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    • 1. 发明授权
    • Process for making printing plates
    • 印版制作工艺
    • US4518677A
    • 1985-05-21
    • US598113
    • 1984-04-09
    • Rudolph L. Pohl
    • Rudolph L. Pohl
    • C08C19/30C08F8/00G03F7/032G03F7/02G03C5/24
    • G03F7/032C08C19/30C08F8/00
    • It has been found that excellent quality photopolymer printing plates having resistance to alcohol-based inks can be prepared by (a) spreading a photopolymer composition comprising a chain extended, liquid, terminally olefinically unsaturated polymer; from about 1% to about 50% by weight based on the weight of the polymer of at least one ethylenically unsaturated monomer; from about 0.1% to about 10% by weight based on the weight of the polymer of photoinitiator; and from about 0.01% to about 2% by weight based on the weight of the polymer of a stabilizer on a support to form a photopolymer element, (b) exposing to actinic light selected areas of said photopolymer composition on said support until substantial cross-linking takes place in the exposed areas without significant cross-linking in the unexposed areas, and (c) removing the unexposed areas of photopolymer composition by washing the plate with an aqueous detergent solution.
    • 已经发现,具有对醇基油墨具有耐性的优质光敏聚合物印刷版可以通过以下步骤制备:(a)铺展包含延伸链,液态,末端烯属不饱和聚合物的光聚合物组合物; 约1重量%至约50重量%,基于聚合物的至少一种烯键式不饱和单体的重量; 基于光引发剂的聚合物的重量计约0.1%至约10%; 和约0.01重量%至约2重量%,基于载体上的稳定剂聚合物的重量,以形成光聚合物元件,(b)将所述光聚合物组合物的光化选择区域暴露于所述载体上, 连接发生在暴露区域,而在未曝光区域中没有明显的交联,和(c)通过用洗涤剂水溶液洗涤板来去除未曝光的光聚合物组合物区域。
    • 4. 发明授权
    • Polymers for increasing the viscosity of photosensitive resins
    • 用于增加感光树脂粘度的聚合物
    • US4168173A
    • 1979-09-18
    • US940226
    • 1978-09-07
    • Rudolph L. Pohl
    • Rudolph L. Pohl
    • G03F7/032G03C1/68C08G18/00
    • G03F7/032
    • It has been found that high quality relief printing plates can be made using a photosensitive composition comprising at least one unsaturated polyester, at least one ethylenically unsaturated, addition polymerizable monomer, at least one photosensitive initiator and a poly(hydroxylether) derived from a diphenol and an epihalohydrin, such as bisphenol A-epichlorohydrin resin. The poly(hydroxylether) increases the viscosity of the photosensitive resin such that the resin is less likely to flow during platemaking process, thereby avoiding undesirable blemishes on the finished plate.
    • 已经发现,可以使用包含至少一种不饱和聚酯,至少一种烯键式不饱和的可加成聚合单体,至少一种光敏引发剂和衍生自二酚的聚(羟基醚)的光敏组合物制备高质量的凸版印刷版, 表卤代醇,如双酚A-表氯醇树脂。 聚(羟基醚)增加感光性树脂的粘度,使得树脂在制版过程中不太可能流动,从而避免了成品板上的不希望的瑕疵。
    • 7. 发明授权
    • Relief plates from polymer with terminal unsaturation
    • 具有末端不饱和度的聚合物的浮雕板
    • US4174218A
    • 1979-11-13
    • US934281
    • 1978-08-16
    • Rudolph L. Pohl
    • Rudolph L. Pohl
    • G03F7/033G03C5/00G03C1/68G03C1/78G03C1/96
    • G03F7/033
    • It has been found that excellent quality photopolymer printing plates having hardness, flexibility, resilience, abrasion resistance and resistance to alcohol-based inks can be prepared from photopolymer compositions comprising a liquid polymer containing at least two terminal olefin groups attached to the polymer through a combination of at least two ether, thioether, ester, keto or amide groups, from about 1 to about 50% by weight based on the polymer of at least one ethylenically unsaturated monomer, from about 0.1 to about 10% by weight of a photoinitiator and about 0.01 to about 2% of a stabilizer.
    • 已经发现,具有硬度,柔韧性,回弹性,耐磨性和耐醇性油墨的优质光敏聚合物印刷版可以由光聚合物组合物制备,所述光聚合物组合物包含含有通过组合连接到聚合物上的至少两个末端烯烃基团的液体聚合物 至少两个醚,硫醚,酯,酮或酰胺基,约1-约50重量%,基于至少一种烯属不饱和单体的聚合物,约0.1-约10重量%的光引发剂和约 0.01至约2%的稳定剂。