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1. 发明授权

US08664142B2 Manufacturing method of solid catalyst for propylene polymerization 有权
标题翻译：丙烯聚合固体催化剂的制备方法
公开(公告)号：US08664142B2
公开(公告)日：2014-03-04
申请号：US13514673
申请日：2010-10-01
申请人： Sang Yull Kim , Joon Ryeo Park , Eun Il Kim , Jin Woo Lee
发明人： Sang Yull Kim , Joon Ryeo Park , Eun Il Kim , Jin Woo Lee
IPC分类号： C08F4/16 , C08F110/06 , C08F210/06 , C08F4/649
CPC分类号： C08F110/06 , Y02P20/52 , C08F2500/12 , C08F2500/03 , C08F4/6548 , C08F4/651
摘要： Disclosed is a method for preparing a solid catalyst for propylene polymerization, specifically to a method for preparing a solid catalyst for propylene polymerization which can produce a polypropylene having high melt flow rate, a wide molecular distribution and excellent stereoregularity with a high production yield.
摘要翻译：公开了一种制备用于丙烯聚合的固体催化剂的方法，具体涉及制备用于丙烯聚合的固体催化剂的方法，该方法可以制备具有高熔体流动速率，宽分子量分布和优异的立构规整性并具有高产率的聚丙烯。

2. 发明授权

US08394734B2 Solid catalyst for propylene polymerization and a method for preparation of polypropylene using the same 有权
标题翻译：用于丙烯聚合的固体催化剂及其制备方法
公开(公告)号：US08394734B2
公开(公告)日：2013-03-12
申请号：US13457944
申请日：2012-04-27
申请人： Sang Yull Kim , Jin Woo Lee , Eun Il Kim , Joon Ryeo Park
发明人： Sang Yull Kim , Jin Woo Lee , Eun Il Kim , Joon Ryeo Park
IPC分类号： B01J31/00 , C08F4/02 , C08F4/44 , C08F2/00
CPC分类号： C08F10/00 , C08F110/06 , Y02P20/52 , C08F4/651
摘要： Provided are a solid catalyst for propylene polymerization which includes titanium, magnesium, halogen and an internal electron donor mixture of two or more compounds wherein the internal electron donor mixture includes at least one selected from the bicycloalkanes or bicycloalkenes and at least one selected from diethers and succinates, and a method for preparing propylene using the same. As disclosed, it is possible to prepare polypropylene having an excellent stereoregularity with a high production yield.
摘要翻译：提供了一种用于丙烯聚合的固体催化剂，其包括钛，镁，卤素和两种或更多种化合物的内给电子体混合物，其中内电子给体混合物包括选自双环烷烃或双链烯烃中的至少一种和选自二醚和琥珀酸酯和使用其制备丙烯的方法。如所公开的，可以以高的产率制备具有优异立构规整性的聚丙烯。

3. 发明申请

US20130017946A1 PREPARATION METHOD OF SOLID CATALYST FOR PROPYLENE POLYMERIZATION AND CATALYST PREPARED THEREBY 有权
标题翻译：用于丙烯聚合的固体催化剂的制备方法及其制备的催化剂
公开(公告)号：US20130017946A1
公开(公告)日：2013-01-17
申请号：US13520863
申请日：2010-12-30
申请人： Sang Yull Kim , Jin Woo Lee , Eun Il Kim , Joon Ryeo Park
发明人： Sang Yull Kim , Jin Woo Lee , Eun Il Kim , Joon Ryeo Park
IPC分类号： C08F4/649
CPC分类号： C08F110/06 , C08F10/06 , Y02P20/52 , C08F4/651 , C08F4/6565
摘要： Disclosed are a method for preparing a solid catalyst for propylene polymerization and a catalyst prepared thereby. Specifically, disclosed are a method for preparing a solid catalyst for propylene polymerization which can prepare polypropylene having excellent stereoregularity with a high production yield by using silane compounds and bicycloalkanedicarboxylate or bicycloalkenedicarboxylate as an internal electron donor, and a catalyst prepared thereby method for preparing polypropylene using the same.
摘要翻译：公开了一种制备用于丙烯聚合的固体催化剂的方法和由其制备的催化剂。具体地说，公开了一种制备用于丙烯聚合的固体催化剂的方法，其可以通过使用硅烷化合物和双链烷二羧酸酯或双环烯烃二羧酸酯作为内给电子体，制备具有优异的立构规整性的聚异丁烯，并由此制备用于制备聚丙烯的方法一样。

4. 发明授权

US06958378B2 Method for producing homo-and co-polymers of ethylene 有权
标题翻译：乙烯均聚物和共聚物的制备方法
公开(公告)号：US06958378B2
公开(公告)日：2005-10-25
申请号：US10416382
申请日：2001-11-09
申请人： Chun-Byung Yang , Sang-Yull Kim , Yong-Bok Lee , Weon Lee
发明人： Chun-Byung Yang , Sang-Yull Kim , Yong-Bok Lee , Weon Lee
IPC分类号： C08F4/656 , C08F4/642 , C08F4/658 , C08F10/00 , C08F110/02 , C08F4/42
CPC分类号： C08F10/00 , C08F110/02 , C08F4/6565 , C08F4/651 , C08F4/6495 , C08F2500/12 , C08F2500/18 , C08F2500/03
摘要： The present invention provides a method for producing homo- and co-polymers of ethylene, or more particularly a method for producing homo- and co-polymers of ethylene in the presence of (a) a solid titanium catalyst produced by preparing a magnesium solution by contact-reacting a halogenated magnesium compound with an alcohol; reacting thereto an ester compound having at least one hydroxyl group and a silicon compound having at least one alkoxy group; and adding a mixture of a titanium compound and a silicon compound; (b) organometallic compounds of Group II or III of the Periodic Table; and (c) a cyclic nitrogen compound. The catalyst for homo- and co-polymerization of ethylene, produced according to the present invention, exhibits high activity, and the polymers produced by the method of the present invention by using said catalyst have the advantages of exhibiting high bulk densities and narrow molecular weight distributions.
摘要翻译：本发明提供了一种制备乙烯的均聚物和共聚物的方法，或更具体地是一种在（a）通过制备镁溶液制备的固体钛催化剂的存在下制备乙烯的均聚物和共聚物的方法，使卤代镁化合物与醇接触反应; 与具有至少一个羟基的酯化合物和具有至少一个烷氧基的硅化合物反应; 并加入钛化合物和硅化合物的混合物; （b）元素周期表II或III族的有机金属化合物; 和（c）环状氮化合物。根据本发明制备的乙烯的均聚和共聚催化剂表现出高活性，并且通过使用所述催化剂通过本发明的方法制备的聚合物具有表现出高堆积密度和窄分子量的优点分布。

5. 发明授权

US06803427B2 Method for producing ethylene homo- and co-polymer 失效
标题翻译：生产乙烯均聚物和共聚物的方法
公开(公告)号：US06803427B2
公开(公告)日：2004-10-12
申请号：US09866499
申请日：2001-05-25
申请人： Chun-Byung Yang , Sang-Yull Kim , Weon Lee
发明人： Chun-Byung Yang , Sang-Yull Kim , Weon Lee
IPC分类号： C08F426
CPC分类号： C08F10/00 , C08F110/02 , C08F4/651 , C08F4/6565 , C08F4/6465 , C08F2500/03 , C08F2500/12 , C08F2500/18
摘要： The present invention relates to a method for producing a polymer and copolymer of ethylene, and more particularly to a method for producing an ethylene polymer and copolymer by reacting a compound of an organic metal of Group 2, 12, or 13 on the periodic table of elements with an alkoxy silane compound in the presence of a titanium catalyst, the said titanium catalyst being produced by a process of preparing a magnesium compound by contact-reacting a halogenated magnesium compound and alcohol, of reacting the said solution with an ester compound which contains at least one hydroxy group and a silicon compound containing an alkoxy group, and also of reacting it with a solid matter obtained by reaction of a mixture of a titanium compound and a silicon compound with a titanium compound. The catalyst used in polymerization and copolymerization of ethylene in the present invention is high in catalytic activity, and the polymer produced by the use of this catalyst has the merits of a high bulk density and a narrow molecular weight distribution.
摘要翻译：本发明涉及一种制备乙烯的聚合物和共聚物的方法，更具体地说，涉及一种通过使第2,12或13族的有机金属的化合物在周期表上与元素与烷氧基硅烷化合物在钛催化剂存在下，所述钛催化剂是通过使卤化镁化合物和醇接触反应来制备镁化合物的方法制备的，使所述溶液与含有至少一种羟基和含有烷氧基的硅化合物，并且还使其与通过钛化合物和硅化合物的混合物与钛化合物反应获得的固体物质反应。在本发明中用于乙烯聚合和共聚的催化剂的催化活性高，通过使用该催化剂制备的聚合物具有高堆积密度和窄分子量分布的优点。

6. 发明授权

US07754833B2 Process for polymerization or copolymerization of ethylene 失效
标题翻译：乙烯的聚合或共聚方法
公开(公告)号：US07754833B2
公开(公告)日：2010-07-13
申请号：US12160773
申请日：2006-12-28
申请人： Sang Yull Kim , Ho Sik Chang , Chun Byung Yang
发明人： Sang Yull Kim , Ho Sik Chang , Chun Byung Yang
IPC分类号： C08F4/44
CPC分类号： C08F10/00 , C08F110/02 , C08F4/6565 , C08F2500/12 , C08F2500/18 , C08F4/651
摘要： Provided is a process for polymerization and copolymerization of ethylene, specifically comprising carrying out polymerization or copolymerization ethylene in the presence of (a) a solid complex titanium catalyst which is produced by the process comprising: (i) preparing a magnesium compound solution by contacting a halogenated magnesium compound and an alcohol for allowing a reaction; (ii) reacting the resulted magnesium compound solution with an ester compound having at least one hydroxyl group and a silicon compound having at least one alkoxy group; (iii) reacting the resulted solution with a mixture of a titanium compound and a silicon compound to obtain a solid titanium catalyst component; (iv) washing the resulted solid titanium catalyst component with a halogenated saturated hydrocarbon compound; and (v) further reacting the washed solid titanium catalyst component with a titanium compound to obtain a solid complex titanium catalyst, and (b) an organometallic compound from Group II or III of Periodic table of elements. According to the present invention, it is possible to provide a process for polymerization or copolymerization of ethylene in which the catalyst activity is improved and a polymer of high bulk density is provided, with the use of a catalyst prepared by a simple process.
摘要翻译：提供了一种乙烯的聚合和共聚方法，特别包括在（a）固体络合物钛催化剂的存在下进行聚合或共聚乙烯，所述固体络合物钛催化剂通过以下方法制备，所述方法包括：（i）通过使卤化镁化合物和用于允许反应的醇; （ii）使得到的镁化合物溶液与具有至少一个羟基的酯化合物和具有至少一个烷氧基的硅化合物反应; （iii）使所得溶液与钛化合物和硅化合物的混合物反应，得到固体钛催化剂组分; （iv）用卤化饱和烃化合物洗涤得到的固体钛催化剂组分; 和（v）使洗涤的固体钛催化剂组分与钛化合物进一步反应以获得固体络合物钛催化剂，和（b）元素周期表第II或III族的有机金属化合物。根据本发明，通过使用通过简单的方法制备的催化剂，可以提供改进催化剂活性的乙烯的聚合或共聚方法和提供高堆积密度的聚合物。

7. 发明授权

US07151071B2 Method for preparation of a solid titanium catalyst for olefin polymerization 失效
标题翻译：烯烃聚合固体钛催化剂的制备方法
公开(公告)号：US07151071B2
公开(公告)日：2006-12-19
申请号：US11046130
申请日：2005-01-28
申请人： Sang-Yull Kim , Ki-Hwa Lee , Chun-Byung Yang , Ho-Sik Chang
发明人： Sang-Yull Kim , Ki-Hwa Lee , Chun-Byung Yang , Ho-Sik Chang
IPC分类号： B01J31/00
CPC分类号： B01J31/38 , B01J31/0202 , B01J31/0204 , B01J2231/12
摘要： The present invention relates to a method for preparing a solid titanium catalyst for olefin polymerization. The method for preparing a solid titanium catalyst for olefin polymerization according to the present invention comprises: preparing a magnesium compound solution by dissolving magnesium halide compound in a solvent mixture of cyclic ether and one or more of alcohol; preparing a carrier by adding titanium halide compound to said magnesium compound solution, then elevating the temperature of the solution and aging the solution to precipitate particles, and then adding titanium halide compound thereto for further reaction; preparing a catalyst by reacting said carrier with titanium compound and electron donor; and washing said catalyst with halogenated saturated hydrocarbon. According to the method of the present invention, a catalyst having high activity can be obtained and polyolefin produced by using the catalyst prepared by the method of the present invention has high stereoregularity, relatively easily compared with the conventional method.
摘要翻译：本发明涉及一种制备用于烯烃聚合的固体钛催化剂的方法。制备本发明的烯烃聚合用固体钛催化剂的方法包括：通过将卤化镁化合物溶解在环醚和一种或多种醇的溶剂混合物中来制备镁化合物溶液; 通过向所述镁化合物溶液中加入卤化钛化合物制备载体，然后升高溶液的温度并使溶液老化以沉淀颗粒，然后加入卤化钛化合物进一步反应; 通过使所述载体与钛化合物和电子给体反应制备催化剂; 并用卤化饱和烃洗涤所述催化剂。根据本发明的方法，与传统方法相比，可以获得具有高活性的催化剂，并且通过使用本发明方法制备的催化剂制备的聚烯烃具有高的立构规整性。

8. 发明授权

US09045572B2 Preparation method of solid catalyst for propylene polymerization and catalyst prepared thereby 有权
标题翻译：丙烯聚合用固体催化剂的制备方法及其制备的催化剂
公开(公告)号：US09045572B2
公开(公告)日：2015-06-02
申请号：US13520863
申请日：2010-12-30
申请人： Sang Yull Kim , Jin Woo Lee , Eun Il Kim , Joon Ryeo Park
发明人： Sang Yull Kim , Jin Woo Lee , Eun Il Kim , Joon Ryeo Park
IPC分类号： B01J21/00 , B01J23/00 , B01J25/00 , B01J29/00 , B01J37/00 , C08F110/06 , C08F10/06
CPC分类号： C08F110/06 , C08F10/06 , Y02P20/52 , C08F4/651 , C08F4/6565
摘要： Disclosed are a method for preparing a solid catalyst for propylene polymerization and a catalyst prepared thereby. Specifically, disclosed are a method for preparing a solid catalyst for propylene polymerization which can prepare polypropylene having excellent stereoregularity with a high production yield by using silane compounds and bicycloalkanedicarboxylate or bicycloalkenedicarboxylate as an internal electron donor, and a catalyst prepared thereby method for preparing polypropylene using the same.
摘要翻译：公开了一种制备用于丙烯聚合的固体催化剂的方法和由其制备的催化剂。具体地说，公开了一种制备用于丙烯聚合的固体催化剂的方法，其可以通过使用硅烷化合物和双链烷二羧酸酯或双环烯烃二羧酸酯作为内给电子体，制备具有优异的立构规整性的聚异丁烯，并由此制备用于制备聚丙烯的方法一样。

9. 发明申请

US20130237406A1 SOLID CATALYST FOR THE POLYMERIZATION OF PROPYLENE, AND METHOD FOR PREPARING SAME 有权
标题翻译：用于丙烯聚合的固体催化剂及其制备方法
公开(公告)号：US20130237406A1
公开(公告)日：2013-09-12
申请号：US13885879
申请日：2011-09-02
申请人： Sang Yull Kim , Jin Woo Lee , Eun Il Kim , Joon Ryeo Park
发明人： Sang Yull Kim , Jin Woo Lee , Eun Il Kim , Joon Ryeo Park
IPC分类号： C08F110/06
CPC分类号： C08F110/06 , C08F10/06 , Y02P20/52 , C08F4/651 , C08F4/6565
摘要： Provided are a solid catalyst for propylene polymerization and a method for preparing the same, specifically a solid catalyst for propylene polymerization which does not contain any environmentally harmful material and can produce a polypropylene having excellent stereoregularity with a high production yield, and a method for preparing the catalyst.
摘要翻译：提供一种用于丙烯聚合的固体催化剂及其制备方法，具体地说是用于丙烯聚合的固体催化剂，其不含任何对环境有害的材料，并且可以制备具有高生产率的立构规整性优异的聚丙烯，以及制备方法催化剂。

10. 发明授权

US09034781B2 Solid catalyst for the polymerization of propylene, and method for preparing same 有权
标题翻译：用于丙烯聚合的固体催化剂及其制备方法
公开(公告)号：US09034781B2
公开(公告)日：2015-05-19
申请号：US13885879
申请日：2011-09-02
申请人： Sang Yull Kim , Jin Woo Lee , Eun Il Kim , Joon Ryeo Park
发明人： Sang Yull Kim , Jin Woo Lee , Eun Il Kim , Joon Ryeo Park
IPC分类号： C08F110/06 , B01J31/00 , C08F4/02 , C08F4/44 , C08F2/00 , C08F10/06
CPC分类号： C08F110/06 , C08F10/06 , Y02P20/52 , C08F4/651 , C08F4/6565
摘要： Provided are a solid catalyst for propylene polymerization and a method for preparing the same, specifically a solid catalyst for propylene polymerization which does not contain any environmentally harmful material and can produce a polypropylene having excellent stereoregularity with a high production yield, and a method for preparing the catalyst.
摘要翻译：提供一种用于丙烯聚合的固体催化剂及其制备方法，具体地说是用于丙烯聚合的固体催化剂，其不含任何对环境有害的材料，并且可以制备具有高生产率的立构规整性优异的聚丙烯，以及制备方法催化剂。

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