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    • 3. 发明授权
    • Pyrimidine derivatives herbicides
    • US5604181A
    • 1997-02-18
    • US397123
    • 1995-03-08
    • Thomas L. HoughPeter S. Gates
    • Thomas L. HoughPeter S. Gates
    • C07D239/26A01N43/54A01N43/66A01N47/02A01N47/12A01N47/30A01N47/34C07D239/30C07D239/34C07D239/42C07D239/52C07D251/20C07D239/32
    • C07D251/20A01N43/54A01N47/02A01N47/12A01N47/30A01N47/34C07D239/52
    • Herbicidal compounds of formula (I) and salts thereof, where A is --N.dbd. or --CH.dbd.; X is --OH, --OR.sup.10, --SH, --SR.sup.10, --SCN, NH.sub.2, --NHacyl, --CH.sub.2 OH, --CH.sub.2 OR.sup.9 or --CN; R.sup.1 and R.sup.2, which may be the same or different, each represent alkyl, alkoxy, haloalkyl, haloalkoxy, halo, alkylamino or dialkylamino; R.sup.3 is --CN, --COOR.sup.5, --CONR.sup.6 R.sup.7, --CSNH.sub.2, --CHO, --CH.dbd.Z, --CH(Oalkyl).sub.2, --CH.sub.2 OH, --CH.sub.2 OR.sup.9, --COSR.sup.4a, --CS.sub.2 R.sup.4a, or a substituted or unsubstituted 5- or 6-membered heterocyclic group linked via a ring carbon atom which is between two ring heteroatoms; R.sup.4 and R.sup.4a, which may be the same or different, are each H, or a substituted or unsubstituted alkyl, alkenyl, alkynyl, cycloalkyl, aryl, aralkyl or heteroaryl group; R.sup.5 is H, or a substituted or unsubstituted alkyl, alkenyl, alkynyl, cycoalkyl, aryl, aralkyl or heteroaryl group, or a group of formula (II) where B and D are each alkyl, or together with the carbon atom to which they are attached form a 5-, 6- or 7-membered carbocyclic or heterocyclic ring; R.sup.6 is a group as defined for R.sup.4a, and R.sup.7 is a group as defined for R.sup.4a or is --SO.sub.2 R.sup.8, --OH, --CN, --OR.sup.10, --NH.sub.2 or --NHR.sup.10 ; or R.sup.6 and R.sup.7 together form a ring; R.sup.8 is a substituted or unsubstituted alkyl alkenyl, alkynyl, cycloalkyl, aralkyl, aryl or heteroaryl group, or a group --NR.sup.4b R.sup.4c where R.sup.4b and R.sup.4c, which may be the same or different, are each a group as defined for R.sup.4a, or together form a ring; R.sup.9 is a substituted or unsubstituted alkyl, alkenyl, alkynyl, cycloalkyl, aralkyl or acyl group; R.sup.10 is a substituted or unsubstituted alkyl, alkenyl, alkynyl, cycloalkyl, aryl, aralkyl, heteroaryl or acyl group; Z is .dbd.NOR.sup.4a or .dbd.N--NR.sup.4d R.sup.12, where R.sup.4d is a group as defined for R.sup.4a, and R.sup.1 is a group as defined for R.sup.4a or is a substituted or unsubstituted acyl group, or R.sup.4d and R.sup.12 together form a ring; with the proviso that, when R.sup.4 is ortho-substituted phenyl or naphthyl, any ortho-substituent thereon is halogen, --NO.sub.2, --OH, --OR.sup.10, --SH, --SR.sup.8, --SOR.sup.8, --SO.sub.2 R.sup.8, --NH.sub.2, --NR.sup.6 R.sup.10, aryl or heteroaryl.
    • 4. 发明授权
    • Herbicides
    • 除草剂
    • US5401710A
    • 1995-03-28
    • US87691
    • 1993-07-09
    • Peter S. Gates
    • Peter S. Gates
    • C07D251/22A01N43/54A01N43/64A01N43/66A01N43/70C07D239/26C07D239/46C07D239/47C07D239/52C07D251/46C07D251/52C07D239/42C07D239/48
    • C07D239/47A01N43/54A01N43/66A01N43/70C07D239/52C07D251/46C07D251/52
    • Herbicidal compositions which comprise one or more compounds of the formula: ##STR1## or salts thereof, where: A is --CH.dbd. or --N.dbd.;R.sup.1 is alkyl, alkoxy, halo or --NR.sup.7 R.sup.8 ;R.sup.2 is alkyl or alkoxy;R.sup.3 is hydrogen, alkenyl or alkynyl, or substituted or unsubstituted alkyl, alkanoyl or alkoxycarbonyl;R.sup.4 is hydrogen or substituted or unsubstituted alkyl;R.sup.5 is halo or substituted or unsubstituted alkyl or aryl; andX is --CO.sub.2 R.sup.6, --CONR.sup.7 R.sup.8 or --CN;in which R.sup.6, R.sup.7 and R.sup.8, which may be the same or different, each represent hydrogen, substituted or unsubstituted alkyl, or one of R.sup.7 and R.sup.8 represents substituted amino;in association with a suitable carrier and/or surface active agent, together with the compounds of formula I per se where R.sup.5 represents isopropyl, and/or X represents methoxycarbonyl, and salts thereof.
    • PCT No.PCT / GB92 / 00018 Sec。 371日期:1993年7月9日 102(e)日期1993年7月9日PCT提交1992年1月6日PCT公布。 WO92 / 11763 PCT出版物 日期:1992年7月23日。包含一种或多种下式的化合物或其盐的杀真菌组合物:其中:A为-CH =或-N =; R1是烷基,烷氧基,卤素或-NR7R8; R2是烷基或烷氧基; R3是氢,烯基或炔基,或取代或未取代的烷基,烷酰基或烷氧基羰基; R4是氢或取代或未取代的烷基; R5是卤素或取代或未取代的烷基或芳基; 且X为-CO 2 R 6,-CONR 7 R 8或-CN; 其中可以相同或不同的R 6,R 7和R 8各自表示氢,取代或未取代的烷基,或者R 7和R 8中的一个表示取代的氨基; 与合适的载体和/或表面活性剂以及其中R 5表示异丙基的式I化合物,和/或X表示甲氧基羰基,以及其盐。
    • 6. 发明授权
    • Herbicidally-active sulphonates
    • US4162154A
    • 1979-07-24
    • US875189
    • 1978-02-03
    • Peter S. GatesDerek Baldwin
    • Peter S. GatesDerek Baldwin
    • A01N41/04A01N41/06A01N43/12A01N43/24A01N43/32A01N43/88A01N57/36C07C67/00C07C301/00C07C307/02C07C309/63C07C309/65C07C309/66C07C325/00C07C381/00C07D307/79C07D307/83C07D307/94C07D321/10C07D327/10C07F9/6574A01N9/14C07D307/86
    • C07D307/79A01N41/04A01N41/06A01N43/12A01N43/32A01N43/88A01N57/36C07C309/65C07C309/66C07D307/94C07D321/10C07D327/10C07F9/65744
    • The invention provides herbicidally-active sulphonates of the formula ##STR1## wherein X represents a group --CHR.sup.3 --OR.sup.4 and Y represents a group --OR.sup.5, or X and Y together represent a group --CHR.sup.3 --O-- or a group --CHR.sup.3 --O--Z--O--, the free oxygen atom of which is attached to the benzene ring; R.sup.1, R.sup.2 and R.sup.3, which may be the same or different, each represent hydrogen or C 1 to 6 alkyl, or R.sup.1 and R.sup.2 together or R.sup.2 and R.sup.3 together form a C 3 to 6 alkylene chain; R.sup.4 and R.sup.5, which may be the same or different, each represent hydrogen, C 1 to 6 alkyl, C 2 to 6 alkenyl, C 2 to 6 alkynyl, phenyl, a group --O(.dbd.O)R.sup.10 or a group --SO.sub.2 R.sup.11 ; R.sup.6, R.sup.7 and R.sup.8, which may be the same or different, each represent hydrogen, C 1 to 6 alkyl, halogen, cyano, C 2 to 6 carboxylic acyl, or C 1 to 4 alkoxy; R.sup.9 represents C 1 to 6 alkyl, phenyl or C 7 to 10 phenylalkyl (each of which may be unsubstituted or substituted by one or more chlorine or bromine atoms, C 1 to 4 alkyl groups, C 1 to 4 alkoxy groups or nitro groups), C 5 to 7 cycloalkyl, C 1 to 4 alkylamino, or dialkylamino wherein each alkyl moiety has from 1 to 4 carbon atoms; R.sup.10 represents C 1 to 6 alkyl or alkoxy, C 2 to 6 alkenyl or alkenyloxy, C 2 to 6 alkynyl or alkynyloxy, phenyl, phenoxy, phenylamino, C 1 to alkylamino alylamino or dialkylamino wherein each alkyl moiety has from 1 to 6 carbon atoms, each of the groups which R.sup.10 may represent being unsubstituted or substituted by one or more halogen atoms or C 1 to 4 alkoxy groups; R.sup.11 represents C 1 to 6 alkyl, phenyl, C 1 to 6 alkylamino or dialkylamino each of the alkyl moieties thereof having from 1 to 6 carbon atoms, each of the groups which R.sup.11 may represent being unsubstituted or substituted by one or more halogen atoms or C 1 to 4 alkoxy groups; Z represents a group of formula--S(.dbd.O)n, --CR.sup.12 R.sup.13 or --P(.dbd.Q)(OR.sup.14)--;n represents 1 or 2; R.sup.12 and R.sup.13, which may be the same or different, each represent hydrogen, C 1 to 6 alkyl or alkoxy, C 2 to 6 alkenyl or alkynyl, phenyl, phenoxy, cyano or (C 1 to 6 alkoxy)carbonyl, or R.sup.12 and R.sup.13 together represent an oxygen atom, a sulphur atom, a C 3 to 6 alkylene chain or a C 1 to 6 alkylimino group or a phenylimino group; and R.sup.14 represents C 1 to 6 alkyl; and Q represents oxygen or sulphur, together with processes for their preparation and herbicidal compositions containing them.
    • 8. 发明授权
    • Herbicides
    • 除草剂
    • US4795483A
    • 1989-01-03
    • US43370
    • 1987-04-28
    • Peter S. Gates
    • Peter S. Gates
    • A01N43/90A01P13/00C07D249/08C07D277/80C07D513/04C07D519/00C07D521/00
    • C07D513/04A01N43/90
    • The invention provides certain herbicidal thiazolotriazole sulphonamides, processes for their preparation, and compositions containing them, the compounds being of the formula: ##STR1## where: R.sup.1 and R.sup.2, which may be the same or different, each represent hydrogen, hydroxy, halo, cyano, substituted or unsubstituted alkyl, alkoxy, alkenyloxy, alkynyloxy, aryl, aralkyl, heteroaryl or carbamoyl, or a group --COR.sup.a or --CO.sub.2 R.sup.a or where R.sup.a is hydrogen or alkyl; or R.sup.1 and R.sup.2 together represent an alkylene chain of 3 or 4 carbon atoms;R.sup.3 represents a substituted or unsubstituted aryl, heterocyclyl or benzheterocyclyl group; andR.sup.4 represents hydrogen, an alkali-metal atom, an ammonium group, a substituted or unsubstituted alkyl, alkenyl, alkynyl, acyl, alkoxycarbonyl or aralkyl group, a heterocyclic group, or a group of the formula: ##STR2## where R.sup.1 and R.sup.2 are as defined hereinbefore.
    • 本发明提供了某些除草噻唑并三唑磺酰胺,其制备方法和含有它们的组合物,该化合物具有下式:其中:R 1和R 2可以相同或不同,各自代表氢,羟基 卤素,氰基,取代或未取代的烷基,烷氧基,烯氧基,炔氧基,芳基,芳烷基,杂芳基或氨基甲酰基,或基团-CORa或-CO 2 R a,或其中R a为氢或烷基; 或R 1和R 2一起表示3或4个碳原子的亚烷基链; R3表示取代或未取代的芳基,杂环基或苯并杂环基; 和R 4表示氢,碱金属原子,铵基,取代或未取代的烷基,烯基,炔基,酰基,烷氧基羰基或芳烷基,杂环基或下式的基团:其中 R1和R2如上文所定义。