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1. 发明授权

US08202679B2 Oxime ester compound and photopolymerization initiator containing the same 有权
标题翻译：肟酯化合物和含有它的光聚合引发剂
公开(公告)号：US08202679B2
公开(公告)日：2012-06-19
申请号：US12740452
申请日：2007-12-25
申请人： Daisuke Sawamoto , Nobuhide Tominaga
发明人： Daisuke Sawamoto , Nobuhide Tominaga
IPC分类号： C08F2/50 , C07C391/02 , C07C323/63 , C07C323/47 , C07C251/66 , C07C255/64 , C07D345/00 , C07D333/76 , C07D327/08 , C07D307/91 , C07D215/18 , C08L101/00
CPC分类号： C08F2/50 , B33Y70/00 , C07C251/62 , C07C251/66 , C07C323/47 , C07C323/63 , C07C391/02 , C07C2603/18 , C07D209/86 , C07D215/18 , C07D303/16 , C07D303/22 , C07D307/91 , C07D327/08 , C07D333/76 , C07D345/00 , C07F9/5022 , G03F7/0007 , G03F7/031
摘要： An oxime ester compound of formula (I) useful as a photopolymerization initiator. A photopolymerization initiator having the oxime ester compound as an active ingredient is activated through efficient absorption of light of long wavelength, e.g., 405 nm or 365 nm, to exhibit high sensitivity. In formula (I), R1 and R2 are each R11, OR11, COR11, SR11, CONR12R13, or CN; R11, R12, and R13 are each hydrogen, a C1-C20 alkyl group, C6-C30 aryl group, a C7-C30 arylalkyl group, or a C2-C20 heterocyclic group; R3 and R4 are each R11, OR11, SR11, COR11, CONR12R13, NR12COR11, OCOR11, COOR11, SCOR11, OCSR11, COSR11, CSOR11, CN, halogen, or a hydroxyl group; a and b is each 0 to 4; X is oxygen, sulfur, selenium, CR31R32, CO, NR33, or PR34; and R31, R32, R33, and R34 each have the same meaning as R1.
摘要翻译：用作光聚合引发剂的式（I）的肟酯化合物。具有肟酯化合物作为活性成分的光聚合引发剂通过有效吸收长波长例如405nm或365nm的光而活化，以表现出高灵敏度。在式（I）中，R 1和R 2各自为R 11，OR 11，COR 11，SR 11，CONR 12 R 13或CN; R11，R12和R13各自为氢，C1-C20烷基，C6-C30芳基，C7-C30芳烷基或C2-C20杂环基; R3和R4各自为R11，OR11，SR11，COR11，CONR12R13，NR12COR11，OCOR11，COOR11，SCOR11，OCSR11，COSR11，CSOR11，CN，卤素或羟基; a和b分别为0〜4; X是氧，硫，硒，CR31R32，CO，NR33或PR34; 和R 31，R 32，R 33和R 34各自具有与R 1相同的含义。

2. 发明授权

US5728646A Heat-sensitive recording material 失效
标题翻译：热敏记录材料
公开(公告)号：US5728646A
公开(公告)日：1998-03-17
申请号：US744251
申请日：1996-11-05
申请人： Nobuhide Tominaga , Keiji Oya
发明人： Nobuhide Tominaga , Keiji Oya
IPC分类号： B41M5/333 , B41M5/337 , C09B26/02 , B41M5/30
CPC分类号： B41M5/3375 , B41M5/3335
摘要： A heat-sensitive recording material, comprising a heat-sensitive recording layer containing at least one acid hydrazide compound represented by the following general formula (I): ##STR1## wherein X.sub.1 and X.sub.2 each independently represent a hydrogen atom, a hydroxyl group, a halogen atom or an alkyl group or alkoxy group having 1 to 10 carbon atoms, A represents --CO-- or --SO.sub.2 --, n is 1 or 2, when n is 1, R.sub.1 represents an alkyl group, an aryl group, a hydroxyaryl group, an alkoxyaryl group, or an alkylaryl group having 1 to 22 carbon atoms and when n is 2, R.sub.1 represents an alkylene group or arylene group having 1 to 18 carbon atoms or a direct bond.
摘要翻译：一种热敏记录材料，其包含含有至少一种由以下通式（I）表示的酸酰肼化合物的热敏记录层：其中X 1和X 2各自独立地表示氢原子，羟基基团，卤素原子或具有1-10个碳原子的烷基或烷氧基，A表示-CO-或-SO2-，n为1或2，当n为1时，R 1表示烷基，芳基，羟基芳基，烷氧基芳基或碳原子数1〜22的烷芳基，n为2时，R 1表示碳原子数1〜18的亚烷基或亚芳基或直接键合。

3. 发明授权

US5607894A Heat-sensitive recording material 失效
标题翻译：热敏记录材料
公开(公告)号：US5607894A
公开(公告)日：1997-03-04
申请号：US487847
申请日：1995-06-07
申请人： Mitsuo Akutsu , Nobuhide Tominaga , Keiji Oya , Athuo Tomita , Kouichi Shigeno
发明人： Mitsuo Akutsu , Nobuhide Tominaga , Keiji Oya , Athuo Tomita , Kouichi Shigeno
IPC分类号： B41M5/337 , B41M5/333 , B41M5/30
CPC分类号： B41M5/3335
摘要： The heat-sensitive recording material of the present invention comprises a heat-sensitive recording layer containing at least one resorcylic anilide derivative represented by the following general formula: ##STR1## wherein R.sub.1 represents an alkyl or alkoxy, group having 1 to 4 carbon atoms and R.sub.2 represents a hydrogen atom or an alkyl or alkoxy group having 1 to 4 carbon atoms.
摘要翻译：本发明的热敏记录材料包含含有至少一种由以下通式表示的间苯二酰胺衍生物的热敏记录层：其中R1表示烷基或烷氧基，具有1-4个碳原子，R 2表示氢原子或碳原子数1〜4的烷基或烷氧基。

4. 发明授权

US4105627A Mercaptoheterocyclic resin stabilizers 失效
标题翻译：甲基环己醇树脂稳定剂
公开(公告)号：US4105627A
公开(公告)日：1978-08-08
申请号：US725356
申请日：1976-09-20
申请人： Tetsuo Sekiguchi , Masami Abe , Kouji Tsuruga , Nobuhide Tominaga
发明人： Tetsuo Sekiguchi , Masami Abe , Kouji Tsuruga , Nobuhide Tominaga
IPC分类号： C08K5/34 , C08K5/37 , C08K5/52 , C09K3/00
CPC分类号： C08K5/37 , C08K5/09 , C08K5/15 , C08K5/34 , C08K5/52 , C08K5/57
摘要： Improved clarity and resistance to deterioration on heating of polyvinyl fluoride and vinyl chloride polymers is obtained by employing a stabilizer composition consisting essentially of (A) a heterocyclic nitrogen compound having as part of a 5 or 6 membered heterocyclic ring the group ##STR1## in which R is hydrogen, aryl, or alkyl having 1 to 12 carbon atoms, and X is oxygen or sulfur, and (B) one or more 1,2-epoxides, organic phosphites, or stannous tin, zinc, magnesium, aluminum, potassium, sodium, calcium, strontium, or barium salts of non-nitrogenous monocarboxylic acids having from 6 to 24 carbon atoms or hydrocarbon-substituted phenols having from about 10 to about 30 carbon atoms.

5. 发明申请

US20100249262A1 OXIME ESTER COMPOUND AND PHOTOPOLYMERIZATION INITIATOR CONTAINING THE SAME 有权
标题翻译：含有酯化合物和含有它的光聚合引发剂
公开(公告)号：US20100249262A1
公开(公告)日：2010-09-30
申请号：US12740452
申请日：2007-12-25
申请人： Daisuke Sawamoto , Nobuhide Tominaga
发明人： Daisuke Sawamoto , Nobuhide Tominaga
IPC分类号： C08L101/00 , C07C251/66 , C07C255/64 , C07D333/76 , C07D307/91 , C07D345/00 , C07D215/06
CPC分类号： C08F2/50 , B33Y70/00 , C07C251/62 , C07C251/66 , C07C323/47 , C07C323/63 , C07C391/02 , C07C2603/18 , C07D209/86 , C07D215/18 , C07D303/16 , C07D303/22 , C07D307/91 , C07D327/08 , C07D333/76 , C07D345/00 , C07F9/5022 , G03F7/0007 , G03F7/031
摘要： An oxime ester compound of formula (I) useful as a photopolymerization initiator. A photopolymerization initiator having the oxime ester compound as an active ingredient is activated through efficient absorption of light of long wavelength, e.g., 405 nm or 365 nm, to exhibit high sensitivity. In formula (I), R1 and R2 are each R11, OR11, COR11, SR11, CONR12R13, or CN; R11, R12, and R13 are each hydrogen, a C1-C20 alkyl group, C6-C30 aryl group, a C7-C30 arylalkyl group, or a C2-C20 heterocyclic group; R3 and R4 are each R11, OR11, SR11, COR11, CONR12R13, NR12COR11, OCOR11, COOR11, SCOR11, OCSR11, COSR11, CSOR11, CN, halogen, or a hydroxyl group; a and b is each 0 to 4; X is oxygen, sulfur, selenium, CR31R32, CO, NR33, or PR34; and R31, R32, R33, and R34 each have the same meaning as R1.
摘要翻译：用作光聚合引发剂的式（I）的肟酯化合物。具有肟酯化合物作为活性成分的光聚合引发剂通过有效吸收长波长例如405nm或365nm的光而活化，以表现出高灵敏度。在式（I）中，R 1和R 2各自为R 11，OR 11，COR 11，SR 11，CONR 12 R 13或CN; R11，R12和R13各自为氢，C1-C20烷基，C6-C30芳基，C7-C30芳烷基或C2-C20杂环基; R3和R4各自为R11，OR11，SR11，COR11，CONR12R13，NR12COR11，OCOR11，COOR11，SCOR11，OCSR11，COSR11，CSOR11，CN，卤素或羟基; a和b分别为0〜4; X是氧，硫，硒，CR31R32，CO，NR33或PR34; 和R 31，R 32，R 33和R 34各自具有与R 1相同的含义。

6. 发明授权

US06432875B1 Thermal recording material 失效
标题翻译：热敏记录材料
公开(公告)号：US06432875B1
公开(公告)日：2002-08-13
申请号：US09451845
申请日：1999-12-01
申请人： Mitsuo Akutsu , Nobuhide Tominaga , Keiji Ohya , Koichi Shigeno , Takahiro Mori
发明人： Mitsuo Akutsu , Nobuhide Tominaga , Keiji Ohya , Koichi Shigeno , Takahiro Mori
IPC分类号： B41M530
CPC分类号： B41M5/3335 , B41M5/333 , B41M5/3331 , B41M5/3333
摘要： A thermal recording material includes a condensation reaction product of a carboxylic acid component (A) with a polyhydric alcohol component (B) in a thermal recording layer as an essential component, wherein the carboxylic acid component (A) includes (poly) 4-hydroxybenzoic acid represented by the following general formula (I) as an essential component and another monocarboxylic acid and/or dicarboxylic acid as an arbitrary component, and wherein the polyhydric alcohol component (B) includes a polyhydric alcohol which is a trihydric or more alcohol as an essential component and a dihydric low molecular-weight alcohol as an arbitrary component. wherein in the general formula(I), a letter p denotes an integer ranging from 0 to 2.
摘要翻译：热敏记录材料包括在热敏记录层中的羧酸组分（A）与多元醇组分（B）的缩合反应产物作为必需组分，其中羧酸组分（A）包括（聚）4-羟基苯甲酸由下述通式（I）表示的酸作为必要成分，另一种单羧酸和/或二羧酸为任意成分，其中，所述多元醇成分（B）含有作为三元醇以上的多元醇必要成分和二元低分子量醇作为任意成分。在通式（I）中，字母p表示0〜2的整数。

7. 发明授权

US5334484A Photopolymerizable composition and photopolymerizable element 失效
标题翻译：光聚合组合物和光聚合元素
公开(公告)号：US5334484A
公开(公告)日：1994-08-02
申请号：US859430
申请日：1992-06-15
申请人： Yoshitaka Minami , Hajime Kakumaru , Naohiro Kubota , Nobuhide Tominaga , Koji Ishizaki
发明人： Yoshitaka Minami , Hajime Kakumaru , Naohiro Kubota , Nobuhide Tominaga , Koji Ishizaki
IPC分类号： G03F7/027 , C07D219/02 , C08F2/50 , G03F7/031 , H01L21/027 , H01L21/30 , G03C1/73
CPC分类号： G03F7/031 , C07D219/02 , Y10S430/117 , Y10S430/121
摘要： A photopolymerizable composition comprising: (a) 100 parts by weight of a compound having at least one ethylenically unsaturated group, (b) 0 to 400 parts by weight of a thermoplastic organic polymer and (c) 0.01 to 20 parts by weight of a photoinitiator, characterized in that an acridine compound of the following general formula (I) is used as the photoinitiator: ##STR1## wherein R represents an alkylene, oxadialkylene or thiodialkylene group having 2 to 20 carbon atoms,and a photopolymerizable element comprising a layer of the photopolymerizable composition formed on a support.
摘要翻译： PCT No.PCT / JP91 / 01293 Sec。 371日期：1992年6月15日 102（e）日期1992年6月15日PCT 1991年9月27日PCT公布。出版物WO92 / 06412 一种光聚合组合物，其包含：（a）100重量份的具有至少一个烯属不饱和基团的化合物，（b）0-400重量份的热塑性有机聚合物和（c）0.01至 20重量份的光引发剂，其特征在于使用以下通式（I）的吖啶化合物作为光引发剂：其中R表示具有2-20个碳原子的亚烷基，氧亚烷基或硫代亚烷基以及包含形成在载体上的可光聚合组合物层的光聚合元件。

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