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    • 4. 发明授权
    • Process for removing oil from solid materials recovered from a well bore
    • 从井眼回收的固体物料中除去油的工艺
    • US06846420B2
    • 2005-01-25
    • US10325762
    • 2002-12-19
    • B. Raghava ReddySears T. DealyIan D. Robb
    • B. Raghava ReddySears T. DealyIan D. Robb
    • C02F1/52C02F1/56E21B43/22
    • E21B21/068
    • The present invention provides a process and an additive package for removing oil from solid material recovered from a well bore, e.g., drill cuttings and produced sand. In this process, the solid material is passed from the well bore to a separation zone. An aqueous acidic solution containing a polymer substituted with an amino group is introduced to the separation zone containing the solid material along with a halogenating agent and optionally one or more surfactants. The polymer, halogenating agent, and optional surfactant constitute the additive package. The polymer substituted with an amino group is preferably chitosan, and the halogenating agent is preferably a sodium hypochlorite solution. The mixture formed in the separation zone is agitated to cause a product of a reaction between the polymer and the halogenating agent to contact the solid material and remove residual oil therefrom.
    • 本发明提供了一种用于从井眼例如钻屑和产生的砂回收的固体材料中除去油的方法和添加剂包。 在这个过程中,固体材料从井眼穿过分离区。 将含有被氨基取代的聚合物的酸性水溶液与卤化剂和任选的一种或多种表面活性剂一起引入含有固体材料的分离区。 聚合物,卤化剂和任选的表面活性剂构成添加剂包装。 被氨基取代的聚合物优选为壳聚糖,卤化剂优选为次氯酸钠溶液。 搅拌分离区中形成的混合物,使聚合物和卤化剂之间的反应产物与固体材料接触并从中除去残留的油。