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    • 1. 发明申请
    • HIGH-TEMPERATURE METAL-ORGANIC ACCEPTOR MAGNETS
    • 高温金属有机接收磁铁
    • US20100267978A1
    • 2010-10-21
    • US12770316
    • 2010-04-29
    • Rajsapan JainRobin Gary Hicks
    • Rajsapan JainRobin Gary Hicks
    • C07F15/04
    • C07F15/045H01F1/42
    • A stable magnet having a high Tc is provided. The stable magnet is synthesized from an at least one ion of a metal from a metal-containing precursor and molecules of an organic compound in a metal to organic ratio of at least about 1 ion to 1 organic molecule and as much as 10 or more ions to 1 organic molecule. The metal-containing precursor provides at least one ion having a valency lower than its maximum valency state. The organic molecules are selected from a group of organic compounds having a reduction potential suitable to accept at least one electron from the metal ion and an at least one functional group that is able to coordinate with the metal ion.
    • 提供具有高Tc的稳定磁体。 稳定磁体由至少一种来自含金属前体的金属离子和有机化合物分子以至少约1个离子至1个有机分子和多达10个或更多个离子的金属与有机比合成 1有机分子。 含金属的前体提供至少一种具有低于其最大化合价态的化合价的离子。 有机分子选自具有适合于接受来自金属离子的至少一种电子的还原电位的一组有机化合物和能够与金属离子配位的至少一种官能团。
    • 2. 发明授权
    • Verdazyl agents for the production of free standing polymers
    • 用于生产自由基聚合物的维肟化剂
    • US07638587B2
    • 2009-12-29
    • US11737046
    • 2007-04-18
    • Robin Gary HicksMichael Georges
    • Robin Gary HicksMichael Georges
    • C08F2/38C07D257/12
    • C08F4/00C08F12/08C08F220/00C08F2/42C08F2/38
    • The present disclosure concerns embodiments of a method of synthesizing polymers using verdazyl agents selected for their property of being moderately unstable free radicals. In one embodiment of the invention a method of synthesizing free standing polymers from suitably selected polymerizable subunits, such as monomers, is provided. In another embodiment of the invention a combination for the synthesis of free standing polymers from suitably selected polymerizable subunits using moderately unstable verdazyls is provided. Using moderately unstable verdazyls permits lower reaction temperatures and faster reaction times, while yielding polymers with low polydispersity.
    • 本公开涉及使用由于其适度不稳定的自由基的性质而选择的格列烷基试剂合成聚合物的方法的实施方案。 在本发明的一个实施方案中,提供了从合适选择的可聚合亚单位如单体合成自由基聚合物的方法。 在本发明的另一个实施方案中,提供了使用适度不稳定的格列札从合适选择的可聚合亚单位合成自由基聚合物的组合。 使用适度不稳定的格列腙允许较低的反应温度和更快的反应时间,同时产生具有低多分散性的聚合物。