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    • 3. 发明授权
    • Encapsulated barrier for flexible films and a method of making the same
    • 柔性膜的封装屏障及其制造方法
    • US06500514B1
    • 2002-12-31
    • US09650385
    • 2000-08-29
    • Robert J. BlembergGregory L. PetkovsekChad M. Perre
    • Robert J. BlembergGregory L. PetkovsekChad M. Perre
    • B32B0302
    • B32B7/02B32B7/12Y10S428/91Y10T428/1383Y10T428/239Y10T428/31743Y10T428/31928
    • The present invention relates to a film structure and a method of manufacturing the same. More specifically, the film structure may include a barrier material made from EVOH, nylon or other thermally sensitive barrier material encapsulated by a first adhesive material. The barrier material and the first adhesive material form a barrier layer and a first set of adhesive layers when coextruded. The barrier layer and the first set of adhesive layers may be coextruded at the same or a similar temperature to form a first extrudate. The extrudate may be encapsulated by or otherwise coextruded with a second adhesive material to form a second extrudate at a higher temperature than the first extrudate that then may be formed into a flat sheet via a die. The first set of adhesive layers protects the barrier layer from high temperatures and long residence times related to the coextrusion/lamination process that may degrade the barrier layer. In addition, acid terpolymer consisting of ethylene/methyl acrylate/acrylic acid adheres a barrier material of EVOH to outer layers of the film structure.
    • 膜结构及其制造方法技术领域本发明涉及膜结构及其制造方法。 更具体地,膜结构可以包括由EVOH,尼龙或由第一粘合剂材料包封的其它热敏阻挡材料制成的阻挡材料。 当共挤出时,阻挡材料和第一粘合材料形成阻挡层和第一组粘合剂层。 阻挡层和第一组粘合剂层可以在相同或相似的温度下共挤出以形成第一挤出物。 挤出物可以用第二粘合剂材料包封或以其它方式共挤出,以在比可以通过模具形成平板的第一挤出物更高的温度下形成第二挤出物。 第一组粘合剂层保护阻隔层不受高温和长时间停留时间的影响,共挤出/层压过程可能会降低阻挡层。 此外,由乙烯/丙烯酸甲酯/丙烯酸组成的酸性三元共聚物将EVOH的阻隔材料粘合到膜结构的外层。
    • 5. 发明授权
    • High oxygen barrier film
    • 高氧阻隔膜
    • US5061534A
    • 1991-10-29
    • US184997
    • 1988-04-22
    • Robert J. BlembergDennis Kester
    • Robert J. BlembergDennis Kester
    • B29C47/06B32B7/00B32B27/08B32B27/30B32B37/15
    • B32B37/153B29C47/0021B29C47/061B29C47/065B29C47/145B32B27/30Y10T428/1341Y10T428/1383Y10T428/2826Y10T428/31913Y10T428/3192
    • Packaging films, and packages made with those films which have reduced sensitivity to humidity. The films include a first layer comprising an EVOH copolymer and a second layer comprising a vinylidene chloride copolymer. Packages made with the vinylidene chloride copolymer layer between the low ethylene content EVOH copolymer and the contained product provide high oxygen barrier properties under both high and low humidity conditions. At high humidity conditions, the oxygen barrier properties of the package are provided by the vinylidene chloride copolymer. At lower humidity conditions, the packaging material provides the superior oxygen barrier properties of the EVOH. So the packages of the invention provide superior oxygen barrier properties of the low ethylene content EVOH at lower humidities. But the oxygen barrier properties of the package are never less than those provided by the vinylidene chloride copolymer, even at high humidity conditions.
    • 包装薄膜和使用那些对湿度敏感性降低的膜制成的包装。 膜包括包含EVOH共聚物的第一层和包含偏二氯乙烯共聚物的第二层。 在低乙烯含量的EVOH共聚物和所含的产物之间用偏二氯乙烯共聚物层制成的包装在高低湿条件下提供高氧阻隔性能。 在高湿度条件下,包装的阻氧性由偏二氯乙烯共聚物提供。 在较低的湿度条件下,包装材料提供EVOH优异的氧气阻隔性能。 因此,本发明的包装在较低的湿度下提供了低乙烯含量EVOH的优异的氧气阻隔性能。 但是即使在高湿度条件下,封装的氧气阻隔性也不会低于偏二氯乙烯共聚物所提供的阻氧性能。