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1. 发明授权

US08221892B2 Rubber-reinforced resin, anti-static resin composition, molded article and laminate 失效
标题翻译：橡胶增强树脂，防静电树脂组合物，模制品和层压材料
公开(公告)号：US08221892B2
公开(公告)日：2012-07-17
申请号：US12063116
申请日：2006-08-23
申请人： Norifumi Sumimoto , Wataru Kakuno
发明人： Norifumi Sumimoto , Wataru Kakuno
IPC分类号： B32B27/30 , B32B25/14 , B32B33/00 , C08L33/06 , C08L33/24
CPC分类号： C08F279/06 , B32B25/08 , B32B25/14 , C08F279/02 , C08F279/04 , C08F287/00 , C08L9/00 , C08L33/18 , C08L51/04 , C08L53/025 , C08L55/02 , Y10T428/31786 , Y10T428/31855 , Y10T428/31931 , Y10T428/31935 , C08L2666/08 , C08L2666/02 , C08L2666/04 , C08L2666/14
摘要： The objective of the present invention is to provide a rubber-reinforced resin which, when formed into a molded article, can prevent contamination or soiling of an article contacted with the molded article or a device on the periphery of the molded article and is excellent in impact resistance and transparency, and an anti-static resin composition which is excellent in impact resistance and anti-static properties. The present rubber-reinforced resin comprises a rubber-reinforced copolymeric resin produced by polymerization of 20 to 95 parts by mass of monomer components comprising methyl methacrylate, an aromatic vinyl compound and a cyanidated vinyl compound in the presence of a rubbery polymer having a predetermined volume-average particle diameter, or comprises a mixture of the rubber-reinforced copolymeric resin and a copolymer of the above-mentioned monomer components. Additionally, the present anti-static resin composition comprises the above-mentioned rubber-reinforced resin and a polymer type anti-static agent, wherein the rubbery polymer is contained in an amount from 5% to 40% by mass. In each of the rubber-reinforced resin and the anti-static resin composition, the total amount of substances detected at a retention time of 10 to 24 minutes is 20,000 μg or less per gram of the sample as determined by pyrolysis GC analysis.
摘要翻译：本发明的目的是提供一种橡胶增强树脂，其在形成成型品时能够防止与模制品接触的制品或模制品的周边上的装置的污染或污染，并且在耐冲击性和透明性，以及抗冲击性和抗静电性优异的抗静电性树脂组合物。本发明的橡胶增强树脂包括通过在具有预定体积的橡胶状聚合物的存在下聚合20至95质量份包含甲基丙烯酸甲酯，芳族乙烯基化合物和氰化乙烯基化合物的单体组分而制备的橡胶增强共聚树脂平均粒径，或包含橡胶增强共聚树脂和上述单体成分的共聚物的混合物。此外，本发明的抗静电树脂组合物包含上述橡胶增强树脂和聚合物型防静电剂，其中橡胶状聚合物的含量为5〜40质量％。在每种橡胶增强树脂和防静电树脂组合物中，通过热分解GC分析测定，在每10克样品中，在10至24分钟的保留时间内检测的物质的总量为20,000μg或更少。

2. 发明授权

US08563106B2 Thermoplastic resin composition and resin molding 有权
标题翻译：热塑性树脂组合物和树脂成型
公开(公告)号：US08563106B2
公开(公告)日：2013-10-22
申请号：US12780253
申请日：2010-05-14
申请人： Norifumi Sumimoto
发明人： Norifumi Sumimoto
IPC分类号： C08L77/00 , C08L25/08
CPC分类号： C08F212/10 , B65D25/107 , C08F212/08 , C08F220/14 , C08F220/44 , C08F255/04 , C08F279/02 , C08F279/04 , C08F2220/281 , C08G69/40 , C08L25/12 , C08L25/14 , C08L51/04 , C08L51/06 , C08L55/02 , C08L77/02 , C08L77/06 , Y10T428/13 , Y10T428/1352 , C08L2666/24 , C08L2666/02
摘要： The present invention provides a thermoplastic resin composition producing an extremely small amount of outgas and providing a molded article having excellent antistaticity. The present thermoplastic resin composition comprises a thermoplastic resin and is characterized in that the amount of outgas is 1500 μg/g or less. The composition may comprise a surface resistivity reducing substance in an amount of 0.1 to 70 parts by mass relative to 100 parts by mass of the thermoplastic resin. The present invention is suitable to a composition comprising a styrenic resin as the thermoplastic resin. The surface resistivity reducing substrate is preferably a polyamide elastomer comprising a hard segment formed of polyamide 12 and a soft segment formed of poly(alkylene oxide)glycol. The polyamide elastomer preferably has a refractive index of 1.5 to 1.53, a melting point of 130 to 160° C., a solution viscosity of 1.35 to 1.70 and a surface resistivity of 1×108 to 1×1011Ω.
摘要翻译：本发明提供一种生产极少量废气的热塑性树脂组合物，并提供具有优异抗静电性的模塑制品。本发明的热塑性树脂组合物包含热塑性树脂，其特征在于，排气量为1500mug / g以下。相对于100质量份热塑性树脂，组合物可以含有0.1〜70质量份的表面电阻率降低物质。本发明适用于包含苯乙烯树脂作为热塑性树脂的组合物。表面电阻率降低基材优选为包含由聚酰胺12形成的硬链段和由聚（环氧烷）二醇形成的软链段的聚酰胺弹性体。聚酰胺弹性体的折射率优选为1.5〜1.53，熔点为130〜160℃，溶液粘度为1.35〜1.70，表面电阻率为1×108〜1×1011Omega。

3. 发明授权

US5773532A Process for producing a polyorganosiloxane-based thermoplastic resin 失效
标题翻译：聚有机硅氧烷类热塑性树脂的制造方法
公开(公告)号：US5773532A
公开(公告)日：1998-06-30
申请号：US784960
申请日：1997-01-16
申请人： Motoki Okaniwa , Norifumi Sumimoto , Yoshihisa Ohta , Nobuo Kawahashi , Kazuki Iwai
发明人： Motoki Okaniwa , Norifumi Sumimoto , Yoshihisa Ohta , Nobuo Kawahashi , Kazuki Iwai
IPC分类号： C08F283/12 , C08F283/00
CPC分类号： C08F283/12
摘要： A process for producing a polyorganosiloxane-based thermoplastic resin which comprises graft polymerizing (3) at least one vinyl monomer using (4) an initiator which is an organic peroxide which, upon decomposition, produces an organic radical represented by the structural formula: ##STR1## wherein R.sup.2, R.sup.3 and R.sup.4 represent independently hydrogen atoms or alkyl groups having 1 to 10 carbon atoms, in the presence of (2) a polyorganosiloxane.
摘要翻译：一种聚有机硅氧烷类热塑性树脂的制造方法，其特征在于，使用（4）作为有机过氧化物的引发剂使（3）至少一种乙烯基单体接枝聚合，所述引发剂在分解时产生由结构式表示的有机基团：其中R2，R3和R4独立地表示氢原子或碳原子数1〜10的烷基，（2）聚有机硅氧烷的存在下进行。

4. 发明申请

US20100222511A1 THERMOPLASTIC RESIN COMPOSITION AND RESIN MOLDING 有权
标题翻译：热塑性树脂组合物和树脂模塑
公开(公告)号：US20100222511A1
公开(公告)日：2010-09-02
申请号：US12780253
申请日：2010-05-14
申请人： Norifumi SUMIMOTO
发明人： Norifumi SUMIMOTO
IPC分类号： C08L77/00
CPC分类号： C08F212/10 , B65D25/107 , C08F212/08 , C08F220/14 , C08F220/44 , C08F255/04 , C08F279/02 , C08F279/04 , C08F2220/281 , C08G69/40 , C08L25/12 , C08L25/14 , C08L51/04 , C08L51/06 , C08L55/02 , C08L77/02 , C08L77/06 , Y10T428/13 , Y10T428/1352 , C08L2666/24 , C08L2666/02
摘要： The present invention provides a thermoplastic resin composition producing an extremely small amount of outgas and providing a molded article having excellent antistaticity. The present thermoplastic resin composition comprises a thermoplastic resin and is characterized in that the amount of outgas is 1500 μg/g or less. The composition may comprise a surface resistivity reducing substance in an amount of 0.1 to 70 parts by mass relative to 100 parts by mass of the thermoplastic resin. The present invention is suitable to a composition comprising a styrenic resin as the thermoplastic resin. The surface resistivity reducing substrate is preferably a polyamide elastomer comprising a hard segment formed of polyamide 12 and a soft segment formed of poly(alkylene oxide)glycol. The polyamide elastomer preferably has a refractive index of 1.5 to 1.53, a melting point of 130 to 160° C., a solution viscosity of 1.35 to 1.70 and a surface resistivity of 1×108 to 1×1011Ω.
摘要翻译：本发明提供一种生产极少量废气的热塑性树脂组合物，并提供具有优异抗静电性的模塑制品。本发明的热塑性树脂组合物包含热塑性树脂，其特征在于，废气量为1500μg/ g以下。相对于100质量份热塑性树脂，组合物可以含有0.1〜70质量份的表面电阻率降低物质。本发明适用于包含苯乙烯树脂作为热塑性树脂的组合物。表面电阻率降低基材优选为包含由聚酰胺12形成的硬链段和由聚（环氧烷）二醇形成的软链段的聚酰胺弹性体。聚酰胺弹性体的折射率优选为1.5〜1.53，熔点为130〜160℃，溶液粘度为1.35〜1.70，表面电阻率为1×108〜1×1011·OHgr。

5. 发明申请

US20100016507A1 THERMOPLASTIC RESIN, PROCESS FOR PRODUCTION OF THE SAME, AND MOLDED ARTICLE MANUFACTURED FROM THE SAME 审中-公开
标题翻译：热塑性树脂，其制造方法和从其制造的模制品
公开(公告)号：US20100016507A1
公开(公告)日：2010-01-21
申请号：US11916065
申请日：2006-06-01
申请人： Norifumi Sumimoto , Wataru Kakuno , Tetsuya Kubota , Atsushi Watanabe , Toshio Oohama , Takeshi Watanabe
发明人： Norifumi Sumimoto , Wataru Kakuno , Tetsuya Kubota , Atsushi Watanabe , Toshio Oohama , Takeshi Watanabe
IPC分类号： C08L51/04
CPC分类号： C08F265/06 , C08F265/00 , C08F265/04 , C08L51/003 , C08L51/04 , C08L2666/02
摘要： The objective of the present invention is to provide a thermoplastic resin capable of producing a thin-walled article such as a film, a sheet and a bag stably by extrusion such as calender molding, and of leading to a thin-walled article wherein an undesirable phenomenon due to flow marks generated on the surface is improved and which is excellent in whitening resistance upon bending, and the like, and a method for the production thereof, a molded article and a composite article comprising thereof. The present thermoplastic resin comprises an acryl-based rubbery polymer reinforced resin having a graft ratio of 80% to 170%, a number-average particle diameter of an acryl-based rubbery polymer of 60 to 150 nm, an intrinsic viscosity of a component dissolved by acetonitrile of 0.4 to 0.8 dl/g, a content of a bound cyanidated vinyl compound in the component dissolved by acetonitrile of 20% to 30% by mass, and standard deviation of a distribution of the content of a bound cyanidated vinyl compound measured using liquid chromatography is 5 or less.
摘要翻译：本发明的目的是提供一种热塑性树脂，其能够通过诸如压延成型的挤出来稳定地制造薄膜，片材和袋子等薄壁制品，并且导致薄壁制品，其中不期望的表面上产生的流痕产生的现象得到改善，弯曲时的耐白化性优异等，以及其制造方法，成型品及其组合物。本发明的热塑性树脂包括接枝率为80〜170％，丙烯酸系橡胶质聚合物的数均粒径为60〜150nm，溶解成分的特性粘度的丙烯酸类橡胶状聚合物强化树脂通过乙腈为0.4〜0.8dl / g，由乙腈溶解的成分中的结合的氰化乙烯基化合物的含量为20〜30质量％，使用结合的氰化乙烯基化合物的含量的分布的标准偏差液相色谱法为5以下。

6. 发明申请

US20090104466A1 RUBBER-REINFORCED RESIN, ANTI-STATIC RESIN COMPOSITION, MOLDED ARTICLE AND LAMINATE 失效
标题翻译：橡胶增强树脂，防静电树脂组合物，模制品和层压板
公开(公告)号：US20090104466A1
公开(公告)日：2009-04-23
申请号：US12063116
申请日：2006-08-23
申请人： Norifumi Sumimoto , Wataru Kakuno
发明人： Norifumi Sumimoto , Wataru Kakuno
IPC分类号： B32B27/08 , C08L33/06 , C08L33/24
CPC分类号： C08F279/06 , B32B25/08 , B32B25/14 , C08F279/02 , C08F279/04 , C08F287/00 , C08L9/00 , C08L33/18 , C08L51/04 , C08L53/025 , C08L55/02 , Y10T428/31786 , Y10T428/31855 , Y10T428/31931 , Y10T428/31935 , C08L2666/08 , C08L2666/02 , C08L2666/04 , C08L2666/14
摘要： The objective of the present invention is to provide a rubber-reinforced resin which, when formed into a molded article, can prevent contamination or soiling of an article contacted with the molded article or a device on the periphery of the molded article and is excellent in impact resistance and transparency, and an anti-static resin composition which is excellent in impact resistance and anti-static properties. The present rubber-reinforced resin comprises a rubber-reinforced copolymeric resin produced by polymerization of 20 to 95 parts by mass of monomer components comprising methyl methacrylate, an aromatic vinyl compound and a cyanidated vinyl compound in the presence of a rubbery polymer having a predetermined volume-average particle diameter, or comprises a mixture of the rubber-reinforced copolymeric resin and a copolymer of the above-mentioned monomer components. Additionally, the present anti-static resin composition comprises the above-mentioned rubber-reinforced resin and a polymer type anti-static agent, wherein the rubbery polymer is contained in an amount from 5% to 40% by mass. In each of the rubber-reinforced resin and the anti-static resin composition, the total amount of substances detected at a retention time of 10 to 24 minutes is 20,000 μg or less per gram of the sample as determined by pyrolysis GC analysis.
摘要翻译：本发明的目的是提供一种橡胶增强树脂，其在形成成型品时能够防止与模制品接触的制品或模制品的周边上的装置的污染或污染，并且在耐冲击性和透明性，以及抗冲击性和抗静电性优异的抗静电性树脂组合物。本发明的橡胶增强树脂包括通过在具有预定体积的橡胶状聚合物的存在下聚合20至95质量份包含甲基丙烯酸甲酯，芳族乙烯基化合物和氰化乙烯基化合物的单体组分而制备的橡胶增强共聚树脂平均粒径，或包含橡胶增强共聚树脂和上述单体成分的共聚物的混合物。此外，本发明的抗静电树脂组合物包含上述橡胶增强树脂和聚合物型防静电剂，其中橡胶状聚合物的含量为5〜40质量％。在每种橡胶增强树脂和抗静电树脂组合物中，通过热解GC分析测定，每10克样品中保留时间为10至24分钟时检测的物质总量为20,000杯或更少。

7. 发明申请

US20080248227A1 Thermoplastic Resin Composition and Resin Molding 审中-公开
标题翻译：热塑性树脂组合物和树脂成型
公开(公告)号：US20080248227A1
公开(公告)日：2008-10-09
申请号：US11547191
申请日：2005-03-25
申请人： Norifumi Sumimoto
发明人： Norifumi Sumimoto
IPC分类号： B32B1/02 , C08L71/02
CPC分类号： C08F212/10 , B65D25/107 , C08F212/08 , C08F220/14 , C08F220/44 , C08F255/04 , C08F279/02 , C08F279/04 , C08F2220/281 , C08G69/40 , C08L25/12 , C08L25/14 , C08L51/04 , C08L51/06 , C08L55/02 , C08L77/02 , C08L77/06 , Y10T428/13 , Y10T428/1352 , C08L2666/24 , C08L2666/02
摘要： The present invention provides a thermoplastic resin composition producing an extremely small amount of outgas and providing a molded article having excellent antistaticity. The present thermoplastic resin composition comprises a thermoplastic resin and is characterized in that the amount of outgas is 1500 μg/g or less. The composition may comprise a surface resistivity reducing substance in an amount of 0.1 to 70 parts by mass relative to 100 parts by mass of the thermoplastic resin. The present invention is suitable to a composition comprising a styrenic resin as the thermoplastic resin. The surface resistivity reducing substrate is preferably a polyamide elastomer comprising a hard segment formed of polyamide 12 and a soft segment formed of poly(alkylene oxide)glycol. The polyamide elastomer preferably has a refractive index of 1.5 to 1.53, a melting point of 130 to 160° C., a solution viscosity of 1.35 to 1.70 and a surface resistivity of 1×108 to 1×1011Ω.
摘要翻译：本发明提供一种生产极少量废气的热塑性树脂组合物，并提供具有优异抗静电性的模塑制品。本发明的热塑性树脂组合物包含热塑性树脂，其特征在于，排气量为1500mug / g以下。相对于100质量份热塑性树脂，组合物可以含有0.1〜70质量份的表面电阻率降低物质。本发明适用于包含苯乙烯树脂作为热塑性树脂的组合物。表面电阻率降低基材优选为包含由聚酰胺12形成的硬链段和由聚（环氧烷）二醇形成的软链段的聚酰胺弹性体。聚酰胺弹性体的折射率优选为1.5〜1.53，熔点为130〜160℃，溶液粘度为1.35〜1.70，表面电阻率为1×10 8〜1×10 6。 11欧米茄。

8. 发明授权

US06737453B2 Flame retardant thermoplastic resin composition 有权
标题翻译：阻燃热塑性树脂组合物
公开(公告)号：US06737453B2
公开(公告)日：2004-05-18
申请号：US09729927
申请日：2000-12-06
申请人： Norifumi Sumimoto , Masahiko Noro , Kunio Matsusaka
发明人： Norifumi Sumimoto , Masahiko Noro , Kunio Matsusaka
IPC分类号： C08K552
CPC分类号： C08L51/04 , C08F279/02 , C08F279/04 , C08K5/49 , C08L55/00 , C08L55/02 , C08L2666/02 , C08L2666/24 , C08L2666/04 , C08L2666/14
摘要： The present invention relates to a flame retardant thermoplastic resin composition comprising: (A) 100 parts by weight of a rubber-reinforced thermoplastic resin comprising: a graft copolymer (A1) produced by graft-polymerizing a monomer component (b) containing an aromatic vinyl compound, a cyanided vinyl compound and, if required, the other copolymerizable monomer in the presence of a rubber polymer (a) containing polymer particles having a particle size of not more than 150 nm in an amount of 0 to 15% by weight, polymer particles having a particle size of from more than 150 to less than 350 nm in an amount of 60 to 100% by weight and polymer particles having a particle size of not less than 350 nm in an amount of 0 to 40% by weight, or a mixture of the graft copolymer (A1) and a copolymer (A2) of monomer component (b′), said rubber-reinforced thermoplastic resin (A) having a graft ratio of 20 to 150% and a rubber polymer content of 8 to 20% by weight; and (B) 5 to 20 parts by weight of a phosphorus-based flame retardant comprising a condensed phosphoric acid ester, a phosphazene compound or mixture thereof.
摘要翻译：本发明涉及一种阻燃热塑性树脂组合物，其包含：（A）100重量份的橡胶增强热塑性树脂，其包含：通过将含有芳族乙烯基的单体组分（b）接枝聚合而制备的接枝共聚物（A1）化合物，氰化乙烯基化合物，如果需要，在含有0〜15重量％的粒径为150nm以下的聚合物粒子的橡胶聚合物（a）的存在下，另外可共聚单体，聚合物粒度为60〜100重量％以上的粒径为150〜小于350nm的粒子，0〜40重量％的粒径为350nm以上的聚合物粒子，或接枝共聚物（A1）和单体成分（b'）的共聚物（A2）的混合物，所述橡胶强化热塑性树脂（A）的接枝率为20〜150％，橡胶聚合物含量为8〜20 重量％和（B）5〜20重量份的包含缩合磷酸酯，磷腈化合物或其混合物的磷系阻燃剂。

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