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1. 发明申请

US20140110643A1 ELECTRICAL INSULATING OIL COMPOSITION HAVING EXCELLENT LOW TEMPERATURE PROPERTIES 审中-公开
标题翻译：具有优异低温特性的电绝缘油组合物
公开(公告)号：US20140110643A1
公开(公告)日：2014-04-24
申请号：US14123970
申请日：2012-05-25
申请人： Nobuhiro Kimura , Hiroyuki Hoshino , Takahiro Kawaguchi , Mikihiro Takaki , Minoru Iizuka
发明人： Nobuhiro Kimura , Hiroyuki Hoshino , Takahiro Kawaguchi , Mikihiro Takaki , Minoru Iizuka
IPC分类号： H01B3/22
CPC分类号： H01B3/22 , C10M105/06 , C10M169/04 , C10M2203/06 , C10M2203/065 , C10M2207/046 , C10N2220/022 , C10N2230/02 , C10N2230/41 , C10N2240/20 , C10N2240/201 , H01G4/221 , H01G9/035
摘要： The present invention provides an electric insulating oil composition that has excellent low temperature properties, hydrogen gas absorbability and giving less adverse effect on living bodies and comprises [A] 1,1-diphenylethane in an amount of 30 to 70 percent by mass, [B] at least one or more component selected from 4 components that are (a) 1-phenyl-1-methylphenylethane, (b) 1-phenyl-1-xylylethane, (c) 1-phenyl-1-ethylphenylethane and (d) benzyltoluene in a total amount of 30 to 70 percent by mass, and [C] 1,2-diphenylethane in an amount of 0.1 to 2 percent by mass and/or diphenylmethane in an amount of 0.1 to 13 percent by mass.
摘要翻译：本发明提供一种具有优异的低温性，氢气吸收性，对生物体的不利影响较小的电绝缘油组合物，其含有30〜70质量％的[A] 1,1-二苯基乙烷[B ]（a）1-苯基-1-甲基苯基乙烷，（b）1-苯基-1-木糖醇，（c）1-苯基-1-乙基苯基乙烷和（d）苄基甲苯的4种组分中的至少一种或多种组分总量为30〜70质量％，[C] 1,2-二苯基乙烷为0.1〜2质量％，和/或二苯基甲烷为0.1〜13质量％。

2. 发明授权

US08203025B2 Solid phosphoric acid catalyst and methods of olefin dimerization reaction with the same 有权
标题翻译：固体磷酸催化剂和烯烃二聚反应方法与此相同
公开(公告)号：US08203025B2
公开(公告)日：2012-06-19
申请号：US11920816
申请日：2006-05-25
申请人： Tatsuo Hamamatsu , Nobuhiro Kimura , Tsutomu Takashima , Takashi Morikita
发明人： Tatsuo Hamamatsu , Nobuhiro Kimura , Tsutomu Takashima , Takashi Morikita
IPC分类号： C07C2/18
CPC分类号： C07C2/18 , B01J27/16 , B01J27/182
摘要： The invention provides a solid phosphoric acid catalyst which has high activity and attains high dimer selectivity in olefin dimerization reactions and efficient methods of olefin dimerization. The solid phosphoric acid catalyst comprises a carrier and phosphoric acid supported thereon. When the solid phosphoric acid catalyst is heated at 250° C. for 20 minutes, heating loss of water is 50 mass % or more based on diphosphorus pentoxide (P2O5) derived from the phosphoric acid. A method of olefin dimerization comprises bringing an olefin-containing feed material containing water in an amount of 10-1000 mass ppm into contact with the catalyst to initiate the reaction.
摘要翻译：本发明提供一种固体磷酸催化剂，其在烯烃二聚反应中具有高活性和高二聚体选择性，并且烯烃二聚的有效方法。固体磷酸催化剂包括载体和负载在其上的磷酸。当固体磷酸催化剂在250℃加热20分钟时，基于磷酸衍生的五氧化二磷（P 2 O 5），水的加热损失为50质量％以上。烯烃二聚的方法包括将含有10-1000质量ppm的含有烯烃的进料与催化剂接触以引发反应。

3. 发明授权

US07397999B2 Signal receiver 失效
标题翻译：信号接收机
公开(公告)号：US07397999B2
公开(公告)日：2008-07-08
申请号：US09757645
申请日：2001-01-11
申请人： Satoaki Nakagawa , Nobuhiro Kimura
发明人： Satoaki Nakagawa , Nobuhiro Kimura
IPC分类号： H04N5/91
CPC分类号： H04N17/04 , H04N5/44513 , H04N5/782
摘要： A signal receiver for displaying received broadcast electric waves including: a first memory for storing as a past record information representing whether the signal receiver was previously subjected to initial setup, an alarm device for alarming the necessity of initial setup of the signal receiver when the connection of a power source plug to an external power source is detected and no past record exists in the first memory, whereby a user can surely perform the initial setup, a second memory for holding the initial setup frame displayed on the display device after a response to the alarm of said alarm device is received or at the same time when the alarm is made, a third memory for storing district codes and reception channel groups corresponding to the respective district codes as a district code comparative chart district, and a tuner with which when a district code is input on the initial setup frame, the reception channel group corresponding to the district code thus input is read out and a channel contained in the reception channel group thus read out is selected.
摘要翻译：一种用于显示所接收的广播电波的信号接收机，包括：第一存储器，用于存储表示信号接收机是否先前已经进行初始设置的过去记录信息;报警装置，用于在连接时警告信号接收机的初始建立的必要性检测到电源插头到外部电源，并且在第一存储器中不存在过去的记录，由此用户可以可靠地执行初始设置;第二存储器，用于保持显示在显示设备上的初始设置帧，接收到报警装置的报警，或者在报警的同时，将与各个区域代码对应的区域代码和接收通道组的第三存储器作为区域代码比较图区域，以及调谐器在初始设置帧上输入区号，对应于这样输入的区码的接收信道组进行re 广告输出，并且选择由此读出的接收频道组中包含的频道。

4. 发明申请

US20050153605A1 Connection terminal 有权
公开(公告)号：US20050153605A1
公开(公告)日：2005-07-14
申请号：US10512937
申请日：2003-05-16
申请人： Tsugio Anbo , Yukifumi Machida , Shinji Yamaguchi , Seiichiro Hayashi , Nobuhiro Kimura
发明人： Tsugio Anbo , Yukifumi Machida , Shinji Yamaguchi , Seiichiro Hayashi , Nobuhiro Kimura
IPC分类号： H01R4/18 , H01R13/11 , H01R13/115 , H01R13/187 , H01R43/16 , H01R11/22
CPC分类号： H01R13/113 , H01R4/185 , H01R43/16
摘要： In a connector terminal into which a cooperating male contact terminal can be smoothly inserted and a movable contact strip can be prevented from being buckled while a desired contact pressure can be attained, a connecting portion 11 is formed into a substantially box shape by folding a bottom plate 13, side plates 14, 15 (14 is not shown) continuously extending from respective sides of the bottom plate and a top plate 16 continuously extending from one of the side plates. A movable contact strip 17 is formed by folding back the top plate 16 around a gently curved portion 17a into a resilient spring having an inverted triangular shape including a contact portion 17b near an inwardly bent middle portion of the movable contact strip 17. A hole 17c is formed at an end portion of the movable contact strip 17 into which an engagement tip 16b formed by folding a part of the top plate 16 inwardly is inserted.

5. 发明授权

US09314784B2 Olefin dimers and method for producing and washing olefin dimers 有权
标题翻译：烯烃二聚体和烯烃二聚体的生产和洗涤方法
公开(公告)号：US09314784B2
公开(公告)日：2016-04-19
申请号：US13257838
申请日：2010-01-21
申请人： Nobuhiro Kimura , Tatsuo Hamamatsu
发明人： Nobuhiro Kimura , Tatsuo Hamamatsu
IPC分类号： C07C11/12 , C07C2/02 , B01J35/02 , B01J27/182 , B01J37/02 , C07C2/18
CPC分类号： B01J35/023 , B01J27/182 , B01J37/0201 , C07C2/18 , C07C2527/173 , Y02P20/52 , C07C11/02
摘要： The process for producing an olefin dimer of the present invention includes a first step of carrying out a dimerization reaction of an olefin in the presence of a solid phosphoric acid catalyst in which phosphoric acid is supported on inorganic support particles at a reaction temperature of 55 to 300° C. by introducing into a reactor an olefin-containing raw material containing water in an amount of 10 ppm by mass or more and less than the saturated water content at the reaction temperature, thereby preparing a reaction product containing an olefin dimer, a second step of washing the reaction product prepared in the first step at a temperature of 50° C. or higher using an alkaline substance-containing water adjusted to pH 8 to 13 and a third step of washing the reaction product after the alkaline washing in the second step with water at a temperature of 0 to 110° C., thereby preparing an olefin dimer.
摘要翻译：本发明的烯烃二聚体的制造方法包括在固体磷酸催化剂的存在下进行烯烃的二聚反应的第一步骤，其中磷酸在无机载体颗粒上的反应温度为55〜通过将含有10ppm质量以上且小于饱和水含量的含有烯烃的原料引入反应器中，由此制备含有烯烃二聚体的反应产物，将第一步骤中制备的反应产物在50℃或更高的温度下使用调节至pH8至13的含碱性物质的水进行洗涤的第二步骤;以及在碱洗后将反应产物洗涤的第三步骤第二步，在0〜110℃的温度下加水，由此制备烯烃二聚体。

6. 发明申请

US20080027261A1 Solid Phosphoric Acid Catalyst and Methods of Dimerizing Olefin with the Same 有权
标题翻译：固体磷酸催化剂及其与烯烃二聚体二聚的方法
公开(公告)号：US20080027261A1
公开(公告)日：2008-01-31
申请号：US11632369
申请日：2005-07-13
申请人： Tatsuo Hamamatsu , Nobuhiro Kimura , Tsutomu Takashima , Takashi Morikita
发明人： Tatsuo Hamamatsu , Nobuhiro Kimura , Tsutomu Takashima , Takashi Morikita
IPC分类号： B01J27/16 , B01J37/02 , C07B61/00 , C07C2/18 , C07C9/16
CPC分类号： B01J27/16 , B01J21/08 , B01J27/182 , B01J37/0201 , C07C2/18
摘要： The present invention provides a solid phosphoric acid catalyst which attains high activity and dimer selectivity in olefin dimerization reaction and an efficient method for dimerization of olefin using the same. The solid phosphoric acid catalyst comprises phosphoric acid supported on a siliceous carrier, the proportion of orthophosphoric acid in the phosphoric acid supported being 60 mol % or more in terms of phosphorus atom amount. The solid phosphoric acid catalyst is prepared by bringing a phosphoric acid aqueous solution into contact with the siliceous carrier followed by drying, the preparation step being carried out at a temperature lower than 100° C. Also provided is a method for bringing an olefin-containing raw material into contact with the catalyst. In this method, the olefin-containing raw material contains water in an amount of 10 to 1000 mass ppm, the olefin-containing raw material is brought into contact with the solid phosphoric acid catalyst in a liquid phase, and the olefin is a monoolefin having 3 to 7 carbon atoms.
摘要翻译：本发明提供一种在烯烃二聚反应中获得高活性和二聚体选择性的固体磷酸催化剂，以及使用该固体磷酸催化剂二烯化的有效方法。固体磷酸催化剂包含负载在硅质载体上的磷酸，磷酸中的正磷酸的比例以磷原子量计为60摩尔％以上。固体磷酸催化剂是通过使磷酸水溶液与硅质载体接触，然后干燥而制备的，制备步骤在低于100℃的温度下进行。还提供了一种使含烯烃原料与催化剂接触。在该方法中，含有烯烃的原料含有10〜1000质量ppm的水，使含烯烃的原料与液相中的固体磷酸催化剂接触，烯烃为具有 3至7个碳原子。

7. 发明授权

US06971927B2 Connection terminal 有权
标题翻译：连接端子
公开(公告)号：US06971927B2
公开(公告)日：2005-12-06
申请号：US10512937
申请日：2003-05-16
申请人： Tsugio Anbo , Yukifumi Machida , Shinji Yamaguchi , Seiichiro Hayashi , Nobuhiro Kimura
发明人： Tsugio Anbo , Yukifumi Machida , Shinji Yamaguchi , Seiichiro Hayashi , Nobuhiro Kimura
IPC分类号： H01R4/18 , H01R13/11 , H01R13/115 , H01R13/187 , H01R43/16
CPC分类号： H01R13/113 , H01R4/185 , H01R43/16
摘要： In a connector terminal into which a cooperating male contact terminal can be smoothly inserted and a movable contact strip can be prevented from being buckled while a desired contact pressure can be attained, a connecting portion 11 is formed into a substantially box shape by folding a bottom plate 13, side plates 14, 15 (14 is not shown) continuously extending from respective sides of the bottom plate and a top plate 16 continuously extending from one of the side plates. A movable contact strip 17 is formed by folding back the top plate 16 around a gently curved portion 17a into a resilient spring having an inverted triangular shape including a contact portion 17b near an inwardly bent middle portion of the movable contact strip 17. A hole 17c is formed at an end portion of the movable contact strip 17 into which an engagement tip 16b formed by folding a part of the top plate 16 inwardly is inserted.
摘要翻译：在可以平滑地插入配合的公接头端子的连接器端子中，并且可以防止在可以达到所需接触压力的情况下可动接触片被弯曲，连接部分11通过折叠底部板13，从底板的相应侧连续延伸的侧板14,15（未示出）和从侧板之一连续延伸的顶板16。通过将顶板16围绕轻轻弯曲的部分17a折回到具有倒置的三角形形状的弹性弹簧中，形成可动接触条17，所述弹性弹簧包括在可动接触带17的向内弯曲的中间部分附近的接触部分17b。孔17c形成在可动接触条17的端部，通过将顶板16的一部分向内折叠而形成的接合末端16b插入其中。

8. 发明申请

US20120078022A1 METHOD FOR PRODUCING OLEFIN DIMER, AND OLEFIN DIMER 有权
标题翻译：烯烃二聚体和烯烃二聚体的生产方法
公开(公告)号：US20120078022A1
公开(公告)日：2012-03-29
申请号：US13257838
申请日：2010-01-21
申请人： Nobuhiro Kimura , Tatsuo Hamamatsu
发明人： Nobuhiro Kimura , Tatsuo Hamamatsu
IPC分类号： C07C11/12 , C07C2/02
CPC分类号： B01J35/023 , B01J27/182 , B01J37/0201 , C07C2/18 , C07C2527/173 , Y02P20/52 , C07C11/02
摘要： The process for producing an olefin dimer of the present invention includes a first step of carrying out a dimerization reaction of an olefin in the presence of a solid phosphoric acid catalyst in which phosphoric acid is supported on inorganic support particles at a reaction temperature of 55 to 300° C. by introducing into a reactor an olefin-containing raw material containing water in an amount of 10 ppm by mass or more and less than the saturated water content at the reaction temperature, thereby preparing a reaction product containing an olefin dimer, a second step of washing the reaction product prepared in the first step at a temperature of 50° C. or higher using an alkaline substance-containing water adjusted to pH 8 to 13 and a third step of washing the reaction product after the alkaline washing in the second step with water at a temperature of 0 to 110° C., thereby preparing an olefin dimer.
摘要翻译：本发明的烯烃二聚体的制造方法包括在固体磷酸催化剂的存在下进行烯烃的二聚反应的第一步骤，其中磷酸在无机载体颗粒上的反应温度为55〜通过将含有10ppm质量以上且小于饱和水含量的含有烯烃的原料引入反应器中，由此制备含有烯烃二聚体的反应产物，将第一步骤中制备的反应产物在50℃或更高的温度下使用调节至pH8至13的含碱性物质的水进行洗涤的第二步骤;以及在碱洗后将反应产物洗涤的第三步骤第二步，在0〜110℃的温度下加水，由此制备烯烃二聚体。

9. 发明授权

US07741527B2 Solid phosphoric acid catalyst and method for dimerization of olefin using the same 有权
标题翻译：固体磷酸催化剂及其烯烃二聚方法
公开(公告)号：US07741527B2
公开(公告)日：2010-06-22
申请号：US11632369
申请日：2005-07-13
申请人： Tatsuo Hamamatsu , Nobuhiro Kimura , Tsutomu Takashima , Takashi Morikita
发明人： Tatsuo Hamamatsu , Nobuhiro Kimura , Tsutomu Takashima , Takashi Morikita
IPC分类号： C07C2/24 , B01J27/14
CPC分类号： B01J27/16 , B01J21/08 , B01J27/182 , B01J37/0201 , C07C2/18
摘要： The present invention provides a solid phosphoric acid catalyst which attains high activity and dimer selectivity in olefin dimerization reaction and an efficient method for dimerization of olefin using the same. The solid phosphoric acid catalyst comprises phosphoric acid supported on a siliceous carrier, the proportion of orthophosphoric acid in the phosphoric acid supported being 60 mol % or more in terms of phosphorus atom amount. The solid phosphoric acid catalyst is prepared by bringing a phosphoric acid aqueous solution into contact with the siliceous carrier followed by drying, the preparation step being carried out at a temperature lower than 100° C. Also provided is a method for bringing an olefin-containing raw material into contact with the catalyst. In this method, the olefin-containing raw material contains water in an amount of 10 to 1000 mass ppm, the olefin-containing raw material is brought into contact with the solid phosphoric acid catalyst in a liquid phase, and the olefin is a monoolefin having 3 to 7 carbon atoms.
摘要翻译：本发明提供一种在烯烃二聚反应中获得高活性和二聚体选择性的固体磷酸催化剂，以及使用该固体磷酸催化剂二烯化的有效方法。固体磷酸催化剂包含负载在硅质载体上的磷酸，磷酸中的正磷酸的比例以磷原子量计为60摩尔％以上。固体磷酸催化剂是通过使磷酸水溶液与硅质载体接触，然后干燥而制备的，制备步骤在低于100℃的温度下进行。还提供了一种使含烯烃原料与催化剂接触。在该方法中，含有烯烃的原料含有10〜1000质量ppm的水，使含烯烃的原料与液相中的固体磷酸催化剂接触，烯烃为具有 3至7个碳原子。

10. 发明申请

US20090099400A1 Solid phosphoric acid catalyst and methods of olefin dimerization reaction with the same 有权
标题翻译：固体磷酸催化剂和烯烃二聚反应方法与此相同
公开(公告)号：US20090099400A1
公开(公告)日：2009-04-16
申请号：US11920816
申请日：2006-05-25
申请人： Tatsuo Hamamatsu , Nobuhiro Kimura , Tsutomu Takashima , Takashi Morikita
发明人： Tatsuo Hamamatsu , Nobuhiro Kimura , Tsutomu Takashima , Takashi Morikita
IPC分类号： C07C2/02 , B01J27/14
CPC分类号： C07C2/18 , B01J27/16 , B01J27/182
摘要： A solid phosphoric acid catalyst which has high activity and attains high dimer selectivity in olefin dimerization reactions; and efficient methods of olefin dimerization reaction. The solid phosphoric acid catalyst comprises a carrier and phosphoric acid supported thereon. When the solid phosphoric acid catalyst is heated at 250° C. for 20 minutes, heating loss of water is 50 mass % or more based on diphosphorus pentaoxide (P2O5) derived from the phosphoric acid. One of the methods of olefin dimerization reaction comprises bringing an olefin-containing feed material containing water in an amount of 10-1000 mass ppm into contact with the catalyst to initiate the reaction. Another method of olefin dimerization reaction comprises successively conducting the following steps: a step (1) in which a hydrocarbon containing water in an amount of 10-1000 mass ppm and containing substantially no olefin is brought into contact with the above mentioned catalyst; a step (2) in which the pressure and temperature are regulated to conditions suitable for the initiation of olefin dimerization reaction; and a step (3) in which the hydrocarbon is displaced with an olefin-containing feed material containing water in an amount of 10-1000 mass ppm to bring the olefin into contact with the solid phosphoric acid catalyst and thereby to initiate the reaction. Still another method is the olefin dimerization reaction method described above wherein the temperature in the reaction initiation conditions is higher by 5-50° C. than the reaction•temperature in olefin dimerization in a stationary state after the step (3).
摘要翻译：一种固体磷酸催化剂，在烯烃二聚反应中具有高活性和高二聚体选择性; 和烯烃二聚反应的有效方法。固体磷酸催化剂包括载体和负载在其上的磷酸。当固体磷酸催化剂在250℃下加热20分钟时，基于磷酸衍生的五氧化二磷（P 2 O 5），水的加热损失为50质量％以上。烯烃二聚反应的方法之一包括将含有10-1000质量ppm的含有烯烃的进料与催化剂接触以引发反应。烯烃二聚反应的另一种方法包括依次进行以下步骤：将含有10-1000质量ppm的含烃基本上不含烯烃的烃类与上述催化剂接触的步骤（1）将压力和温度调节到适于引发烯烃二聚反应的条件的步骤（2）; 和使用含有10〜1000质量ppm的水的含烯烃的原料进行碳氢化合物置换的步骤（3），使烯烃与固体磷酸催化剂接触，从而引发反应。另一种方法是上述烯烃二聚反应方法，其中反应开始条件中的温度比在步骤（3）之后的固定状态下的烯烃二聚反应中的反应温度高5-50℃。

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