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    • 1. 发明授权
    • Rugged electrode for electrochemical measurements at high temperatures
and pressures
    • 坚固的电极,用于在高温和高压下进行电化学测量
    • US5516413A
    • 1996-05-14
    • US115380
    • 1993-09-01
    • John P. FosterRichard J. Jacko
    • John P. FosterRichard J. Jacko
    • G01N17/02G01N27/30G21C17/112
    • G21C17/112G01N27/30G21Y2002/104G21Y2002/206G21Y2004/10
    • A high temperature-high pressure electrode for electrochemical potential measurement has a high temperature probe comprising an oxidized zirconium alloy tube member having an electroconductive core which includes a liquid electrolyte and a porous plug held in place by an oxidized zirconium alloy tube and end plug with an axial bore extending therethrough. The electroconductive core can comprise a liquid electrolyte of soaked zirconia sand and a second porous plug. In another embodiment, the zirconia sand is replaced by a surface oxidized zirconium alloy rod with grooves which extend between ends for containment of the liquid electrolyte. This embodiment also contains a second porous plug. In a modification of the latter embodiment, there is a bore in the proximal end of the surface oxidized rod which communicates with the grooves to provide electrical continuity. A Teflon sleeve forms an annular seal between the proximal end of the oxidized rod and the oxidized tube.
    • 用于电化学电位测量的高温高压电极具有包括具有导电芯的氧化锆合金管构件的高温探针,该导电芯包括液体电解质和通过氧化锆合金管保持就位的多孔塞, 轴向孔延伸穿过其中。 导电芯可以包括浸渍的氧化锆砂的液体电解质和第二多孔塞。 在另一个实施例中,氧化锆砂被表面氧化的锆合金棒代替,其中凹槽在端部之间延伸以容纳液体电解质。 该实施例还包含第二多孔塞。 在后一实施例的修改中,在表面氧化棒的近端中存在与凹槽连通以提供电连续性的孔。 特氟龙套筒在氧化棒的近端和氧化管之间形成环形密封。
    • 2. 发明授权
    • Apparatus for conducting accelerated corrosion testing of nickel alloys
    • 镍合金加速腐蚀试验装置
    • US5034190A
    • 1991-07-23
    • US183260
    • 1988-04-08
    • George EconomyRichard J. JackoFredric W. PementAlfred W. Klein
    • George EconomyRichard J. JackoFredric W. PementAlfred W. Klein
    • G01N17/00
    • G01N17/00
    • Both an improved method and apparatus for determining, on an accelerated basis, the susceptibility of a nickel-based alloy to suffer stress corrosion cracking within a steam generator environment is disclosed herein. The method generally comprises the steps of subjecting a mechanically stressed specimen of the alloy to a mixture of steam and hydrogen at a temperature of between about 365.degree. C. to 435.degree. C., wherein the partial steam pressure is between about 10.4 MPa to 30.4 MPa, and the partial hydrogen pressure is between about 32 kPa to 500 kPa. The improved testing apparatus of the invention generally comprises a vessel for containing a stressed specimen and a pressurized atmosphere formed of steam and hydrogen, and an inlet cell for injecting a selected amount of hydrogen into the pressurized atmosphere of the vessel which includes a diffusion membrane which is permeable to hydrogen but impermeable to the remainder of the pressurized atmosphere. The inlet cell has a tubular housing having a wall formed from a thin layer of hydrogen permeable palladium-silver alloy. The tubular housing contains a gas permeable sponge formed by sintered particles of stainless steel to prevent the thin layer of palladium-silver alloy used in the hydrogen diffusion membrane from imploding in response to the pressure within the vessel.
    • 本文公开了一种用于在加速的基础上确定镍基合金在蒸汽发生器环境内遭受应力腐蚀开裂的敏感性的改进的方法和装置。 该方法通常包括以下步骤:在约365℃至435℃的温度下使合金的机械应力样品经受蒸汽和氢气的混合物,其中部分蒸汽压力为约10.4MPa至30.4 MPa,部分氢压为约32kPa至500kPa。 本发明的改进的测试装置通常包括用于容纳应力样品和由蒸汽和氢气形成的加压气氛的容器,以及用于将选定量的氢气注入到容器的加压气氛中的入口单元,该容器包括扩散膜, 对氢气是可渗透的,但对其余的加压气氛是不可渗透的。 入口单元具有管状壳体,其具有由可透氢钯 - 银合金薄层形成的壁。 管状壳体包含由不锈钢烧结颗粒形成的透气海绵,以防止氢扩散膜中使用的钯 - 银合金薄层响应于容器内的压力而侵入。
    • 4. 发明授权
    • Method and apparatus for monitoring the environment of a vessel
    • 监测船舶环境的方法和装置
    • US5333502A
    • 1994-08-02
    • US945788
    • 1992-09-16
    • William C. Clark, Jr.Richard J. JackoLee W. Burtner
    • William C. Clark, Jr.Richard J. JackoLee W. Burtner
    • G01N29/032G01N29/265G01N29/04
    • G01N29/032G01N29/265G01N2291/02416G01N2291/02818G01N2291/105G01N2291/2636G01N2291/267G01N2291/269
    • A method for monitoring the environment of a vessel provides a liquid (18) which may contain particles (20) in a vessel having containment walls (12), where a hollow member (26) such as a thin tube is inserted into the liquid near the containment walls, and the hollow member contains in it a robotic device (34), which can travel within the hollow member and which can emit and receive ultrasonic waves and electromagnetic fields, where both of the ultrasonic waves and electric fields can pass through the hollow member (26) to the containment walls (12), where the device: emits and receives low frequency ultrasonic waves to and from the containment walls (12) and high frequency ultrasonic waves to and from any particles (20), and emits electromagnetic fields to the containment walls (12) or their combination, where absorptions and reflections from the hollow member walls and the containment walls, and any particles present are measured and any current generated in the hollow member walls and the containment wall by the electromagnetic fields are measured, and then any differences are measured to determine flaws (24) in the hollow member and containment walls, and properties of any particles (20) in suspension.
    • 用于监测容器环境的方法提供了一种液体(18),其可以在容器内容纳有容器(12)中的颗粒(20),其中诸如细管的中空构件(26)插入液体附近 容纳壁和中空构件包括机器人装置(34),其可在中空构件内行进并且能够发射和接收超声波和电场,其中超声波和电场都可以通过 空心构件(26)连接到容纳壁(12),其中装置:向容纳壁(12)发射和从容纳壁(12)发射低频超声波,并将高频超声波接收到任何颗粒(20)和从任何颗粒(20)发射电磁 (12)或其组合的场地,其中测量来自中空构件壁和容纳壁以及存在的任何颗粒的吸收和反射,以及在中空构件壁中产生的任何电流 并且测量通过电磁场的容纳壁,然后测量任何差异以确定中空构件和容纳壁中的瑕疵(24)以及悬浮液中任何颗粒(20)的性质。