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    • 2. 发明授权
    • Reaction product of polyol and a metal carbonyl/pyrrolidine complex
    • 多元醇与羰基/吡咯烷金属络合物的反应产物
    • US4496740A
    • 1985-01-29
    • US492720
    • 1983-05-09
    • P. Anthony Hinman
    • P. Anthony Hinman
    • C07F5/04C07F11/00C08G59/18C08G79/00C07F13/00
    • C07F11/005C07F5/04C08G59/18C08G79/00
    • It is disclosed that the properties of epoxy resins may be improved by incorporating therein at least one metal selected from the group consisting of boron, molybdenum, rhenium, tungsten and zirconium. The selection of a particular metal atom for incorporation into the epoxy resin or a combination of these metals will depend on the specific resin properties desired. The metal containing thermosetting resin is obtained by reacting an epoxy resin and one or more metal compounds selected from the following group:(a) the reaction product of a polyol containing more than two hydroxy groups with boric acid;(b) the reaction product of a polyol containing more than two hydroxy groups and a metal complex which is the reaction product of tungsten carbonyl with pyrrolidine;(c) the reaction product of a polyol containing more than two hydroxy groups and a metal complex which is the reaction product of rhenium carbonyl with pyrrolidine;(d) the reaction product of a polyol containing more than two hydroxy groups and a metal complex which is the reaction product of molybdenum carbonyl with pyrrolidine; and(e) zirconium acetate.
    • 公开了通过在其中加入至少一种选自硼,钼,铼,钨和锆的金属来改善环氧树脂的性能。 选择用于结合到环氧树脂中的特定金属原子或这些金属的组合将取决于所需的特定树脂性质。 含金属的热固性树脂是通过使环氧树脂与一种或多种选自下列的金属化合物反应得到的:(a)含有两个以上羟基的多元醇与硼酸的反应产物; (b)含有多于两个羟基的多元醇和作为羰基钨与吡咯烷的反应产物的金属络合物的反应产物; (c)含有多于两个羟基的多元醇和作为羰基铼与吡咯烷的反应产物的金属络合物的反应产物; (d)含有多于两个羟基的多元醇和作为钼羰基与吡咯烷的反应产物的金属络合物的反应产物; 和(e)乙酸锆。
    • 3. 发明授权
    • Metal atom containing epoxy resins
    • 含有环氧树脂的金属原子
    • US4412064A
    • 1983-10-25
    • US406343
    • 1982-08-09
    • P. Anthony Hinman
    • P. Anthony Hinman
    • C08G59/00C07F5/04C07F11/00C07F13/00C08G59/02C08G59/14C08G59/18C08G79/00C09D163/00
    • C07F13/005C07F11/005C07F5/04C08G59/18C08G79/00
    • It is disclosed that the properties of epoxy resins may be improved by incorporating therein at least one metal selected from the group consisting of boron, molybdenum, rhenium, tungsten and zirconium. The selection of a particular metal atom for incorporation into the epoxy resin or a combination of these metals will depend on the specific resin properties desired. The metal containing thermosetting resin is obtained by reacting an epoxy resin and one or more metal compounds selected from the following group:(a) the reaction product of a polyol containing more than two hydroxy groups with boric acid;(b) the reaction product of a polyol containing more than two hydroxy groups and a metal complex which is the reaction product of tungsten carbonyl with pyrrolidine;(c) the reaction product of a polyol containing more than two hydroxy groups and a metal complex which is the reaction product of rhenium carbonyl with pyrrolidine;(d) the reaction product of a polyol containing more than two hydroxy groups and a metal complex which is the reaction product of molybdenum carbonyl with pyrrolidine; and(e) zirconium acetate.
    • 公开了通过在其中加入至少一种选自硼,钼,铼,钨和锆的金属来改善环氧树脂的性能。 选择用于结合到环氧树脂中的特定金属原子或这些金属的组合将取决于所需的特定树脂性质。 含金属的热固性树脂是通过使环氧树脂与一种或多种选自下列的金属化合物反应得到的:(a)含有两个以上羟基的多元醇与硼酸的反应产物; (b)含有多于两个羟基的多元醇和作为羰基钨与吡咯烷的反应产物的金属络合物的反应产物; (c)含有多于两个羟基的多元醇和作为羰基铼与吡咯烷的反应产物的金属络合物的反应产物; (d)含有多于两个羟基的多元醇和作为钼羰基与吡咯烷的反应产物的金属络合物的反应产物; 和(e)乙酸锆。