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    • 6. 发明授权
    • Use of ferrous sulfide suspension for the removal of mercury from flue gases
    • 使用硫化亚铁悬浮液从烟气中去除汞
    • US09073008B2
    • 2015-07-07
    • US14200661
    • 2014-03-07
    • Redox Technology Group, LLC
    • Thomas P. McCulloughGary Joel MeyerRalph E. Roper, Jr.Anthony J. Kriech
    • B01D53/64C09K3/00B01D53/80
    • B01D53/64B01D53/80B01D2251/304B01D2253/1128B01D2257/602B01J20/0229B01J20/0285
    • A wet gas scrubber liquor and method of using the same to remove mercury from flue gases. The wet gas scrubber liquid is an alkaline liquid suspension of ferrous sulfide particles that can be prepared by combining together a ferrous ion source such as ferrous chloride, a sulfide ion source such as sodium hydrosulfide and an alkalinity source such as sodium hydroxide. When used to scrub flue gases to remove mercury from flue gases the mercury reacts with said alkaline liquid suspension of ferrous sulfide particles and can be removed by at least one of: i) adsorption onto said ferrous sulfide particles; ii) adsorption onto iron (hydr)-oxides that form in said alkaline liquid suspension of ferrous sulfide particles; and iii) absorption by reacting with sulfur formed in alkaline liquid suspension of ferrous sulfide particles and forming mercuric sulfide as a precipitate.
    • 一种湿气洗涤液及其使用方法,从烟道气中除去汞。 湿气洗涤器液体是硫化亚铁颗粒的碱性液体悬浮液,其可以通过将亚铁离子源如氯化亚铁,硫化氢离子源如氢硫化钠和碱性源如氢氧化钠组合在一起来制备。 当用于洗涤废气以从烟道气中去除汞时,汞与硫化亚铁颗粒的所述碱性液体悬浮液反应,并且可以通过以下至少一种来除去:i)吸附到所述硫化亚铁颗粒上; ii)吸附在硫化亚铁颗粒的所述碱性液体悬浮液中形成的铁(hydr) - 氧化物; 和iii)通过与在硫化亚铁颗粒的碱性液体悬浮液中形成的硫反应形成硫化汞作为沉淀而吸收。