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    • 3. 发明授权
    • Solvent deasphalting in solid phase
    • 固相溶剂脱沥青
    • US4572781A
    • 1986-02-25
    • US584955
    • 1984-02-29
    • Julio KrasukRodolfo B. SolariLuis G. AquinoJose V. RodriguezAlejandro Granados
    • Julio KrasukRodolfo B. SolariLuis G. AquinoJose V. RodriguezAlejandro Granados
    • C10G21/00C10C3/00C10C3/08
    • C10G21/003
    • A process for separating substantially dry asphaltenes of high softening point from heavy hydrocarbon material comprising:(a) admixing heavy hydrocarbon material containing asphaltenes with a solution of deasphalted oil and an aliphatic hydrocarbon precipitant in a first mixing zone to form a mixture and precipitate asphaltenes;(b) in a first separation zone the mixture from step (a) into (i) a first solution of deasphalted oil and precipitant and (ii) a slurry of solid asphaltene particles in a solution of precipitant and desasphalted oil;(c) separating the first solution of step (b) to obtain said precipitant and the deasphalted oil almost free of asphaltenes;(d) introducing the slurry of asphaltenes of step (b) into a second mixing zone and washing the slurry with a volume of fresh precipitant to remove deasphalted oil;(e) introducing the mixture from the second mixing zone into a second separation zone that comprises a centrifugal decanter to separate a liquid phase from a highly concentrated slurry of solid asphaltenes;(f) recycling the liquid phase from the second separation zone to said first mixing zone;(g) introducing the concentrated slurry of solid asphaltenes from the second separation zone into a solvent removal system to recover the solvent and to obtain a product comprising fine particles of high softening point asphaltenes; and(h) recycling the solvent recovered in the solvent removal system to the second mixing zone.
    • 从重质烃材料中分离出高软化点的基本上干燥的沥青质的方法,包括:(a)在第一混合区中将含有沥青质的重质烃材料与脱沥青油和脂族烃沉淀剂的溶液混合以形成混合物并沉淀沥青质; (b)在第一分离区中将来自步骤(a)的混合物转化为(i)脱沥青油和沉淀剂的第一溶液和(ii)固体沥青质颗粒在沉淀剂和脱沥青油溶液中的浆料; (c)分离步骤(b)的第一溶液以获得所述沉淀剂,脱沥青油几乎不含沥青质; (d)将步骤(b)的沥青质浆液引入第二混合区,并用一定体积的新鲜沉淀剂洗涤浆料以除去脱沥青的油; (e)将来自第二混合区的混合物引入第二分离区,该分离区包括离心沉降器,以将液相与固体沥青质的高浓度浆料分离; (f)将液相从第二分离区再循环到所述第一混合区; (g)将固体沥青质的浓缩浆料从第二分离区引入溶剂除去系统中以回收溶剂,并获得包含高软化点沥青质细颗粒的产品; 和(h)将在溶剂去除系统中回收的溶剂回收到第二混合区。