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    • 1. 发明授权
    • Fiber-reactive phosphorus mothproofing agents
    • 纤维反应磷防蛀剂
    • US4303652A
    • 1981-12-01
    • US938253
    • 1978-08-30
    • Francis W. JonesRobert J. MayfieldGary J. O'Loughlin
    • Francis W. JonesRobert J. MayfieldGary J. O'Loughlin
    • C07F9/11A01N57/02A01N57/14A01N57/16C07F9/165C07F9/18C07F9/24C07F9/38C07F9/40C07F9/6509C07F9/6512C07F9/6518C07F9/6521C07F9/653D06M16/00A61K31/41A61K31/675C07D249/12C07F9/65
    • D06M16/006A01N57/02A01N57/14A01N57/16C07F9/18C07F9/650911C07F9/650929C07F9/65125C07F9/65183C07F9/65212C07F9/653
    • Organophosphorus esters, useful in increasing the resistance of keratinous materials to attack by keratin-eating insects, have the general formula: ##STR1## wherein: X and Y are independently O or S;R.sub.1 is an alkyl, alkoxy, alkylamino, dialkylamino or alkylmercapto radical having 1 to 6 carbon atoms;an amino or aryl radical;R.sub.2 is an alkyl radical having 1 to 6 carbon atoms;R.sub.3 is a radical of the general formula:-J-(K-L).sub.n (2) wherein:J is an aliphatic radical, or radical containing an aromatic or heterocyclic ring;K is one of the following radicals: ##STR2## linked to J through the oxygen atom in the case of (3), (5) or (6), and through the nitrogen atom in the case of (4), and in which the carbonyl oxygen atom of (3), (4) or (5), or one or both carbonyl oxygen atoms of (6) may be replaced by sulphur; R.sub.4 is hydrogen, an aryl radical, or an alkyl radical of 1 to 6 carbon atoms;L is a halogenated alkyl or alkenyl radical; an alkyl radical (having 1 to 4 carbon atoms) or aryl radical substituted with a vinylsulphonyl group, vinylsulphonamido group or precursors thereof; or a heterocyclic radical containing 1 to 4 halogen atoms attached to carbon atoms adjacent to a nitrogen atom of the ring, the ring being linked directly to K or through an alkylene group having 1 to 4 carbon atoms;n is 1 to 3.
    • 有机磷酯可用于增加角蛋白材料抵抗角蛋白食用昆虫的抵抗力,具有以下通式:其中:X和Y独立地为O或S; R1是具有1至6个碳原子的烷基,烷氧基,烷基氨基,二烷基氨基或烷基巯基; 氨基或芳基; R2是具有1至6个碳原子的烷基; R3是通式的基团:-J-(K-L)n(2)其中:J是脂族基团,或含有芳族或杂环的基团; (3)在(3)的情况下,K是通过氧原子与J相连的O(7)(3) 在(4)的情况下通过氮原子,其中(3),(4)或(5)的羰基氧原子,或者(3),(4)或(5)中的一个或两个羰基氧原子 (6)可以用硫代替; R4是氢,芳基或1-6个碳原子的烷基; L是卤代烷基或烯基; 具有1-4个碳原子的烷基或被乙烯基磺酰基取代的芳基,乙烯基磺酰胺基或其前体; 或与环的氮原子相邻的碳原子上连接有1至4个卤素原子的杂环基团,该环直接连接至K或通过具有1至4个碳原子的亚烷基; n为1〜3。
    • 2. 发明授权
    • Mothproofing agents
    • 防蛀剂
    • US4343618A
    • 1982-08-10
    • US291999
    • 1981-08-11
    • Francis W. JonesRobert J. MayfieldGary J. O'LoughlinIan M. Russell
    • Francis W. JonesRobert J. MayfieldGary J. O'LoughlinIan M. Russell
    • C07F9/11A01N57/02A01N57/14A01N57/16C07F9/165C07F9/18C07F9/24C07F9/38C07F9/40C07F9/6509C07F9/6512C07F9/6518C07F9/6521C07F9/653D06M16/00D06M3/02D06M13/32
    • D06M16/006A01N57/02A01N57/14A01N57/16C07F9/18C07F9/650911C07F9/650929C07F9/65125C07F9/65183C07F9/65212C07F9/653
    • Organophosphorus esters, useful in increasing the resistance of keratinous materials to attack by keratin-eating insects, have the general formula: ##STR1## wherein: X and Y are independently O or S;R.sub.1 is an alkyl, alkoxy, alkylamino, dialkylamino or alkylmercapto radical having 1 to 6 carbon atoms; an amino or aryl radical;R.sub.2 is an alkyl radical having 1 to 6 carbon atoms;R.sub.3 is a radical of the general formula:--J--(K--L).sub.n ( 2)wherein:J is an aliphatic radical, or radical containing an aromatic or heterocyclic ring;K is one of the following radicals: ##STR2## linked to J through the oxygen atom in the case of (3), (5) or (6), and through the nitrogen atom in the case of (4), and in which the carbonyl oxygen atom of (3), (4) or (5), or one or both carbonyl oxygen atoms of (6) may be replaced by sulphur; R.sub.4 is hydrogen, an aryl radical, or an alkyl radical of 1 to 6 carbon atoms;L is a halogenated alkyl or alkenyl radical; an alkyl radical (having 1 to 4 carbon atoms) or aryl radical substituted with a vinylsulphonyl group, vinylsulphonamido group or precursors thereof; or a heterocyclic radical containing 1 to 4 halogen atoms attached to carbon atoms adjacent to a nitrogen atom of the ring, the ring being linked directly to K or through an alkylene group having 1 to 4 carbon atoms;n is 1 to 3.
    • 有机磷酯可用于增加角蛋白材料抵抗角蛋白食用昆虫的抵抗力,具有以下通式:其中:X和Y独立地为O或S; R1是具有1至6个碳原子的烷基,烷氧基,烷基氨基,二烷基氨基或烷基巯基; 氨基或芳基; R2是具有1至6个碳原子的烷基; R3是通式的基团:-J-(K-L)n(2)其中:J是脂族基团,或含有芳族或杂环的基团; (3)在(3)的情况下,K是通过氧原子与J相连的O(7)(3) 在(4)的情况下通过氮原子,其中(3),(4)或(5)的羰基氧原子,或者(3),(4)或(5)中的一个或两个羰基氧原子 (6)可以用硫代替; R4是氢,芳基或1-6个碳原子的烷基; L是卤代烷基或烯基; 具有1-4个碳原子的烷基或被乙烯基磺酰基取代的芳基,乙烯基磺酰胺基或其前体; 或与环的氮原子相邻的碳原子上连接有1至4个卤素原子的杂环基团,该环直接连接至K或通过具有1至4个碳原子的亚烷基; n为1〜3。