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1. 发明授权

US4755497A Preparaton of copper aluminum borate catalyst and optional improvement of the catalyst by incorporation with active metals 失效
标题翻译：制备硼酸铜铝催化剂，并通过与活性金属的结合任选改进催化剂
公开(公告)号：US4755497A
公开(公告)日：1988-07-05
申请号：US924064
申请日：1986-10-28
申请人： Richard E. De Simone , Eric J. Moore , Bruce I. Rosen
发明人： Richard E. De Simone , Eric J. Moore , Bruce I. Rosen
IPC分类号： B01J23/72 , B01J23/885 , B01J23/89 , C01B35/12 , B01J21/02 , C01B15/12
CPC分类号： B01J23/72 , B01J23/885 , B01J23/8926 , B01J23/8993 , C01B35/128
摘要： The invention is a solid state preparation of copper aluminum borate catalyst comprising: dry mixing solid reagents comprising suitable precursors of copper oxide (CuO), aluminum oxide (Al.sub.2 O.sub.3) and boron oxide (B.sub.2 O.sub.3) with a solid binder which aids compaction of the solid reagents, is essentially inert to said reagents, and burns away upon calcination, said dry mixing resulting in formation of a superficially dry copper aluminum borate precursor; compacting the dry precursor; and calcining the precursor at a sufficiently high temperature to form crystalline copper aluminum borate.
摘要翻译：本发明是一种硼酸铜铝催化剂的固态制剂，其包括：将含有氧化铜（CuO），氧化铝（Al 2 O 3）和氧化硼（B 2 O 3））的合适前体与固体粘合剂混合的干混固体试剂，其有助于固体试剂的压实，对所述试剂基本上是惰性的，并且在煅烧时烧掉，所述干混合导致形成表面干燥的硼酸铜铝前体; 压实干前体; 并在足够高的温度下煅烧前体以形成结晶的硼酸铜铝。

2. 发明授权

US4673767A AMS-1B crystalline borosilicate molecular sieve-based catalyst compositions and process for toluene alkylation 失效
标题翻译： AMS-1B结晶硼硅酸盐分子筛催化剂组合物和甲苯烷基化方法
公开(公告)号：US4673767A
公开(公告)日：1987-06-16
申请号：US801471
申请日：1985-11-25
申请人： Tayseer S. Nimry , Richard E. De Simone
发明人： Tayseer S. Nimry , Richard E. De Simone
IPC分类号： C07C2/66 , C07C2/68
CPC分类号： C07C2/66 , C07C2529/86 , Y02P20/52
摘要： Described are catalyst compositions comprising a HAMS-1B crystalline borosilicate molecular sieve incorporated into an inorganic matrix, which have been impregnated with a magnesium compound or with both a phosphorus compound and a magnesium compound, said impregnated compositions having improved para-selectively for toluene alkylation. Such impregnated compositions, when used for the alkylation of toluene using methanol, methylether, ethylene, or propylene yield dialkylbenzene products containing a higher proportion of the para-isomer than corresponding unimpregnated borosilicate-based compositions. When toluene is alkylated with propylene using the impregnated catalyst compositions of this invention, a significant increase in para-selectivity among the cymene isomers is obtained at high total-cymene/n-propyltoluene ratios.
摘要翻译：描述了催化剂组合物，其包含结合到无机基质中的HAMS-1B结晶硼硅酸盐分子筛，其已经用镁化合物或磷化合物和镁化合物浸渍，所述浸渍的组合物具有改进的对甲苯烷基化选择性。当使用甲醇，甲基醚，乙烯或丙烯烷基化甲苯时，这种浸渍的组合物产生的二烷基苯产物含有比相应的未浸渍的硼硅酸盐基组合物更高比例的对位异构体。当使用本发明的浸渍催化剂组合物用丙烯烷基化甲苯时，在高的总甲基异丙基苯胺/正丙基甲苯比例下，可以获得在异氰酸酯异构体之间对位选择性的显着增加。

3. 发明授权

US4670616A AMS-1B crystalline borosilicate molecular sieve-based catalyst compositions and process for toluene methylation 失效
标题翻译： AMS-1B结晶硼硅酸盐分子筛催化剂组合物和甲苯甲基化方法
公开(公告)号：US4670616A
公开(公告)日：1987-06-02
申请号：US801472
申请日：1985-11-25
申请人： Richard E. De Simone , Muin S. Haddad
发明人： Richard E. De Simone , Muin S. Haddad
IPC分类号： B01J29/86 , C07C2/86 , C07C2/68
CPC分类号： B01J29/86 , C07C2/864 , C07C2529/70 , Y02P20/52
摘要： Described are catalyst compositions comprising a HAMS-1B crystalline borosilicate molecular sieve, the majority of the crystallites of which are between about 1 micron and about 15 micron in largest diameter, incorporated into an inorganic matrix, which have been impregnated with a small amount of a magnesium compound, said impregnated compositions having improved para-selectively for toluene methylation to xylene. Such impregnated compositions, when used for the methylation of toluene using methanol or dimethylether, yield a xylene product containing a very high proportion of the para isomer compared to corresponding unimpregnated or magnesium compound-impregnated borosilicate-based compositions containing standard size (0.2.mu. to 0.5.mu.) borosilicate molecular sieve crystallites.
摘要翻译：描述了包含HAMS-1B结晶硼硅酸盐分子筛的催化剂组合物，其大部分微晶在最大直径为约1微米至约15微米之间，掺入无机基质中，其已经用少量的镁化合物，所述浸渍的组合物具有改进的对选择性用于甲苯甲基化成二甲苯。当使用甲醇或二甲醚甲苯甲酸甲酯化时，这种浸渍的组合物与含有标准尺寸（0.2至0.5）的相应的未浸渍或镁化合物浸渍的硼硅酸盐基组合物相比，产生含有非常高比例的对位异构体的二甲苯产物 mu）硼硅酸盐分子筛微晶。

4. 发明授权

US4665254A AMS-1B crystalline borosilicate molecular sieve-based catalyst compositions and process for xylene methylation 失效
标题翻译： AMS-1B结晶硼硅酸盐分子筛催化剂组合物和二甲苯甲基化方法
公开(公告)号：US4665254A
公开(公告)日：1987-05-12
申请号：US801603
申请日：1985-11-25
申请人： Richard E. De Simone
发明人： Richard E. De Simone
IPC分类号： B01J29/86 , C07C2/86 , C07C2/68
CPC分类号： C07C2/864 , B01J29/86 , C07C2/865 , C07C2529/86 , Y02P20/52
摘要： Disclosed are improved HAMS-1B crystalline molecular sieve-based catalyst compositions made by impregnating such a sieve, which has been incorporated in an inorganic matrix, with a small amount of a magnesium compound, and a process for employing such catalyst compositions for the methylation of a xylene in which the amount of pseudocumene in the product is substantially enhanced compared to that produced by the unimpregnated catalyst composition.
摘要翻译：公开了通过用少量的镁化合物浸渍已经掺入无机基质中的筛子制备的改进的HAMS-1B结晶分子筛基催化剂组合物，以及使用这种催化剂组合物用于甲基化的方法其中与未浸渍的催化剂组合物相比，产物中假枯烯的量显着提高的二甲苯。

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