copolymer prior to the graft copolymerization. When the fluorine-containing elastomeric copolymer as the first segment is dispersed in another liquid medium containing t-butanol, water, a carboxylic ester and barium hydroxide, the elastic fluorohydrocarbon resin becomes improved in thermal stability with higher graft copolymerization rate.
摘要翻译：本发明涉及弹性氟代烃树脂。该树脂通过作为氟弹性体和结晶聚合物之一的第一链段与作为这些聚合物中的另一个的第二链段的接枝共聚获得。第一段通过使至少一种具有过氧键的第一不饱和单体与至少一种第二含氟单体共聚来制备。当在共聚之前将第一单体溶解在第一溶剂中时，可以更高的收率安全地进行共聚。该第一溶剂选自叔丁醇，二氯甲烷，1,1,1-三氯乙烷的羧酸酯，以及分别由R1COOR2，C2HxClyFz，C3HxClyFz和C4HxClyFz表示的第一，第二，第三和第四化合物。当作为第一段的含氟弹性体共聚物在接枝共聚之前通过与钡盐接触而纯化时，弹性氟代烃树脂的热稳定性提高。当具有0.1-50重量％水含量的含氟弹性体共聚物作为第一链段分散在含有叔丁醇和水的液体介质中时，在接枝共聚之前不需要干燥该弹性体共聚物。当作为第一段的含氟弹性体共聚物分散在含有叔丁醇，水，羧酸酯和氢氧化钡的另一种液体介质中时，弹性氟代烃树脂的热稳定性提高，接枝共聚速率更高。

2. 发明授权

US4748204A Flexible and melt processable fluororesin 失效
标题翻译：柔性和可熔融加工的氟树脂
公开(公告)号：US4748204A
公开(公告)日：1988-05-31
申请号：US906825
申请日：1986-09-12
申请人： Chikashi Kawashima , Seiiti Minegishi , Shinji Ogasawara , Takashi Mukaino
发明人： Chikashi Kawashima , Seiiti Minegishi , Shinji Ogasawara , Takashi Mukaino
IPC分类号： C08L1/00 , C08L23/00 , C08L27/00 , C08L27/12 , C08L27/16 , C08L51/00 , C08L51/02 , C08L51/04 , C08L57/00 , C08L101/00
CPC分类号： C08L27/12 , C08L51/04 , C08L27/16
摘要： A melt-processable fluororesin of wide use is obtained by blending 100 parts by weight of a soft and melt-processable fluorine-containing graft copolymer in which crystalline fluoro-polymer segments are grafted to an elastomeric fluoro-polymer segment and 1-90 parts by weight of a crystalline fluoro-polymer which comprises the structural units of the crystalline fluoro-polymer segments of the graft copolymer. For example, a graft copolymer obtained by graft copolymerization of vinylidene fluoride (VDF) with an elastomeric copolymer of VDF, chlorotrifluoroethylene and an unsaturated peroxy compound is blended with either homopolymer of VDF or a copolymer of VDF and another monomer. By the blending some important characteristics of the graft copolymer such as elastic modulus, hardness and melt flow rate are desirably modified without serious lowering of tensile strength and elongation.
摘要翻译：通过将100重量份的可熔融加工的含氟接枝共聚物（其中结晶氟聚合物链段接枝到弹性体氟聚合物链段上）和1-90份的结晶氟聚合物的重量，其包含接枝共聚物的结晶氟聚合物链段的结构单元。例如，通过将偏二氟乙烯（VDF）与VDF，三氟氯乙烯和不饱和过氧化合物的弹性体共聚物接枝共聚获得的接枝共聚物与VDF的均聚物或VDF的共聚物与其它单体共混。通过混合接枝共聚物的一些重要特性，如弹性模量，硬度和熔体流动速率，而不会严重降低拉伸强度和伸长率。

3. 发明授权

US5898051A Elastic fluorohydrocarbon resin-based polymer blend with graft copolymers of rubbers 失效
标题翻译：弹性氟代烃树脂基聚合物共混物与橡胶的接枝共聚物
公开(公告)号：US5898051A
公开(公告)日：1999-04-27
申请号：US594208
申请日：1996-01-31
申请人： Chikashi Kawashima , Fumiyoshi Yoshikawa , Seiiti Minegishi
发明人： Chikashi Kawashima , Fumiyoshi Yoshikawa , Seiiti Minegishi
IPC分类号： C08L27/16 , C08L51/04 , C08L27/12 , C08L51/00
CPC分类号： C08L27/16 , C08L51/04
摘要： The invention provides a fluorine-containing resin blend. This resin blend includes 100 parts by weight of a first resin and 1-50 parts by weight of a second resin. The first resin is one of an elastic fluorohydrocarbon resin and a vinylidene fluoride based resin. The second resin is a graft copolymer prepared by graft copolymerization of a rubber-like polymer with a first monomer and an optional second monomer. The first monomer is at least one of an acrylic ester and a methacrylic acid ester. The optional second monomer is at least one copolymerizable monomer other than the first monomer. When the elastic fluorohydrocarbon resin is used as the first resin, the resin blend is improved in extensibility upon molding in a melted condition and lowered in modulus of elasticity under a condition that the resin blend is strained by up to 20%, without impairing the elastic fluorohydrocarbon in its heat resistance, low-temperature characteristics and the like. When the vinylidene fluoride based resin is used as the first resin, the resin blend is improved in mechanical strength at low temperature, without impairing superior characteristics of the vinylidene fluoride based resin.
摘要翻译：本发明提供含氟树脂共混物。该树脂共混物包括100重量份的第一树脂和1-50重量份的第二树脂。第一树脂是弹性氟代烃树脂和偏二氟乙烯类树脂之一。第二树脂是通过橡胶状聚合物与第一单体和任选的第二单体的接枝共聚制备的接枝共聚物。第一单体是丙烯酸酯和甲基丙烯酸酯中的至少一种。任选的第二单体是除第一单体之外的至少一种可共聚单体。当弹性氟代烃树脂用作第一树脂时，树脂共混物在熔融条件下成型时的延展性提高，并且在树脂共混物应变达20％的条件下降低弹性模量，而不损害弹性氟代烃的耐热性，低温特性等。当使用偏二氟乙烯基树脂作为第一树脂时，树脂共混物在低温下的机械强度提高，而不损害偏二氟乙烯类树脂的优异特性。

4. 发明授权

US5795654A Adhesive for bonding together polyvinylidene fluoride resin and substrate 失效
标题翻译：用于将聚偏二氟乙烯树脂和基材粘合在一起的粘合剂
公开(公告)号：US5795654A
公开(公告)日：1998-08-18
申请号：US760080
申请日：1996-12-04
申请人： Toshio Koishi , Katsunori Kawamura , Seiiti Minegishi
发明人： Toshio Koishi , Katsunori Kawamura , Seiiti Minegishi
IPC分类号： C09J127/16 , C08L27/12 , C08L33/06 , C09J127/12 , C09J133/04 , C09J133/08 , C09J151/00 , C09J151/06 , C09J175/00 , C09J175/04
CPC分类号： C09J127/12 , C09J151/003 , C08L2205/02 , C08L27/12 , C08L33/06 , Y10T428/3154
摘要： The invention provides an adhesive for bonding together a first substrate made of a polyvinylidene fluoride resin and a second substrate. This adhesive includes an elastic fluorohydrocarbon resin, an acrylic resin, a polyvinylidene fluoride resin, a polyisocyanate, and an organic solvent. This elastic fluorohydrocarbon resin is obtained by graft copolymerization of a fluorine-containing copolymer with a vinylidene fluoride monomer. This copolymer is prepared by copolymerizing at least one first fluorine-containing monomer with at least one unsaturated monomer that has peroxy bond. The adhesive itself is superior in durability, and bond strength between the first and second substrates is also superior.
摘要翻译：本发明提供一种用于将由聚偏二氟乙烯树脂和第二基材制成的第一基材粘合在一起的粘合剂。该粘合剂包括弹性氟代烃树脂，丙烯酸树脂，聚偏二氟乙烯树脂，多异氰酸酯和有机溶剂。该弹性氟代烃树脂通过含氟共聚物与偏二氟乙烯单体的接枝共聚获得。该共聚物通过使至少一种第一含氟单体与至少一种具有过氧键的不饱和单体共聚来制备。粘合剂本身的耐久性优异，第一和第二基板之间的粘结强度也优异。

5. 发明授权

US5696215A Elastic fluorohydrocarbon resin and method of producing same 失效
标题翻译：弹性氟代烃树脂及其制备方法
公开(公告)号：US5696215A
公开(公告)日：1997-12-09
申请号：US608354
申请日：1996-02-28
申请人： Chikashi Kawashima , Akira Ishihara , Katunori Kawamura , Seiiti Minegishi
发明人： Chikashi Kawashima , Akira Ishihara , Katunori Kawamura , Seiiti Minegishi
IPC分类号： C08F2/00 , C08F259/08 , C08L51/00 , C08F259/00
CPC分类号： C08L51/00 , C08F259/08
摘要： The invention relates to an elastic fluorohydrocarbon resin. This resin is obtained by graft copolymerization of a first segment which is one of fluorine-containing elastomeric and crystalline polymers with a second segment which is the other of these polymers. The first segment is prepared by copolymerizing at least one first unsaturated monomer that has peroxy bond with at least one second fluorine-containing monomer. When the first monomer is dissolved in a first solvent prior to the copolymerization, the copolymerization can be safely conducted with higher yield. This first solvent is selected from a carboxylic ester of t-butanol, methylene chloride, 1,1,1-trichloroethane, and first, second, third and fourth compounds which are respectively represented by R.sup.1 COOR.sup.2, C.sub.2 H.sub.x Cl.sub.y F.sub.z, C.sub.3 H.sub.x Cl.sub.y F.sub.z, and C.sub.4 H.sub.x Cl.sub.y F.sub.z. When the fluorine-containing elastomeric copolymer as the first segment is purified by contact with a barium salt prior to the graft copolymerization, the elastic fluorohydrocarbon resin becomes improved in thermal stability. When the fluorine-containing elastomeric copolymer having a water content of 0.1-50 wt % as the first segment is dispersed in a liquid medium containing t-butanol and water, it becomes unnecessary to dry this elastomeric copolymer prior to the graft copolymerization. When the fluorine-containing elastomeric copolymer as the first segment is dispersed in another liquid medium containing t-butanol, water, a carboxylic ester and barium hydroxide, the elastic fluorohydrocarbon resin becomes improved in thermal stability with higher graft copolymerization rate.
摘要翻译：本发明涉及弹性氟代烃树脂。该树脂通过作为氟弹性体和结晶聚合物之一的第一链段与作为这些聚合物中的另一个的第二链段的接枝共聚获得。第一段通过使至少一种具有过氧键的第一不饱和单体与至少一种第二含氟单体共聚来制备。当在共聚之前将第一单体溶解在第一溶剂中时，可以更高的收率安全地进行共聚。该第一溶剂选自叔丁醇，二氯甲烷，1,1,1-三氯乙烷的羧酸酯，以及分别由R1COOR2，C2HxClyFz，C3HxClyFz和C4HxClyFz表示的第一，第二，第三和第四化合物。当作为第一段的含氟弹性体共聚物在接枝共聚之前通过与钡盐接触而纯化时，弹性氟代烃树脂的热稳定性提高。当具有0.1-50重量％水含量的含氟弹性体共聚物作为第一链段分散在含有叔丁醇和水的液体介质中时，在接枝共聚之前不需要干燥该弹性体共聚物。当作为第一段的含氟弹性体共聚物分散在含有叔丁醇，水，羧酸酯和氢氧化钡的另一种液体介质中时，弹性氟代烃树脂的热稳定性提高，接枝共聚速率更高。

6. 发明授权

US06025436A Thermoplastic fluorine-containing resin composition useful for calendering 失效
标题翻译：用于压延的热塑性含氟树脂组合物
公开(公告)号：US06025436A
公开(公告)日：2000-02-15
申请号：US861711
申请日：1997-05-23
申请人： Chikashi Kawashima , Katunori Kawamura , Seiiti Minegishi
发明人： Chikashi Kawashima , Katunori Kawamura , Seiiti Minegishi
IPC分类号： B29C43/24 , B29K27/12 , C08L23/00 , C08L27/12 , C08L51/00 , C08L27/16 , C08L51/04
CPC分类号： B29C43/24 , C08L27/12 , C08L51/003 , B29K2027/12 , C08L2205/02
摘要： The invention provides a thermoplastic fluorine-containing resin composition intended to be passed between at least two rollers of a calender to be thinned into a sheet or film. This composition includes: 100 parts by weight of a mixture containing 10-90 wt % of a fluorine-containing elastomeric polymer having a glass transition temperature below room temperature and 90-10 wt % of a fluorine-containing crystalline resin having a melting point not higher than 300.degree. C.; and 0.05-2.0 parts by weight of an agent for releasing the composition from the at least two rollers. The composition has a good melt characteristic and a good elasticity for calendering of the composition, and a good releasibility from a calender roller in calendering of the composition.
摘要翻译：本发明提供一种热塑性含氟树脂组合物，其旨在通过压延机的至少两个辊之间被薄化成片或膜。该组合物包括：将100重量份的含有10-90重量％的玻璃化转变温度低于室温的含氟弹性体聚合物和90-10重量％的不熔点的含氟结晶树脂的混合物高于300℃。和0.05-2.0重量份用于从至少两个辊释放组合物的试剂。组合物具有良好的熔体特性和用于压延组合物的良好的弹性，以及在压延组合物时来自砑光辊的良好的剥离性。

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