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1. 发明授权

US09011734B2 Ligand exchange thermochromic, (LETC), systems 有权
公开(公告)号：US09011734B2
公开(公告)日：2015-04-21
申请号：US13230435
申请日：2011-09-12
申请人： Harlan J. Byker , Paul H. Ogburn, Jr. , Douglas A. Vander Griend , Brad S. Veldkamp , Derick D. Winkle
发明人： Harlan J. Byker , Paul H. Ogburn, Jr. , Douglas A. Vander Griend , Brad S. Veldkamp , Derick D. Winkle
IPC分类号： C09K9/00 , G02F1/00 , C09K9/02 , G02F1/01 , G02F1/15 , G09G3/34
CPC分类号： C09K9/02 , B32B17/10036 , B32B17/10174 , B32B17/10477 , B32B17/10651 , B32B17/10678 , B32B17/10761 , C09K2211/187 , G02F1/0147 , B32B17/10 , B32B2367/00 , B32B2369/00
摘要： Ligand exchange of thermochromic, LETC, systems exhibiting a reversible change in absorbance of electromagnetic radiation as the temperature of the system is reversibly changed are described. The described LETC systems include one or more than one transition metal ion, which experiences thermally induced changes in the nature of the complexation or coordination around the transition metal ion(s) and, thereby, the system changes its ability to absorb electromagnetic radiation as the temperature changes.

2. 发明申请

US20120292581A1 LIGAND EXCHANGE THERMOCHROMIC SYSTEMS AND HIGH E LIGANDS FOR SAME 有权
标题翻译：配套交换式热电偶系统和高电压配置
公开(公告)号：US20120292581A1
公开(公告)日：2012-11-22
申请号：US13477736
申请日：2012-05-22
申请人： Harlan J. Byker , Paul H. Ogburn, JR. , Douglas A. Vander Griend , Brad S. Veldkamp , Derick D. Winkle
发明人： Harlan J. Byker , Paul H. Ogburn, JR. , Douglas A. Vander Griend , Brad S. Veldkamp , Derick D. Winkle
IPC分类号： C09K9/02
CPC分类号： C09K9/02 , B32B17/10036 , B32B17/10174 , B32B17/10477 , B32B17/10651 , B32B17/10678 , B32B17/10761 , C09K2211/187 , G02F1/0147 , B32B17/10 , B32B2367/00 , B32B2369/00
摘要： Ligand exchange of thermochromic, LETC, systems exhibiting a reversible change in absorbance of electromagnetic radiation as the temperature of the system is reversibly changed are described. The described LETC systems include one or more than one transition metal ion, which experiences thermally induced changes in the nature of the complexation or coordination around the transition metal ion(s) and, thereby, the system changes its ability to absorb electromagnetic radiation as the temperature changes.In accordance with certain aspects of the present invention, thermochromic systems are disclosed comprising a transition metal ion with particularly useful ligands, such as phosphine compounds, tridentate ligands that coordinate through three nitrogen atoms, bidentate ligands, or ortho hindered pyridine monodentate ligands.
摘要翻译：描述了随着系统温度的可逆变化，热致变色LETC，电磁辐射吸收率呈现可逆变化的系统的配位交换。所描述的LETC系统包括一个或多于一个的过渡金属离子，其经历过渡金属离子周围的络合或配位性质的热诱导变化，从而系统改变其吸收电磁辐射的能力，如温度变化。根据本发明的某些方面，公开了包含具有特别有用配体的过渡金属离子的热致变色体系，例如膦化合物，通过三个氮原子配位的三齿配体，二齿配体或邻位受体吡啶单齿配位体。

3. 发明授权

US08018639B2 Ligand exchange thermochromic, (LETC), systems 有权
标题翻译：配体交换热变色（LETC），系统
公开(公告)号：US08018639B2
公开(公告)日：2011-09-13
申请号：US12474932
申请日：2009-05-29
申请人： Harlan J. Byker , Paul H. Ogburn, Jr. , Douglas A. Vander Griend , Brad S. Veldkamp , Derick D. Winkle
发明人： Harlan J. Byker , Paul H. Ogburn, Jr. , Douglas A. Vander Griend , Brad S. Veldkamp , Derick D. Winkle
IPC分类号： G02F1/01 , G02F1/15 , G09G3/34
CPC分类号： C09K9/02 , B32B17/10036 , B32B17/10174 , B32B17/10477 , B32B17/10651 , B32B17/10678 , B32B17/10761 , C09K2211/187 , G02F1/0147 , B32B17/10 , B32B2367/00 , B32B2369/00
摘要： Ligand exchange of thermochromic, LETC, systems exhibiting a reversible change in absorbance of electromagnetic radiation as the temperature of the system is reversibly changed are described. The described LETC systems include one or more than one transition metal ion, which experiences thermally induced changes in the nature of the complexation or coordination around the transition metal ion(s) and, thereby, the system changes its ability to absorb electromagnetic radiation as the temperature changes.
摘要翻译：描述了随着系统温度的可逆变化，热致变色LETC，电磁辐射吸收率呈现可逆变化的系统的配位交换。所描述的LETC系统包括一个或多于一个的过渡金属离子，其经历过渡金属离子周围的络合或配位性质的热诱导变化，从而系统改变其吸收电磁辐射的能力，如温度变化。

4. 发明授权

US07525717B2 Multi-layer ligand exchange thermochromic systems 有权
标题翻译：多层配体交换热变色系统
公开(公告)号：US07525717B2
公开(公告)日：2009-04-28
申请号：US11849659
申请日：2007-09-04
申请人： Harlan J. Byker , Frederick A. Millett , Paul H. Ogburn, Jr. , Douglas A. Vander Griend , Brad S. Veldkamp , Derick D. Winkle
发明人： Harlan J. Byker , Frederick A. Millett , Paul H. Ogburn, Jr. , Douglas A. Vander Griend , Brad S. Veldkamp , Derick D. Winkle
IPC分类号： G02F1/01 , G02F1/00 , G09G3/34 , C07F15/04
CPC分类号： C09K9/02 , B32B17/10036 , B32B17/10174 , B32B17/10477 , B32B17/10651 , B32B17/10678 , B32B17/10761 , C09K2211/187 , G02F1/0147 , B32B17/10 , B32B2367/00 , B32B2369/00
摘要： Ligand exchange of thermochromic, LETC, systems exhibiting a reversible change in absorbance of electromagnetic radiation as the temperature of the system is reversibly changed are described. The described LETC systems include one or more than one transition metal ion, which experiences thermally induced changes in the nature of the complexation or coordination around the transition metal ion(s) and, thereby, the system changes its ability to absorb electromagnetic radiation as the temperature changes.In accordance with one aspect of the present invention, a thermochromic device is disclosed comprising at least two thermochromic layers when each thermochromic layer includes a polymer, at least one transition metal ion, at least one HεL ligand capable of forming a HεMLC with the transition metal ion and at least one LεL ligand capable of forming an LεMLC with the transition metal ion. In accordance with yet another aspect of the present invention, the thermochromic device further includes a separator between the first and second thermochromic layers to prevent intermixing of the contents of the layers.
摘要翻译：描述了随着系统温度的可逆变化，热致变色LETC，电磁辐射吸收率呈现可逆变化的系统的配位交换。所描述的LETC系统包括一个或多于一个的过渡金属离子，其经历过渡金属离子周围的络合或配位性质的热诱导变化，从而系统改变其吸收电磁辐射的能力，如温度变化。根据本发明的一个方面，公开了一种热致变色装置，其包含至少两个热致变色层，当每个热变色层包括聚合物，至少一种过渡金属离子，至少一种能够与过渡金属形成HepsilonMLC的HepsilonL配体离子和能够与过渡金属离子形成LepsilonMLC的至少一种Lepsilon配体。根据本发明的另一方面，热致变色装置还包括在第一和第二热变色层之间的隔板，以防止层的内容物的混合。

5. 发明授权

US07817328B2 Thermochromic window structures 有权
标题翻译：热变色窗结构
公开(公告)号：US07817328B2
公开(公告)日：2010-10-19
申请号：US11849704
申请日：2007-09-04
申请人： Frederick A. Millett , Michael D. Broekhuis , Harlan J. Byker , Paul H. Ogburn, Jr.
发明人： Frederick A. Millett , Michael D. Broekhuis , Harlan J. Byker , Paul H. Ogburn, Jr.
IPC分类号： G02F1/01 , G02F1/15
CPC分类号： C09K9/02 , B32B17/10036 , B32B17/10174 , B32B17/10477 , B32B17/10651 , B32B17/10678 , B32B17/10761 , C09K2211/187 , G02F1/0147 , B32B17/10 , B32B2367/00 , B32B2369/00
摘要： An energy efficient, thermochromic device that may be used to allow sunlight or solar radiation into a building or structure when sunlight is absent or at high sun angles and substantially blocks solar radiation when sunlight is directly on the window.
摘要翻译：一种节能的热变色装置，当太阳光不存在或处于高太阳角时，可用于将太阳光或太阳辐射照射到建筑物或结构中，并且当太阳直接在窗户上时基本上阻挡太阳辐射。

6. 发明授权

US07542196B2 Ligand exchange thermochromic, (LETC), systems 有权
标题翻译：配体交换热变色（LETC），系统
公开(公告)号：US07542196B2
公开(公告)日：2009-06-02
申请号：US11849574
申请日：2007-09-04
申请人： Harlan J. Byker , Paul H. Ogburn, Jr. , Douglas A. Vander Griend , Brad S. Veldkamp , Derick D. Winkle
发明人： Harlan J. Byker , Paul H. Ogburn, Jr. , Douglas A. Vander Griend , Brad S. Veldkamp , Derick D. Winkle
IPC分类号： G02F1/01 , G02F1/15 , G09G3/34
CPC分类号： C09K9/02 , B32B17/10036 , B32B17/10174 , B32B17/10477 , B32B17/10651 , B32B17/10678 , B32B17/10761 , C09K2211/187 , G02F1/0147 , B32B17/10 , B32B2367/00 , B32B2369/00
摘要： Ligand exchange of thermochromic, LETC, systems exhibiting a reversible change in absorbance of electromagnetic radiation as the temperature of the system is reversibly changed are described. The described LETC systems include one or more than one transition metal ion, which experiences thermally induced changes in the nature of the complexation or coordination around the transition metal ion(s) and, thereby, the system changes its ability to absorb electromagnetic radiation as the temperature changes.
摘要翻译：描述了随着系统温度的可逆变化，热致变色LETC，电磁辐射吸收率呈现可逆变化的系统的配位交换。所描述的LETC系统包括一个或多于一个的过渡金属离子，其经历过渡金属离子周围的络合或配位性质的热诱导变化，从而系统改变其吸收电磁辐射的能力，如温度变化。

7. 发明授权

US08431045B2 Ligand exchange thermochromic systems and high ε ligands for same 有权
标题翻译：配体交换热变色体系和高ε配体相同
公开(公告)号：US08431045B2
公开(公告)日：2013-04-30
申请号：US13477736
申请日：2012-05-22
申请人： Harlan J. Byker , Paul H. Ogburn, Jr. , Douglas A. Vander Griend , Brad S. Veldkamp , Derick D. Winkle
发明人： Harlan J. Byker , Paul H. Ogburn, Jr. , Douglas A. Vander Griend , Brad S. Veldkamp , Derick D. Winkle
IPC分类号： G01N31/00
CPC分类号： C09K9/02 , B32B17/10036 , B32B17/10174 , B32B17/10477 , B32B17/10651 , B32B17/10678 , B32B17/10761 , C09K2211/187 , G02F1/0147 , B32B17/10 , B32B2367/00 , B32B2369/00
摘要： Ligand exchange of thermochromic, LETC, systems exhibiting a reversible change in absorbance of electromagnetic radiation as the temperature of the system is reversibly changed are described. The described LETC systems include one or more than one transition metal ion, which experiences thermally induced changes in the nature of the complexation or coordination around the transition metal ion(s) and, thereby, the system changes its ability to absorb electromagnetic radiation as the temperature changes. In accordance with certain aspects of the present invention, thermochromic systems are disclosed comprising a transition metal ion with particularly useful ligands, such as phosphine compounds, tridentate ligands that coordinate through three nitrogen atoms, bidentate ligands, or ortho hindered pyridine monodentate ligands.
摘要翻译：描述了随着系统温度的可逆变化，热致变色LETC，电磁辐射吸收率呈现可逆变化的系统的配位交换。所描述的LETC系统包括一个或多于一个的过渡金属离子，其经历过渡金属离子周围的络合或配位性质的热诱导变化，从而系统改变其吸收电磁辐射的能力，如温度变化。根据本发明的某些方面，公开了包含具有特别有用配体的过渡金属离子的热致变色体系，例如膦化合物，通过三个氮原子配位的三齿配体，二齿配体或邻位受体吡啶单齿配位体。

8. 发明授权

US08182718B2 Ligand exchange thermochromic systems and high ε ligands for same 有权
标题翻译：配体交换热变色系统配体相同
公开(公告)号：US08182718B2
公开(公告)日：2012-05-22
申请号：US11849624
申请日：2007-09-04
申请人： Harlan J. Byker , Paul H. Ogburn, Jr. , Douglas A. Vander Griend , Brad S. Veldkamp , Derick D. Winkle
发明人： Harlan J. Byker , Paul H. Ogburn, Jr. , Douglas A. Vander Griend , Brad S. Veldkamp , Derick D. Winkle
IPC分类号： G01N31/00
CPC分类号： C09K9/02 , B32B17/10036 , B32B17/10174 , B32B17/10477 , B32B17/10651 , B32B17/10678 , B32B17/10761 , C09K2211/187 , G02F1/0147 , B32B17/10 , B32B2367/00 , B32B2369/00
摘要： Ligand exchange of thermochromic, LETC, systems exhibiting a reversible change in absorbance of electromagnetic radiation as the temperature of the system is reversibly changed are described. The described LETC systems include one or more than one transition metal ion, which experiences thermally induced changes in the nature of the complexation or coordination around the transition metal ion(s) and, thereby, the system changes its ability to absorb electromagnetic radiation as the temperature changes.In accordance with certain aspects of the present invention, a thermochromic system is disclosed comprising a transition metal ion and a ligand wherein the ligand comprises a nitrogen-containing five or six membered heterocyclic compound that coordinates through the nitrogen atom to the transition metal ion in a HεMLC formed between the transition metal ion and the ligand.In accordance with other aspects of the present invention, thermochromic systems are disclosed comprising a transition metal ion with particularly useful ligands, such as phosphine compounds, tridentate ligands that coordinate through three nitrogen atoms, bidentate ligands, or ortho hindered pyridine monodentate ligands.
摘要翻译：描述了随着系统温度的可逆变化，热致变色LETC，电磁辐射吸收率呈现可逆变化的系统的配位交换。所描述的LETC系统包括一个或多于一个的过渡金属离子，其经历过渡金属离子周围的络合或配位性质的热诱导变化，从而系统改变其吸收电磁辐射的能力，如温度变化。根据本发明的某些方面，公开了一种包含过渡金属离子和配体的热致变色体系，其中配体包括通过氮原子与过渡金属离子配位的含氮五或六元杂环化合物在过渡金属离子和配体之间形成H＆amp; MLC。根据本发明的其他方面，公开了包含具有特别有用的配体的过渡金属离子的热致变色体系，例如膦化合物，通过三个氮原子配位的三齿配体，二齿配体或邻位受体吡啶单齿配体。

9. 发明授权

US08154788B2 Thermochromic window structures 有权
标题翻译：热变色窗结构
公开(公告)号：US08154788B2
公开(公告)日：2012-04-10
申请号：US12906704
申请日：2010-10-18
申请人： Frederick A. Millett , Michael D. Broekhuis, Jr. , Harlan J. Byker , Paul H. Ogburn, Jr.
发明人： Frederick A. Millett , Michael D. Broekhuis, Jr. , Harlan J. Byker , Paul H. Ogburn, Jr.
IPC分类号： G02F1/01 , G02F1/15
CPC分类号： C09K9/02 , B32B17/10036 , B32B17/10174 , B32B17/10477 , B32B17/10651 , B32B17/10678 , B32B17/10761 , C09K2211/187 , G02F1/0147 , B32B17/10 , B32B2367/00 , B32B2369/00
摘要： An energy efficient, thermochromic device that may be used to allow sunlight or solar radiation into a building or structure when sunlight is absent or at high sun angles and substantially blocks solar radiation when sunlight is directly on the window.
摘要翻译：一种节能的热变色装置，当太阳光不存在或处于高太阳角时，可用于将太阳光或太阳辐射照射到建筑物或结构中，并且当太阳直接在窗户上时基本上阻挡太阳辐射。

10. 发明申请

US20090283728A1 LIGAND EXCHANGE THERMOCHROMIC, (LETC), SYSTEMS 有权
标题翻译： LIGAND EXCHANGE THERMOCHROMIC，（LETC），SYSTEMS
公开(公告)号：US20090283728A1
公开(公告)日：2009-11-19
申请号：US12474932
申请日：2009-05-29
申请人： Harlan J. Byker , Paul H. Ogburn, JR. , Douglas A. Vander Griend , Brad S. Veldkamp , Derick D. Winkle
发明人： Harlan J. Byker , Paul H. Ogburn, JR. , Douglas A. Vander Griend , Brad S. Veldkamp , Derick D. Winkle
IPC分类号： G02B5/23
CPC分类号： C09K9/02 , B32B17/10036 , B32B17/10174 , B32B17/10477 , B32B17/10651 , B32B17/10678 , B32B17/10761 , C09K2211/187 , G02F1/0147 , B32B17/10 , B32B2367/00 , B32B2369/00
摘要： Ligand exchange of thermochromic, LETC, systems exhibiting a reversible change in absorbance of electromagnetic radiation as the temperature of the system is reversibly changed are described. The described LETC systems include one or more than one transition metal ion, which experiences thermally induced changes in the nature of the complexation or coordination around the transition metal ion(s) and, thereby, the system changes its ability to absorb electromagnetic radiation as the temperature changes.
摘要翻译：描述了随着系统温度的可逆变化，热致变色LETC，电磁辐射吸收率呈现可逆变化的系统的配位交换。所描述的LETC系统包括一个或多于一个的过渡金属离子，其经历过渡金属离子周围的络合或配位性质的热诱导变化，从而系统改变其吸收电磁辐射的能力，如温度变化。

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