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    • 3. 发明申请
    • TRANSPARENT POLYCARBONATE-POLYESTER BLENDS WITH IMPROVED PERFORMANCE UNDER CAUSTIC AQUEOUS ENVIRONMENTS
    • 透明聚碳酸酯 - 聚酯纤维,具有改善性能的原始环境环境
    • US20080000917A1
    • 2008-01-03
    • US11612937
    • 2006-12-19
    • Parminder AgarwalRodney W. Fonseca
    • Parminder AgarwalRodney W. Fonseca
    • C08G59/00A47G19/12
    • C08L69/005C08K5/52C08L67/02C08L69/00C08L2666/18
    • A composition comprising a clear thermoplastic blend comprising: (a) a polycarbonate component; and (b) a polyester component comprising (i) a polyester based substantially on 1,4 cyclohexane dimethanol and terephthalic acid monomer units, (ii) copolymers polyester based substantially on 1,4 cyclohexane dimethanol and terephthalic acid monomer units and modified with up to 25 mol % of copolymerizable acid and/or diol monomers, and (iii) combinations thereof. The polycarbonate component and the polyester component are present in sufficient proportions to form a molding composition capable of being molded into an article that exhibits transparency and structural integrity after the article is exposed to a caustic aqueous environment for at least 70 hours. The invention also relates to articles made from the composition, methods for making the compositions, and methods for using articles.
    • 一种包含透明热塑性共混物的组合物,其包含:(a)聚碳酸酯组分; 和(b)聚酯组分,其包含(i)基于1,4-环己烷二甲醇和对苯二甲酸单体单元的聚酯,(ii)基于1,4-环己烷二甲醇和对苯二甲酸单体单元的基于聚酯的共聚物, 25摩尔%的可共聚的酸和/或二醇单体,和(iii)它们的组合。 聚碳酸酯组分和聚酯组分以足够的比例存在以形成能够模制成在制品暴露于苛性碱水溶液环境中至少70小时后具有透明性和结构完整性的制品的模塑组合物。 本发明还涉及由组合物制备的制品,制备组合物的方法和使用制品的方法。
    • 10. 发明申请
    • PROCESS FOR MAKING POLYBUTYLENE TEREPHTHALATE (PBT) FROM POLYETHYLENE TEREPHTHALATE (PET)
    • 聚苯乙烯聚苯乙烯(PET)制备聚苯乙烯(PBT)的方法
    • US20070203253A1
    • 2007-08-30
    • US11626684
    • 2007-01-24
    • Parminder AgarwalKristen CohoonSandeep DhawanRobert GallucciGanesh KannanKenneth MillerDhaval Shah
    • Parminder AgarwalKristen CohoonSandeep DhawanRobert GallucciGanesh KannanKenneth MillerDhaval Shah
    • C08J11/04
    • C08G63/183C08J11/24C08J2367/02Y02W30/706
    • The invention relates to a process for making modified polybutylene terephthalate random copolymers from a polyethylene terephthalate component. In one embodiment, the invention relates to a two step process in which a 1,4-butane diol component reacts with a polyethylene terephthalate component under conditions that depolymerize the polyethylene terephthalate component into a molten mixture and the molten mixture is placed under subatmospheric conditions that produce the modified polybutylene terephthalate random copolymers. In another embodiment, the invention relates to a three step process in which a diol component selected from the group consisting of ethylene glycol, propylene glycol, and combinations thereof reacts with a polyethylene terephthalate component under conditions sufficient to depolymerize the polyethylene terephthalate component into a first molten mixture; and where the first molten mixture is combined with 1,4-butane diol under conditions that create a second molten mixture that is subsequently placed under subatmospheric conditions that produce the modified polybutylene terephthalate random copolymers. The invention also relates to compositions made from processes of the invention.
    • 本发明涉及一种由聚对苯二甲酸乙二醇酯组分制备改性聚对苯二甲酸丁二醇酯无规共聚物的方法。 在一个实施方案中,本发明涉及一种二步法,其中1,4-丁二醇组分在聚对苯二甲酸乙二醇酯组分解聚熔融混合物的条件下与聚对苯二甲酸乙二醇酯组分反应,并将熔融混合物置于低于大气压的条件下 生产改性聚对苯二甲酸丁二醇酯无规共聚物。 在另一个实施方案中,本发明涉及一种三步法,其中选自乙二醇,丙二醇及其组合的二醇组分在足以将聚对苯二甲酸乙二醇酯组分解聚为第一 熔融混合物 并且其中在产生第二熔融混合物的条件下将第一熔融混合物与1,4-丁二醇组合,随后将其置于产生改性聚对苯二甲酸丁二醇酯无规共聚物的低于大气压条件下。 本发明还涉及由本发明的方法制备的组合物。