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1. 发明授权

US5340681A Method for preparing photographic elements having single photosensitive layer containing photopolymerizable compound, photoinitiator, diazonium compound and barrier material encapsulated pigment particles; and negative image formation process 失效
标题翻译：制备具有含有光聚合化合物，光引发剂，重氮化合物和阻隔材料包封的颜料颗粒的单一光敏层的照相元件的方法。和负图像形成过程
公开(公告)号：US5340681A
公开(公告)日：1994-08-23
申请号：US148757
申请日：1993-11-05
申请人： Maria T. Sypek , Paul A. Perron , Gary V. Grosclaude
发明人： Maria T. Sypek , Paul A. Perron , Gary V. Grosclaude
IPC分类号： G03F7/004 , G03F7/027 , G03F7/095 , G03F7/105 , G03F7/021 , G03F7/30
CPC分类号： G03F7/004 , G03F7/027 , G03F7/0955 , G03F7/105
摘要： Photopolymeric printing plates are presented wherein and electrochemically etched and anodized, silicated aluminum substrate has a single photosensitive coating thereon composed of a photopolymerizable combination which includes a photopolymerizable pigment dispersion, a photosensitive lithographic diazonium resin, multifunctional acrylate oligomer, multifunctional acrylate monomer, photopolymerizable binder and photoinitiator to yield a non-tacky, mar resistant, easily developed durable plate. In a preferred embodiment, an additional aqueous, non-photosensitive overcoat is applied over the initial coating to retard oxygen inhibition.
摘要翻译：提供了光聚合印刷板，其中电化学蚀刻和阳极氧化，硅酸铝基板在其上具有由可光聚合的组合组成的单一感光涂层，其包含可光聚合的颜料分散体，光敏平版印刷重氮树脂，多官能丙烯酸酯低聚物，多官能丙烯酸酯单体，可光聚合的粘合剂和光引发剂产生非粘性，耐磨损，易开发的耐用板。在优选的实施方案中，在初始涂层上施加另外的水性非光敏外涂层以延缓氧的抑制。

2. 发明授权

US07867691B2 Heated water spray processor 失效
标题翻译：加热喷水处理器
公开(公告)号：US07867691B2
公开(公告)日：2011-01-11
申请号：US12215124
申请日：2008-06-25
申请人： Howard A. Fromson , William J. Ryan , William J. Rozell , Paul A. Perron
发明人： Howard A. Fromson , William J. Ryan , William J. Rozell , Paul A. Perron
IPC分类号： G03F7/26
CPC分类号： G03D5/00 , G03F7/3042 , G03F7/305
摘要： Excellent development of planographic printing plates can be achieved by exposing an imaged, negative working, photopolymerizable coating to a high pressure stream of essentially heated but otherwise untreated tap water, whereby the water completely removes only the less cohesive and adhesive (e.g., partially polymerized) regions to the substrate, thereby directly producing a printing plate having an image pattern of highly cohesive and adhesive, oleophilic regions of the coating and hydrophilic regions of the substrate. The coating removal mechanism appears to be due entirely to ablation. The process variables of spray pressure, spray volumetric flow rate, and water temperature can be traded off to achieve one or more targets for plate quality, energy conservation, production rate, and equipment availability.
摘要翻译：通过将成像的负性可光聚合涂层暴露于基本上加热但未经处理的自来水的高压流，可以实现平版印刷版的优异发展，由此水完全除去较少的内聚和粘合剂（例如，部分聚合的）区域，从而直接制造具有高粘合性和粘合性的图像图案的印刷版，涂层的亲油性区域和基材的亲水区域。涂层去除机制似乎完全归因于消融。喷涂压力，喷雾体积流量和水温的过程变量可以交付，以实现板材质量，节能，生产率和设备可用性的一个或多个目标。

3. 发明授权

US07816065B2 Imageable printing plate for on-press development 有权
标题翻译：可印版印刷版
公开(公告)号：US07816065B2
公开(公告)日：2010-10-19
申请号：US11493183
申请日：2006-07-26
申请人： Howard A. Fromson , William J. Rozell , William J. Ryan , Paul A. Perron
发明人： Howard A. Fromson , William J. Rozell , William J. Ryan , Paul A. Perron
IPC分类号： G03F7/00 , C08F2/00
CPC分类号： G03F7/027 , B41C1/1008 , B41C2210/04 , B41C2210/08 , B41C2210/22 , B41C2210/24
摘要： A novel coating for lithographic printing plates can be imagewise exposed to radiation and then directly processed with only water to remove the non-exposed regions of the coating. The coating comprises a polymer, a monomer and/or oligomer, polymerization or cross link initiator, stabilizer, and dye or pigment, such that after imaging, the non-imaged resin areas are removable from the planar surface by penetration of water through the non-imaged coating without dissolution of the resin components of the coating, to form a lithographic printing plate with clearly defined image and non-image areas. The stabilizer is a solvent soluble, partially water soluble, non-polymerizable organic component that enables the coating to be removable by water in the non-cross linked areas.
摘要翻译：用于平版印刷版的新颖涂层可以成像曝光于辐射，然后仅用水直接处理以除去涂层的未曝光区域。涂层包括聚合物，单体和/或低聚物，聚合或交联引发剂，稳定剂和染料或颜料，使得在成像之后，未成像的树脂区域可通过水穿过非平面表面从平面表面移除而不会溶解涂层的树脂组分，以形成具有清晰定义的图像和非图像区域的平版印刷版。稳定剂是溶剂可溶，部分水溶性，不可聚合的有机成分，使得涂层能够在非交联区域中被水除去。

4. 发明授权

US5543262A Benzanthrone polymerization gate in photopolymerizable compositions 失效
标题翻译：可光聚合组合物中的苯甲酮聚合门
公开(公告)号：US5543262A
公开(公告)日：1996-08-06
申请号：US393969
申请日：1995-02-24
申请人： Maria T. Sypek , John R. Delude , Paul A. Perron
发明人： Maria T. Sypek , John R. Delude , Paul A. Perron
IPC分类号： G03F7/004 , C08F2/50 , G03F7/00 , G03F7/021 , G03F7/027 , G03F7/038 , G03F7/09 , G03F7/016 , G03F7/30
CPC分类号： G03F7/091 , Y10S430/117 , Y10S430/118 , Y10S430/119 , Y10S430/12 , Y10S430/121 , Y10S430/122 , Y10S430/123 , Y10S430/124
摘要： A light sensitive composition which is capable of photopolymerization which includes a photopolymerizable compound a free radical generating component and a benzanthrone or substituted benzanthrone which substantially prevents photopolymerization when the light sensitive composition is exposed to actinic radiation below a threshold amount but permits photopolymerization when the light sensitive composition is exposed to actinic radiation above a threshold amount. This achieves a gate effect which eliminates or decreases unwanted partial exposure in the nonimage areas and hence improves reproduction quality.
摘要翻译：能够光聚合的光敏组合物，其包含可光聚合化合物，自由基产生组分和苯醌或取代苯醌，当光敏组合物暴露于低于阈值量的光化辐射时，其基本上防止光聚合，但当光敏组合物暴露于高于阈值量的光化辐射。这实现了在非图像区域中消除或减少不期望的部分曝光并因此提高再现质量的栅极效应。

5. 发明授权

US07700266B2 Water spray development of planographic plates 失效
标题翻译：平版印刷板的喷水发展
公开(公告)号：US07700266B2
公开(公告)日：2010-04-20
申请号：US11821721
申请日：2007-06-25
申请人： Howard A. Fromson , William J. Ryan , William J. Rozell , Paul A. Perron
发明人： Howard A. Fromson , William J. Ryan , William J. Rozell , Paul A. Perron
IPC分类号： G03F7/26
CPC分类号： G03F7/322 , G03F7/30
摘要： Excellent development of planographic printing plates can be achieved by exposing an imaged, negative working, photopolymerizable coating to a high pressure stream of essentially untreated tap water, whereby the water completely removes only the less cohesive and adhesive (e.g., partially polymerized) regions to the substrate, thereby directly producing a printing plate having an image pattern of highly cohesive and adhesive, oleophilic regions of the coating and hydrophilic regions of the substrate. The coating removal mechanism appears to be due entirely to ablation. The high pressure stream is preferably delivered to the plate through at least one nozzle having a discharge pressure greater than about 200 psi. Each nozzle preferably has a spray pattern that impinges the plate over a substantially rectangular region of the plate, and the nozzle and plate translate relative to each other. The nozzle can reciprocate across the width of a longitudinally transported plate, thereby contacting successive regions of the plate in a rastering fashion.
摘要翻译：平版印刷版的优异发展可以通过将成像的，负性的可光聚合涂层暴露于基本上未处理的自来水的高压流中，由此水完全除去较少的内聚力和粘合剂（例如，部分聚合的）区域从而直接制造具有高度粘合和粘合的图像图案的印刷版，涂层的亲油区域和基底的亲水区域。涂层去除机制似乎完全归因于消融。高压流优选通过具有大于约200psi的排出压力的至少一个喷嘴输送到板。每个喷嘴优选地具有将板撞击在板的基本矩形区域上的喷射图案，并且喷嘴和板相对于彼此平移。喷嘴可以横跨纵向传送的板的宽度往复运动，从而以划痕方式接触板的连续区域。

6. 发明授权

US07229739B2 Positive working thermal plates 失效
标题翻译：正面工作热板
公开(公告)号：US07229739B2
公开(公告)日：2007-06-12
申请号：US11137179
申请日：2005-05-25
申请人： Paul A. Perron , Brian L. Anderson , William J. Ryan
发明人： Paul A. Perron , Brian L. Anderson , William J. Ryan
IPC分类号： G03F7/039 , G03F7/14 , G03F7/30
CPC分类号： B41C1/1008 , B41C2210/02 , B41C2210/06 , B41C2210/22 , B41C2210/24 , B41C2210/262 , C08K5/05 , G03F7/0045 , G03F7/0226 , Y10S430/106 , Y10S430/11 , Y10S430/119 , Y10S430/165 , C08L101/06
摘要： The invention generally relates to positive-working coating compositions and to a substrate formed with a coating of that composition. Advantageous versions of the invention provide an infrared imageable, positive lithographic printing plate having a coating comprising a hydroxy substituted polymer, a diphenylcarbinol solubility suppressing compound and an infrared radiation absorbing compound.
摘要翻译：本发明一般涉及正性涂料组合物和形成有该组合物的涂层的基材。本发明的有利方案提供了具有包含羟基取代的聚合物，二苯基甲醇溶解度抑制化合物和红外辐射吸收化合物的涂层的可红外成像的正版印刷版。

7. 发明授权

US5286594A Photographic elements utilizing a single photosensitive layer containing a photopolymerizable compound, photoinitiator, diazonium compound and barrier material encapsulated pigment particles 失效
标题翻译：使用含有可光聚合化合物，光引发剂，重氮化合物和阻隔材料的单一感光层的照相元件包封的颜料颗粒
公开(公告)号：US5286594A
公开(公告)日：1994-02-15
申请号：US897319
申请日：1992-06-11
申请人： Maria T. Sypek , Paul A. Perron , Gary V. Grosclaude
发明人： Maria T. Sypek , Paul A. Perron , Gary V. Grosclaude
IPC分类号： B41N1/04 , B41N3/03 , G03F7/00 , G03F7/004 , G03F7/021 , G03F7/027 , G03F7/028 , G03F7/038 , G03F7/095 , G03F7/105 , G03F7/11 , G03F7/09
CPC分类号： G03F7/027 , G03F7/004 , G03F7/0955 , G03F7/105
摘要： Photopolymeric printing plates are presented wherein an electrochemically etched and anodized, silicated aluminum substrate has a single photosensitive coating thereon composed of a photopolymerizable combination which includes a photopolymerizable pigment dispersion, a photosensitive lithographic diazonium resin, multifunctional acrylate oligomer, multifunctional acrylate monomer, photopolymerizable binder and photoinitiator to yield a non-tacky, mar resistant, easily developed durable plate. In a preferred embodiment, an additional aqueous, non-photosensitive overcoat is applied over the initial coating to retard oxygen inhibition.
摘要翻译：提出了一种光电聚合印刷板，其中电化学蚀刻和阳极氧化的硅酸铝基板在其上具有由光聚合组合构成的单一感光涂层，其包含可光聚合的颜料分散体，光敏平版印刷重氮树脂，多官能丙烯酸酯低聚物，多官能丙烯酸酯单体，可光聚合的粘合剂和光引发剂产生非粘性，耐磨损，易开发的耐用板。在优选的实施方案中，在初始涂层上施加另外的水性非光敏外涂层以延缓氧的抑制。

8. 发明授权

US5837586A 4-(alkoxyhydroxy)styryl triazine photinitiators and photo sensitive composition 失效
标题翻译： 4-（烷氧基羟基）苯乙烯基三嗪光子引发剂和光敏组合物
公开(公告)号：US5837586A
公开(公告)日：1998-11-17
申请号：US801735
申请日：1997-02-14
申请人： Paul A. Perron
发明人： Paul A. Perron
IPC分类号： G03F7/004 , C08F2/50 , C08F4/00 , C09D4/00 , G03F7/00 , G03F7/027 , G03F7/029 , G03F7/031 , G03F7/033 , G03C1/725 , C07D251/00
CPC分类号： G03F7/0295 , Y10S430/121 , Y10S430/127
摘要： Provided are 4-(alkoxyhydroxy)styryl triazine photoinitiator compounds having the formula: ##STR1## wherein n is 3 or 4, as well as photopolymerizable compositions and photographic elements containing such photoinitiator compounds. These photoinitiator compounds improve the reproduction quality of photographic elements such as lithographic printing plates since the photosensitive compositions in which they are incorporated are resistant to surface blooming.
摘要翻译：提供具有下式的4-（烷氧基羟基）苯乙烯基三嗪光引发剂化合物：含有这种光引发剂化合物的照相组合物和照相元件。这些光引发剂化合物改善了摄影元件如平版印刷版的再现质量，因为它们所掺入的光敏组合物对表面起霜具有抗性。

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