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1. 发明授权

US5114940A Pesticides 失效
标题翻译：农药
公开(公告)号：US5114940A
公开(公告)日：1992-05-19
申请号：US355976
申请日：1989-05-22
申请人： Robert J. Blade , Robert J. Peek , George S. Cockerill
发明人： Robert J. Blade , Robert J. Peek , George S. Cockerill
IPC分类号： A01N43/42 , A01N43/54 , A01N43/58 , A01N43/60 , A01N43/78 , A01N49/00 , C07D215/14 , C07D215/20 , C07D215/22 , C07D215/227 , C07D215/233 , C07D215/26 , C07D215/28 , C07D215/36 , C07D215/54 , C07D217/16 , C07D217/22 , C07D217/24 , C07D237/28 , C07D237/30 , C07D239/88 , C07D239/95 , C07D241/44 , C07D277/68 , C07D405/12
CPC分类号： C07D215/227 , A01N43/42 , A01N49/00 , C07D215/14 , C07D215/20 , C07D215/22 , C07D215/233 , C07D215/26 , C07D215/28 , C07D215/36 , C07D215/54 , C07D217/24 , C07D237/28 , C07D237/30 , C07D239/95 , C07D241/44 , C07D277/68
摘要： Compound of the formula (I) are disclosedArQQ.sup.1 C(.dbd.X)NHR.sup.1 (I)or a salt thereof, wherein Ar is an optionally substituted polycyclic ring system containing n rings, where n is the integer 2 or 3, at least n-1 rings being aromatic and containing one to three ring nitrogen atoms and optionally containing one or more additional heteroatoms; Q is an alkyl chain containing 1 to 12 carbon atoms and optionally containing a sulphur or one or two oxygen atoms; Q.sup.1 is a group (C(R.sup.2).dbd.C(R.sup.3)).sub.a --(C(R.sup.4).dbd.C(R.sup.5)) wherein a is 0 or 1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are the same or different, at least two being hydrogen and the other two being independently selected from hydrogen, halo, C.sub.1-4 haloalkyl; X is oxygen or sulphur; and R.sup.1 is selected from hydrogen and C.sub.1-8 hydrocarbyl optionally substituted by dioxalanyl, halo, cyano, trifluoromethyl, trifluoromethylthio or C.sub.1-6 alkoxy are described which have activity particularly against arthropod pests. Pesticidal formulations containing the compounds of the formula (1), their use in the control of pests and method for their preparation are also disclosed.

2. 发明授权

US5037813A N-alkyl-N-[1,3-butadienyl(thio)carbonyl]-(thio) phosphoramidates, compositions, and methods of use as pesticides 失效
标题翻译： N-烷基-N- [1,3-丁二烯基（硫代）羰基] - （硫代）氨基磷酸酯，组合物和用作农药的方法
公开(公告)号：US5037813A
公开(公告)日：1991-08-06
申请号：US940561
申请日：1986-12-11
申请人： Malcolm H. Black , Robert J. Blade , Robert J. Peek
发明人： Malcolm H. Black , Robert J. Blade , Robert J. Peek
IPC分类号： A01N37/18 , A01N37/28 , A01N37/36 , A01N37/46 , A01N41/12 , A01N47/12 , A01N57/26 , C07C67/00 , C07C233/09 , C07C233/13 , C07C233/20 , C07C233/90 , C07C235/28 , C07C313/00 , C07C325/00 , C07C327/44 , C07D307/38 , C07D307/40 , C07D311/02 , C07D333/04 , C07F9/24 , C07F9/44
CPC分类号： C07F9/2487
摘要： A compound of Formula (I):R.sup.1 (CA.dbd.CA.sup.1).sub.x --C(.dbd.X)NR.sup.2 R.sup.3(I)where R.sup.1 is alkyl optionally substituted by a group selected from alkoxy, alkenyl, alkynyl, alkenyloxy, alkynyloxy, aryl, aryloxy, arylalkoxy and cycloalkyl fused to an aryl ring; x=1 or 2; X=O or S; each A and A.sup.1 is independently hydrogen, alkyl or haloalkyl; R.sup.2 is alkyl, alkenyl or cycloalkyl any of which may be substituted by halo, alkenyl, alkyl, cycloalkyl, alkynyl, dioxalanylalkyl or alkoxy; and R.sup.3 is selected from groups (A) to (D):(A) --Y.dbd.X.sup.1 --(R.sup.4).sub.a where X.sup.1 is O or S, Y is phosphorus or carbon, R.sup.4 is hydrogen, alkyl, alkoxy, acyl or CO.sub.2 R.sup.5 is alkyl or aryl, and a is 1 or 2.(B) --S(R.sup.6)(O).sub.bwhere R.sup.6 alkyl, aryl, aryloxy, alkoxy, thioalkoxy, thioaryl, alkythio, alkoxythio or arylthio and b is 0, 1 or 2(C) --S(O).sub.c NR.sup.7 R.sup.8where c is 0, 1 or 2, R.sup.7 is --COR.sup.9 or --CO.sub.2 R.sup.9 where R.sup.9 is hydrogen, alkyl or a fluorine atom, a group (A) or (B) as defined above, or alkyl substituted by acyl, carboalkoxy or cyano, and R.sup.8 is alkyl(D) R.sup.1 --(CA.dbd.CA.sup.1).sub.n --C(.dbd.X)N(R.sup.2)--wherein the substituents are independently selected as in Formula (I) above.
摘要翻译：式（I）的化合物：R1（CA = CA1）xC（= X）NR2R3（I）其中R1是任选被选自烷氧基，烯基，炔基，烯氧基，炔氧基，芳基，芳氧基，芳基烷氧基和芳基烷氧基的基团取代的烷基稠合到芳环的环烷基; x = 1或2; X = O或S; 每个A和A1独立地是氢，烷基或卤代烷基; R2是烷基，烯基或环烷基，其中任何一个可以被卤素，烯基，烷基，环烷基，炔基，二氧戊环基烷基或烷氧基取代; （A）-Y = X1-（R4）a其中X1为O或S，Y为磷或碳，R4为氢，烷基，烷氧基，酰基或CO2R5 （B）-S（R 6）（O）b其中R 6烷基，芳基，芳氧基，烷氧基，硫代烷氧基，硫代芳基，烷硫基，烷硫基或芳硫基，b是0,1或 2（C）-S（O）cNR 7 R 8，其中c为0,1或2，R 7为-COR 9或-CO 2 R 9，其中R 9为氢，烷基或氟原子，如上所定义的基团（A）或（B）或被酰基，烷氧羰基或氰基取代的烷基，R8是烷基（D）R1-（CA = CA1）nC（= X）N（R2） - ，其中取代基如上式（I）所示独立选择。

3. 发明授权

US5091420A Method of combatting pests using N-(cyclo)alkyl-5-substituted-2,4-thiopentadienamide compounds 失效
标题翻译：使用N-（环）烷基-5-取代-2,4-硫戊二酰胺化合物杀虫的方法
公开(公告)号：US5091420A
公开(公告)日：1992-02-25
申请号：US559397
申请日：1990-07-26
申请人： Robert J. Blade , Robert J. Peek
发明人： Robert J. Blade , Robert J. Peek
IPC分类号： A01N37/18 , A01N37/36 , A01N39/00 , A01N39/02 , A01N43/30 , C07C327/44 , C07F9/40
CPC分类号： C07C327/44 , A01N37/18 , A01N37/36 , A01N39/00 , A01N39/02 , A01N43/30 , C07F9/4006
摘要： Pesticidal compositions for use against insects and acarines comprising a compound of Formula (I):R.sup.1 --(CA.dbd.CA').sub.n C(.dbd.S)NR.sup.2 R.sup.3 (I)wherein R.sup.1 is: C.sub.1-14 alkyl optionally substituted by C.sub.1-6 alkoxy, C.sub.2-6 alkenyl, C.sub.2-6 alkynyl, C.sub.2-6 alkenyloxy, C.sub.2-6 alkynyloxy, aryl, aryloxy or aryl (C.sub.1-6) alkoxy; aryloxy or aryl (C.sub.1-6) alkoxy; any of which groups may be substituted by halo,n is 1 or 2,each A and A' is independently hydrogen, halo, C.sub.1-4 alkyl or halo (C.sub.1-4) alkyl and R.sup.2 and R.sup.3 are independently hydrogen, C.sub.1-6 alkyl or C.sub.3-6 cycloalkyl, either of which may be substituted by one or more of halo, C.sub.2-6 alkenyl, C.sub.1-6 alkyl, C.sub.3-6 cycloalkyl, C.sub.3-6 cycloalkenyl, C.sub.1-6 alkoxy, C.sub.2-6 alkynyl or cyano, except that, when n is 1 and R.sup.2 is alkyl and R.sup.3 is hydrogen and A and A' are both hydrogen then R.sup.1 is not substituted alkyl.Most of the compounds of Formula (I) are novel.
摘要翻译：用于对昆虫和螨类的杀虫组合物，其包含式（I）的化合物：R1-（CA = CA'）n C（= S）NR 2 R 3（I）其中R 1为任选被C 1-6烷氧基取代的C 1-14烷基，C 2-6烯基，C 2-6炔基，C 2-6烯氧基，C 2-6炔氧基，芳基，芳氧基或芳基（C 1-6）烷氧基; 芳氧基或芳基（C 1-6）烷氧基; 其中任何一个可以被卤素取代，n是1或2，每个A和A'独立地是氢，卤素，C 1-4烷基或卤代（C 1-4）烷基，并且R 2和R 3独立地是氢，C 1-6 烷基或C 3-6环烷基，其中任一个可以被一个或多个卤素，C 2-6烯基，C 1-6烷基，C 3-6环烷基，C 3-6环烯基，C 1-6烷氧基，C 2-6炔基或氰基，不同之处在于当n为1且R 2为烷基且R 3为氢且A和A'都为氢时，则R 1为未取代的烷基。式（I）化合物的大部分是新颖的。

4. 发明授权

US5091414A Pesticidal compounds 失效
标题翻译：杀虫化合物
公开(公告)号：US5091414A
公开(公告)日：1992-02-25
申请号：US619872
申请日：1990-11-29
申请人： Malcolm H. Black , Robert J. Blade , Robert J. Peek
发明人： Malcolm H. Black , Robert J. Blade , Robert J. Peek
IPC分类号： C07F9/24
CPC分类号： C07F9/2487
摘要： A compound of Formula (I):(I) R.sup.1 (CA.dbd.CA.sup.1).sub.x --C(.dbd.X)NR.sup.2 R.sup.3where R.sup.1 is alkyl optionally substituted by a group selected from alkoxy, alkenyl, alkynyl, alkenyloxy, alkynyloxy, aryl, aryloxy, arylalkoxy and cycloalkyl fused to an aryl ring; x=1 or 2; X=O or S; each A and A.sup.1 is independently hydrogen, alkyl or haloalkyl; R.sup.2 is alkyl, alkenyl or cycloalkyl any of which may be substituted by halo, alkenyl, alkyl, cycloalkyl, alkynyl, dioxalanylalkyl or alkoxy; and R.sup.3 is selected from groups (A) to (D):(A) --Y=X.sup.1 --(R.sup.4).sub.a where X.sup.1 is O or S, Y is phosphorus or carbon, R.sup.4 is hydrogen, alkyl, alkoxy, acyl or CO.sub.2 R.sup.5 where R.sup.5 is alkyl or aryl, and a is 1 or 2(B) --S(R.sup.6)(O).sub.bwhere R.sup.6 is alkyl, aryl, aryloxy, alkoxy, thioalkoxy, thioaryl, alkythio, alkoxythio or arylthio and b is 0, 1 or 2(C) --S(O).sub.c NR.sup.7 R.sup.8where c is 0, 1 or 2, R.sup.7 is --COR.sup.9 or --CO.sub.2 R.sup.9 where R.sup.9 is hydrogen, alkyl or a fluorine atom, a group (A) or (B) as defined above, or alkyl substituted by acyl, carboalkoxy or cyano, and R.sup.8 is alkyl(D) R.sup.1 --(CA.dbd.CA.sup.1).sub.n --C(.dbd.X)N(R.sup.2)--wherein the subtituents are independently selected as in Formula (I) above.
摘要翻译：式（I）化合物：（I）R1（CA = CA1）xC（= X）NR2R3其中R1是任选被选自烷氧基，烯基，炔基，烯氧基，炔氧基，芳基，芳氧基，芳基烷氧基和芳氧基的基团取代的烷基，稠合到芳环的环烷基; x = 1或2; X = O或S; 每个A和A1独立地是氢，烷基或卤代烷基; R2是烷基，烯基或环烷基，其中任何一个可以被卤素，烯基，烷基，环烷基，炔基，二氧戊环基烷基或烷氧基取代; （A）-Y = X1-（R4）a其中X1为O或S，Y为磷或碳，R4为氢，烷基，烷氧基，酰基或CO2R5 其中R 5是烷基或芳基，且a是1或2（B）-S（R 6）（O）b，其中R 6是烷基，芳基，芳氧基，烷氧基，硫代烷氧基，硫代芳基，链炔基，烷硫基或芳硫基，b是0， 1或2（C）-S（O）cNR 7 R 8，其中c是0,1或2，R 7是-COR 9或-CO 2 R 9，其中R 9是氢，烷基或氟原子，定义的基团（A）或（B）或者被酰基，烷氧羰基或氰基取代的烷基，R8是烷基（D）R1-（CA = CA1）nC（= X）N（R2） - ，其中取代基如上式（I）所示独立选择。

5. 发明授权

US5124348A Pesticidal amides 失效
标题翻译：杀虫剂
公开(公告)号：US5124348A
公开(公告)日：1992-06-23
申请号：US701834
申请日：1991-05-17
申请人： Malcolm H. Black , Robert J. Blade , Robert J. Peek
发明人： Malcolm H. Black , Robert J. Blade , Robert J. Peek
IPC分类号： A01N37/18 , A01N37/28 , A01N37/36 , A01N37/46 , A01N41/12 , A01N47/12 , A01N57/26 , C07C67/00 , C07C233/09 , C07C233/13 , C07C233/20 , C07C233/90 , C07C235/28 , C07C313/00 , C07C325/00 , C07C327/44 , C07D307/38 , C07D307/40 , C07D311/02 , C07D333/04 , C07F9/24 , C07F9/44
CPC分类号： C07F9/2487
摘要： A compound of Formula (I):R.sup.1 (CA.dbd.CA.sup.1).sub.x --C(.dbd.X)NR.sup.2 R.sup.3 (I)where R.sup.1 is alkyl optionally substituted by a group selected from alkoxy, alkenyl, alkynyl, alkenyloxy, alkynyloxy, aryl, aryloxy, arylalkoxy and cycloalkyl fused to an aryl ring; x=1 or 2; X=O or S; each A and A.sup.1 is independently hydrogen, alkyl or haloalkyl; R.sup.2 is alkyl, alkenyl or cycloalkyl any of which may be substituted by halo, alkenyl, alkyl, cycloalkyl, alkynyl, dioxalanylalkyl or alkoxy; and R.sup.3 is selected from groups (A) to (D):(A) --Y.dbd.X.sup.1 --(R.sup.4).sub.a where X.sup.1 is O or S, Y is phosphorus or carbon, R.sup.4 is hydrogen, alkyl, alkoxy, acyl or CO.sub.2 R.sup.5 where R.sup.5 is alkyl or aryl, and a is 1 or 2(B) --S(R.sup.6)(O).sub.b where R.sup.6 is alkyl, aryl, aryloxy, alkoxy, thioalkoxy, thioaryl, alkythio, alkoxythio or arylthio and b is 0, 1 or 2(C) --S(O).sub.c NR.sup.7 R.sup.8 where c is 0, 1 or 2, R.sup.7 is --COR.sup.9 or --CO.sub.2 R.sup.9 where R.sup.9 is hydrogen, alkyl or a fluorine atom, a group (A) or (B) as defined above, or alkyl substituted by acyl, carboalkoxy or cyano, and R.sup.8 is alkyl(D) R.sup.1 --(CA.dbd.CA.sup.1).sub.n --C(.dbd.X)N(R.sup.2)-- wherein the substituents are independently selected as in Formula (I) above.
摘要翻译：式（I）的化合物：R1（CA = CA1）xC（= X）NR2R3（I）其中R1是任选被选自烷氧基，烯基，炔基，烯氧基，炔氧基，芳基，芳氧基，芳基烷氧基和芳基烷氧基的基团取代的烷基稠合到芳环的环烷基; x = 1或2; X = O或S; 每个A和A1独立地是氢，烷基或卤代烷基; R2是烷基，烯基或环烷基，其中任何一个可以被卤素，烯基，烷基，环烷基，炔基，二氧戊环基烷基或烷氧基取代; （A）-Y = X1-（R4）其中X1是O或S，Y是磷或碳，R4是氢，烷基，烷氧基，酰基或CO2R5，其中 R5是烷基或芳基，和a是1或2（B）-S（R6）（O）b，其中R6是烷基，芳基，芳氧基，烷氧基，硫代烷氧基，硫代芳基，链烯基，烷硫基或芳硫基，b是0,1 或2（C）-S（O）cNR 7 R 8，其中c为0,1或2，R 7为-COR 9或-CO 2 R 9，其中R 9为氢，烷基或氟原子，所定义的基团（A）或（B）或者被酰基，烷氧基或氰基取代的烷基，R8是烷基（D）R1-（CA = CA1）nC（= X）N（R2） - ，其中取代基如上述式（I）中独立地选择。

6. 发明授权

US5101071A Pesticidal compounds 失效
标题翻译：杀虫化合物
公开(公告)号：US5101071A
公开(公告)日：1992-03-31
申请号：US733635
申请日：1991-07-22
申请人： Robert J. Blade , Robert J. Peek
发明人： Robert J. Blade , Robert J. Peek
IPC分类号： A01N37/18 , A01N37/34 , A01N37/36 , A01N39/00 , A01N39/02 , A01N43/30 , C07C67/00 , C07C325/00 , C07C327/44 , C07D317/54
CPC分类号： A01N43/30 , A01N37/18 , A01N37/36 , A01N39/00 , A01N39/02 , C07D317/54
摘要： Pesticidal compositions for use against insects and acarines comprising a compound of Formula (I):R.sup.1 --(CA.dbd.CA').sub.n C(.dbd.S)NR.sup.2 R.sup.3 (I)whereinR.sup.1 is: C.sub.1-14 alkyl optionally substituted by C.sub.1-6 alkoxy, C.sub.2-6 alkenyl, C.sub.2-6 alkynyl, C.sub.2-6 alkenyloxy, C.sub.2-6 alkynyloxy, aryl, aryloxy or aryl (C.sub.1-6) alkoxy; aryloxy or aryl (C.sub.1-6) alkoxy; any of which groups may be substituted by halo,n is 1 or 2,each A and A' is independently hydrogen, halo, C.sub.1-4 alkyl or halo (C.sub.1-4) alkyland R.sup.2 and R.sup.3 are independently hydrogen, C.sub.1-6 alkyl or C.sub.3-6 cycloalkyl, either of which may be substituted by one or more of halo, C.sub.2-6 alkenyl, C.sub.1-6 alkyl, C.sub.3-6 cycloalkyl, C.sub.3-6 cycloalkenyl, C.sub.1-6 alkoxy, C.sub.2-6 alkynyl or cyano, except that, when n is 1 and R.sup.2 is alkyl and R.sup.3 is hydrogen and A and A' are both hydrogen then R.sup.1 is not substituted alkyl.
摘要翻译：用于对昆虫和螨类的杀虫组合物，其包含式（I）的化合物：R1-（CA = CA'）n C（= S）NR 2 R 3（I）其中R 1为任选被C 1-6烷氧基取代的C 1-14烷基，C 2-6烯基，C 2-6炔基，C 2-6烯氧基，C 2-6炔氧基，芳基，芳氧基或芳基（C 1-6）烷氧基; 芳氧基或芳基（C 1-6）烷氧基; 其中任何一个可以被卤素取代，n是1或2，每个A和A'独立地是氢，卤素，C 1-4烷基或卤代（C 1-4）烷基，并且R 2和R 3独立地是氢，C 1-6 烷基或C 3-6环烷基，其中任一个可以被一个或多个卤素，C 2-6烯基，C 1-6烷基，C 3-6环烷基，C 3-6环烯基，C 1-6烷氧基，C 2-6炔基或氰基，不同之处在于当n为1且R 2为烷基且R 3为氢且A和A'都为氢时，则R 1为未取代的烷基。

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