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    • 6. 发明申请
    • OLEFIN POLYMERISATION CATALYST
    • OLEFIN聚合催化剂
    • US20110009257A1
    • 2011-01-13
    • US12886435
    • 2010-09-20
    • Petri REKONENPeter DeniflTimo Leinonen
    • Petri REKONENPeter DeniflTimo Leinonen
    • C08F4/60
    • C08F110/06C08F4/6557C08F4/651C08F2500/12C08F2500/18C08F2500/24
    • The present invention relates to particulate olefin polymerisation catalyst components comprising an alkaline earth metal, a compound of a transition metal and an electron donor, characterized in that the catalyst particle size distribution of the catalyst component is essentially monomodal and has a SPAN value below 1.2, where SPAN is defined as: (Particle diameter at 90% cumulative size)-(Particle diameter at 10% cumulative size)/(Particle diameter at 50% cumulative size). The particulate olefin polymerisation catalyst components of the present invention are provided by a process which comprises preparing a solution of a complex of an alkaline earth metal and an electron donor by reacting a compound of said metal with said electron donor or a precursor thereof in an organic liquid reaction medium, reacting said complex in the solution form with a compound of a transition metal to produce a dispersion, wherein the dispersed phase predominantly contains the alkaline earth metal in said complex, and solidifying said dispersed phase to obtain said catalyst component, and is characterized in that a second organic liquid medium is added to the reactor after mixing the alkaline earth metal complex with the transition metal compound.
    • 本发明涉及包含碱土金属,过渡金属和电子给体的化合物的颗粒状烯烃聚合催化剂组分,其特征在于催化剂组分的催化剂粒度分布基本上是单峰的,SPAN值低于1.2, SPAN定义为:(颗粒直径为90%累积尺寸) - (10%累积尺寸下的粒径)/(50%累积尺寸下的粒径)。 通过一种方法提供本发明的颗粒状烯烃聚合催化剂组分,该方法包括通过使所述金属的化合物与所述电子给体或其前体在有机物中反应制备碱土金属和电子给体的络合物的溶液 液体反应介质,使所述溶液形式的复合物与过渡金属的化合物反应以产生分散体,其中分散相主要包含所述络合物中的碱土金属,并固化所述分散相以获得所述催化剂组分,并且是 其特征在于,在将碱土金属络合物与过渡金属化合物混合后,将第二有机液体介质加入到反应器中。
    • 9. 发明申请
    • PROCESS FOR COATING A PIPE WITH HIGH THROUGHPUT USING MULTIMODAL ETHYLENE COPOLYMER, AND COATED PIPES OBTAINED THEREOF
    • 使用多模乙烯共聚物涂覆高通量管的方法及其所得到的涂层管
    • US20110120587A1
    • 2011-05-26
    • US12808357
    • 2008-12-09
    • Martin AnkerSiw Bodil FredriksenPal Christian BentzrodMats BackmanLeif LeidenMarkku VahteriPetri Rekonen
    • Martin AnkerSiw Bodil FredriksenPal Christian BentzrodMats BackmanLeif LeidenMarkku VahteriPetri Rekonen
    • F16L9/14B05D3/02
    • C09D123/06C08L23/0815C08L2205/025C08L2308/00C08L2666/06
    • The present invention deals with coated pipes having a layer of multimodal polyethylene. The multimodal ethylene copolymer is a copolymer of ethylene with one or more alpha-olefin comonomers having from 4 to 10 carbon atoms and has a weight average molecular weight of from 70000 g/mol to 250000 g/mol, the ratio of the weight average molecular weight to the number average molecular weight, Mw/Mn, of from 15 to 50, a melt index MFR2 of from 0.05 g/10 min to 5 g/10 min, a melt index MFR5 of from 0.5 to 10 g/10 min and a density of from 930 kg/m to 955 kg/m3. Further, the multimodal ethylene copolymer comprises the multimodal ethylene copolymer comprises from 49 to 59% based on the weight of the multimodal ethylene copolymer a low molecular weight ethylene homopolymer component, said low molecular weight ethylene homopolymer having a weight average molecular weight of from 5000 g/mol to 70000 g/mol; and from 51 to 41% based on the weight of the multimodal ethylene copolymer a high molecular weight ethylene copolymer component, said high molecular weight ethylene copolymer having a weight average molecular weight of from 100000 g/mol to 700000 g/mol. The pipes can be coated with high throughput and good production economy. The coatings have good mechanical properties.
    • 本发明涉及具有多峰聚乙烯层的涂覆管。 多峰乙烯共聚物是乙烯与一种或多种具有4-10个碳原子的α-烯烃共聚单体的共聚物,其重均分子量为70000g / mol至250000g / mol,重均分子量 数均分子量Mw / Mn为15-50,熔体指数MFR2为0.05g / 10min至5g / 10min,熔体指数MFR5为0.5-10g / 10min, 密度为930kg / m至955kg / m 3。 此外,多峰乙烯共聚物包含多峰乙烯共聚物,其包含基于多峰乙烯共聚物的重量的49-59%的低分子量乙烯均聚物组分,所述低分子量乙烯均聚物的重均分子量为5000g / mol至70000g / mol; 和基于多峰乙烯共聚物重量的51至41%的高分子量乙烯共聚物组分,所述高分子量乙烯共聚物的重均分子量为100000g / mol至700000g / mol。 管道可以高产量和良好的生产经济性涂层。 涂层具有良好的机械性能。