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    • 3. 发明授权
    • Sucrose inversion process
    • 蔗糖反转过程
    • US08404109B2
    • 2013-03-26
    • US13316278
    • 2011-12-09
    • Robert JansenJohn KerrAnthony Baiada
    • Robert JansenJohn KerrAnthony Baiada
    • B01D17/12C13K3/00B01J14/00
    • C13K3/00C13B20/14
    • A method of inverting sucrose, including (i) determining an initial solids concentration of an aqueous sucrose solution, an initial bed volume of a sucrose inversion resin system, a minimum target inversion percentage, a maximum target inversion percentage, a target maximum hydroxymethylfuran (HMF) concentration, a minimum target pH, or a maximum target pH; (ii) contacting the sucrose inversion resin system with the aqueous sucrose solution under conditions of aqueous solution flow rate and aqueous solution temperature to produce an inverted sucrose solution having an inversion percentage, an HMF concentration, and a pH; (iii) observing an instantaneous inversion percentage, an instantaneous HMF concentration, or an instantaneous pH of the inverted sucrose solution; and, if appropriate; (iv) changing at least one of the aqueous solution flow rate or the aqueous solution temperature to yield a product having a desired inversion percentage, HMF concentration, and/or pH. An apparatus capable of performing the method.
    • 一种反相蔗糖的方法,包括(i)测定蔗糖水溶液的初始固体浓度,蔗糖反转树脂体系的初始床体积,最小目标反转百分比,最大目标反转百分比,目标最大羟甲基呋喃(HMF )浓度,最小目标pH或最大目标pH; (ii)在水溶液流动速率和水溶液温度条件下使蔗糖反转树脂体系与蔗糖溶液水溶液接触,以产生具有倒置百分比,HMF浓度和pH值的倒置蔗糖溶液; (iii)观察反转蔗糖溶液的瞬时反转百分比,瞬时HMF浓度或瞬时pH值; 并酌情; (iv)改变水溶液流速或水溶液温度中的至少一个,得到具有所需转化百分比,HMF浓度和/或pH值的产物。 一种能够执行该方法的装置。
    • 4. 发明申请
    • METHODS FOR THE RECOVERY OF HCL AND FOR THE PRODUCTION OF CARBOHYDRATES
    • HCL的回收和碳水化合物的生产方法
    • US20130047979A1
    • 2013-02-28
    • US13499638
    • 2010-09-21
    • Aharon EyalRobert Jansen
    • Aharon EyalRobert Jansen
    • C13K1/02C01B7/07C09K3/00
    • C07H3/02C01B7/0712C01B7/0737C13K1/04
    • The invention provides an organic phase composition comprising: a. a first component selected from the group consisting of quaternary amines; b. a second component selected from: b1. The group consisting of category B organic acids; b2. The group consisting of a mixtures of category B organic acids and category C organic acids at a B/C molar ratio of RB/C; and b3. The group consisting of a mixtures of category A organic acids and category C organic acids at an A/C molar ratio of RA/C; c. a third component selected from the group consisting of solvents for said first component and for said second component, wherein (i) all three components are oil-soluble and water-insoluble; (ii) the molar concentration of each of said first component and said second component is greater than 0.6 mol/Kg; (iii) the molar ratio between said second component and said first component is greater than 0.9; (iv) RB/C and RA/c are greater than 2; (v) category A organic acids are selected from the group consisting of poly-aromatic sulfonic acids, naphthalene sulfonic acids and acids with a pKa in the range within +/−0.5 pKa units of that of naphthalene sulfonic acid; (vi) category B organic acids are selected from the group consisting of mono-aromatic sulfonic acids, benzene sulfonic acids, and acids with a pKa in the range within +/−0.5 pKa units of that of benzene sulfonic acid; and (vii) category C organic acids are selected from the group consisting of phosphoric acid esters and acids with a pKa in the range within +/−0.5 pKa units of that of di-octyl esters of phosphoric acid.
    • 本发明提供一种有机相组合物,其包含:a。 选自季胺的第一组分; b。 第二个组件选自:b1。 由B类有机酸组成的组; b2。 由B / C摩尔比为RB / C的B类有机酸和C类有机酸的混合物组成的组; 和b3。 由A / C摩尔比为RA / C的A类有机酸和C类有机酸的混合物组成的组; C。 选自由所述第一组分和所述第二组分的溶剂组成的组的第三组分,其中(i)所有三种组分都是油溶性和水不溶性的; (ii)所述第一组分和所述第二组分的摩尔浓度大于0.6mol / Kg; (iii)所述第二组分和所述第一组分之间的摩尔比大于0.9; (iv)RB / C和RA / c大于2; (v)A类有机酸选自聚芳族磺酸,萘磺酸和pKa在萘磺酸的+/- 0.5pKa单位范围内的酸; (vi)B类有机酸选自单芳族磺酸,苯磺酸和pKa在苯磺酸的+/- 0.5pKa单位范围内的酸; 和(vii)C类有机酸选自磷酸酯和酸,其中pKa在磷酸二辛基酯的+/- 0.5pKa单位范围内。
    • 5. 发明授权
    • Process for efficient energy recovery from biomass
    • 从生物质能源回收有效的方法
    • US08220400B2
    • 2012-07-17
    • US12173247
    • 2008-07-15
    • Raymond C. GangaGreg ImigBlake McBurneyRobert JansenJohn KerrSteven J. Reust
    • Raymond C. GangaGreg ImigBlake McBurneyRobert JansenJohn KerrSteven J. Reust
    • F23D1/00F23B80/02F23C9/08
    • F23G7/10F23G5/12F23G5/46F23G2202/106F23G2206/20F23G2900/00001F23G2900/7012F23J7/00
    • A method for extracting energy from biomass depleted of at least some carbohydrate, at least some oil, or both by a) introducing the biomass into a vertically elongated combustion chamber having i) at least one suspension burner at the top of the combustion chamber which is capable of projecting a flame down the axis of the combustion chamber, ii) a heat transfer apparatus having at least a portion of a heat collection surface located radially from the flame and below the burner, and iii) an exhaust opening located below the flame and below at least a portion of the heat collection surface; b) combusting the biomass to yield a mixture containing hot flue gas and molten ash above the exhaust opening; c) transferring heat from the hot flue gas to at least a portion of the heat collection surface substantially by radiation prior to any substantial contact of ash to a surface of the combustion chamber, to yield a mixture containing warm flue gas and non-molten ash and having a lower molten ash content than the mixture yielded by the combusting step; and d) cooling the warm flue gas with cold gas, to yield a mixture containing cool flue gas and non-molten ash and having a lower molten ash content than the mixture yielded by the transferring step.
    • 一种用于从生物量中提取能量的方法,所述方法是从至少一些碳水化合物,至少一些油或二者中消耗的能量,通过以下步骤:a)将生物质引入垂直细长的燃烧室,所述燃烧室具有:i)在燃烧室顶部的至少一个悬浮燃烧器, 能够沿着燃烧室的轴线向下突出火焰,ii)传热装置,其具有位于燃烧器的径向位于燃烧器下方的集热表面的至少一部分,以及iii)位于火焰下方的排气口, 在集热面的至少一部分的下方; b)燃烧生物质以产生在排气口上方含有热烟道气和熔融灰渣的混合物; c)在灰分与燃烧室的任何实质接触之前,基本上通过辐射将热量从热烟道气传递到至少一部分集热表面,以产生含有热烟气和非熔融灰的混合物 并且具有比通过燃烧步骤产生的混合物更低的熔融灰分含量; 和d)用冷气体冷却暖烟道气,得到含有冷烟道气和非熔融灰分的混合物,其熔融灰分含量低于转移步骤产生的混合物。
    • 6. 发明申请
    • Method of Concentrating Hydrochloric Acid
    • 浓盐酸方法
    • US20100264372A1
    • 2010-10-21
    • US12426308
    • 2009-04-20
    • Avraham BANIELRobert Jansen
    • Avraham BANIELRobert Jansen
    • C09K3/00C01B7/01
    • C01B7/0706
    • A method for producing concentrated HCl vapor from an aqueous solution of HCl, including: (a) introducing an aqueous feed liquor to an evaporation chamber containing a mother liquor, the feed liquor having an initial, super-azeotropic HCl concentration; (b) directly contacting a liquor of these liquors with a heat-laden heat transfer fluid, to transfer heat from the fluid; (c) utilizing the heat to evaporate HCl, within the chamber, to produce the concentrated HCl vapor and to produce the mother liquor, the mother liquor including an aqueous phase having a reduced concentration of HCl, with respect to the initial HCl concentration; (d) subjecting the mother liquor to a liquid-liquid separation to produce a liquid phase containing HCl, and another liquid phase containing the heat transfer fluid in a heat-depleted state, with respect to the heat transfer fluid in step (b); (e) heating the heat transfer fluid in the heat-depleted state, to regenerate the heat-laden heat transfer fluid, and (f) returning this heat transfer fluid to step (b).
    • 一种从HCl水溶液中生产浓HCl蒸气的方法,包括:(a)将含水原料液引入到含有母液的蒸发室中,该进料液体具有初始的超共沸HCl浓度; (b)将这些液体的液体与加热的传热流体直接接触,以从流体传递热量; (c)利用热量在室内蒸发HCl以产生浓缩的HCl蒸气并产生母液,该母液包含相对于初始HCl浓度具有降低的HCl浓度的水相; (d)相对于步骤(b)中的传热流体,使母液进行液液分离以产生含有HCl的液相和含有热耗尽状态的传热流体的另一液相; (e)加热处于耗热状态的传热流体,以再生载热的传热流体,和(f)将该传热流体返回到步骤(b)。