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1. 发明授权

US08703310B2 High elastic modulus polymer electrolytes suitable for preventing thermal runaway in lithium batteries 有权
标题翻译：适用于防止锂电池热失控的高弹性模量聚合物电解质
公开(公告)号：US08703310B2
公开(公告)日：2014-04-22
申请号：US13664345
申请日：2012-10-30
申请人： Scott Mullin , Ashoutosh Panday , Nitash Pervez Balsara , Mohit Singh , Hany Basam Eitouni , Enrique Daniel Gomez
发明人： Scott Mullin , Ashoutosh Panday , Nitash Pervez Balsara , Mohit Singh , Hany Basam Eitouni , Enrique Daniel Gomez
IPC分类号： H01M10/44 , C08L71/02
CPC分类号： H01M10/0565 , C08F297/02 , C08L53/00 , G01N27/4166 , H01B1/122 , H01M10/052 , H01M10/443 , H01M2300/0082 , C08L2666/02
摘要： A polymer that combines high ionic conductivity with the structural properties required for Li electrode stability is useful as a solid phase electrolyte for high energy density, high cycle life batteries that do not suffer from failures due to side reactions and dendrite growth on the Li electrodes, and other potential applications. The polymer electrolyte includes a linear block copolymer having a conductive linear polymer block with a molecular weight of at least 5000 Daltons, a structural linear polymer block with an elastic modulus in excess of 1×107 Pa and an ionic conductivity of at least 1×10−5 Scm−1. The electrolyte is made under dry conditions to achieve the noted characteristics. In another aspect, the electrolyte exhibits a conductivity drop when the temperature of electrolyte increases over a threshold temperature, thereby providing a shutoff mechanism for preventing thermal runaway in lithium battery cells.
摘要翻译：将高离子电导率与Li电极稳定性所需的结构性质结合的聚合物可用作高能量密度的固相电解质，高循环寿命的电池，不会由于Li电极上的副反应和枝晶生长而发生故障，和其他潜在应用。聚合物电解质包括具有分子量至少为5000道尔顿的导电线性聚合物嵌段的直链嵌段共聚物，弹性模量超过1×10 7 Pa的离子电导率至少为1×10 5 -5 Scm-1。在干燥条件下制备电解质以达到所述特征。在另一方面，当电解液的温度升高超过阈值温度时，电解质呈现电导率下降，从而提供一种用于防止锂电池电池热失控的关闭机构。

2. 发明申请

US20120264880A1 Block Copolymer with Simultaneous Electric and Ionic Conduction for Use in Lithium ION Batteries 有权
标题翻译：用于锂离子电池的具有同时电和离子传导的嵌段共聚物
公开(公告)号：US20120264880A1
公开(公告)日：2012-10-18
申请号：US13427640
申请日：2012-03-22
申请人： Anna Esmeralda K. Javier , Nitash Pervez Balsara , Shrayesh Naran Patel , Daniel T. Hallinan, JR.
发明人： Anna Esmeralda K. Javier , Nitash Pervez Balsara , Shrayesh Naran Patel , Daniel T. Hallinan, JR.
IPC分类号： C08G81/02
CPC分类号： H01M4/604 , C08G81/00 , H01M4/137 , H01M10/0525
摘要： Redox reactions that occur at the electrodes of batteries require transport of both ions and electrons to the active centers. Reported is the synthesis of a block copolymer that exhibits simultaneous electronic and ionic conduction, A combination of Grignard metathesis polymerization and click reaction was used successively to synthesize the block copolymer containing regioregular poly(3-hexylthiophene) (P3HT) and poly(ethylene oxide) (PEO) segments. The P3HT-PEO/LiTFSI mixture was then used to make a lithium battery cathode with LiFePO4 as the only other component. All-solid lithium batteries of the cathode described above, a solid electrolyte and a lithium foil as the anode showed capacities within experimental error of the theoretical capacity of the battery. The ability of P3HT-PEO to serve all of the transport and binding functions required in a lithium battery electrode is thus demonstrated.
摘要翻译：在电池电极处发生的氧化还原反应需要将离子和电子两者传输到活性中心。报道了嵌段共聚物的合成，其表现出同时的电子和离子传导，连续使用格氏复分解聚合和咔咔反应的组合来合成含有区域性聚（3-己基噻吩）（P3HT）和聚（环氧乙烷）的嵌段共聚物，（PEO）段。然后将P3HT-PEO / LiTFSI混合物用于制备锂电池阴极，其中LiFePO4作为唯一的其他组分。上述阴极的全固体锂电池，固体电解质和作为阳极的锂箔显示出电池理论容量的实验误差范围内的容量。因此证明了P3HT-PEO能够满足锂电池电极所需的所有运输和绑定功能的能力。

3. 发明申请

US20090075176A1 Solid Electrolyte Material Manufacturable by Polymer Processing Methods 有权
标题翻译：通过聚合物加工方法制造的固体电解质材料
公开(公告)号：US20090075176A1
公开(公告)日：2009-03-19
申请号：US12271829
申请日：2008-11-14
申请人： Mohit Singh , Ilan Gur , Hany Basam Eitouni , Nitash Pervez Balsara
发明人： Mohit Singh , Ilan Gur , Hany Basam Eitouni , Nitash Pervez Balsara
IPC分类号： H01M10/26
CPC分类号： H01M10/0565 , H01B1/122 , H01M2/16 , H01M2/1686 , H01M6/181 , H01M10/052 , H01M2300/0082 , H01M2300/0088 , Y10T428/31511 , Y10T428/31515 , Y10T428/31536 , Y10T428/31573 , Y10T428/31576 , Y10T428/31587 , Y10T428/31663
摘要： The present invention relates generally to electrolyte materials. According to an embodiment, the present invention provides for a solid polymer electrolyte material that is ionically conductive, mechanically robust, and can be formed into desirable shapes using conventional polymer processing methods. An exemplary polymer electrolyte material has an elastic modulus in excess of 1×106 Pa at 90 degrees C. and is characterized by an ionic conductivity of at least 1×10−5 Scm−1 at 90 degrees C. An exemplary material can be characterized by a two domain or three domain material system. An exemplary material can include material components made of diblock polymers or triblock polymers. Many uses are contemplated for the solid polymer electrolyte materials. For example, the present invention can be applied to improve Li-based batteries by means of enabling higher energy density, better thermal and environmental stability, lower rates of self-discharge, enhanced safety, lower manufacturing costs, and novel form factors.
摘要翻译：本发明一般涉及电解质材料。根据一个实施方案，本发明提供了一种固体聚合物电解质材料，其是离子导电的，机械牢固的，并且可以使用常规的聚合物加工方法形成所需的形状。示例性聚合物电解质材料在90℃下具有超过1×10 6 Pa的弹性模量，其特征在于在90℃下离子电导率至少为1×10 -5 Scm-1。示例性材料可以由两个结构域或三个领域材料系统。示例性材料可以包括由二嵌段聚合物或三嵌段聚合物制成的材料组分。考虑到固体聚合物电解质材料的许多用途。例如，本发明可以用于通过实现更高的能量密度，更好的热和环境稳定性，更低的自放电速率，更高的安全性，更低的制造成本和新的外形因素来改进Li-基电池。

4. 发明申请

US20090104523A1 High elastic modulus polymer electrolytes suitable for preventing thermal runaway in lithium batteries 审中-公开
标题翻译：适用于防止锂电池热失控的高弹性模量聚合物电解质
公开(公告)号：US20090104523A1
公开(公告)日：2009-04-23
申请号：US12286898
申请日：2008-10-01
申请人： Scott Mullin , Ashoutosh Panday , Nitash Pervez Balsara , Mohit Singh , Hany Basam Eitouni , Enrique Daniel Gomez
发明人： Scott Mullin , Ashoutosh Panday , Nitash Pervez Balsara , Mohit Singh , Hany Basam Eitouni , Enrique Daniel Gomez
IPC分类号： H01M6/18 , C08L53/00 , H02J7/00
CPC分类号： H01M10/0565 , C08F297/02 , C08L53/00 , G01N27/4166 , H01B1/122 , H01M10/052 , H01M10/443 , H01M2300/0082 , C08L2666/02
摘要： A polymer that combines high ionic conductivity with the structural properties required for Li electrode stability is useful as a solid phase electrolyte for high energy density, high cycle life batteries that do not suffer from failures due to side reactions and dendrite growth on the Li electrodes, and other potential applications. The polymer electrolyte includes a linear block copolymer having a conductive linear polymer block with a molecular weight of at least 5000 Daltons, a structural linear polymer block with an elastic modulus in excess of 1×107 Pa and an ionic conductivity of at least 1×10−5 Scm−1. The electrolyte is made under dry conditions to achieve the noted characteristics. In another aspect, the electrolyte exhibits a conductivity drop when the temperature of electrolyte increases over a threshold temperature, thereby providing a shutoff mechanism for preventing thermal runaway in lithium battery cells.
摘要翻译：将高离子电导率与Li电极稳定性所需的结构性质结合的聚合物可用作高能量密度的固相电解质，高循环寿命的电池，不会由于Li电极上的副反应和枝晶生长而发生故障，和其他潜在应用。聚合物电解质包括具有分子量至少为5000道尔顿的导电线性聚合物嵌段的直链嵌段共聚物，弹性模量超过1×10 7 Pa的结构线性聚合物嵌段和至少1×10 -5 Scm- 1。在干燥条件下制备电解质以达到所述特征。在另一方面，当电解液的温度升高超过阈值温度时，电解质呈现电导率下降，从而提供一种用于防止锂电池电池热失控的关闭机构。

5. 发明授权

US09136562B2 Multiple electrolyte electrochemical cells 有权
标题翻译：多电解电解池
公开(公告)号：US09136562B2
公开(公告)日：2015-09-15
申请号：US13128232
申请日：2009-11-06
申请人： Mohit Singh , Ilan Gur , Hany Basam Eitouni , Nitash Pervez Balsara
发明人： Mohit Singh , Ilan Gur , Hany Basam Eitouni , Nitash Pervez Balsara
IPC分类号： H01M10/40 , H01M4/36 , H01M4/48 , H01M10/0565 , H01M2/16 , H01M10/052 , H01M10/0566
CPC分类号： H01M10/0565 , H01M2/16 , H01M10/052 , H01M10/0566 , H01M2300/0094 , Y02E60/122
摘要： Electrode assemblies for use in electrochemical cells are provided. The negative electrode assembly comprises negative electrode active material and an electrolyte chosen specifically for its useful properties in the negative electrode. These properties include reductive stability and ability to accommodate expansion and contraction of the negative electrode active material. Similarly, the positive electrode assembly comprises positive electrode active material and an electrolyte chosen specifically for its useful properties in the positive electrode. These properties include oxidative stability and the ability to prevent dissolution of transition metals used in the positive electrode active material. A third electrolyte can be used as separator between the negative electrode and the positive electrode.
摘要翻译：提供了用于电化学电池的电极组件。负极组件包括负极活性材料和专门用于其在负极中的有用特性的电解质。这些性质包括还原稳定性和适应负极活性物质的膨胀和收缩的能力。类似地，正电极组件包括正电极活性材料和专门用于其在正电极中的有用特性的电解质。这些性质包括氧化稳定性和防止在正极活性物质中使用的过渡金属溶解的能力。第三电解质可以用作负极和正极之间的隔板。

6. 发明授权

US08268197B2 Solid electrolyte material manufacturable by polymer processing methods 有权
标题翻译：通过聚合物加工方法制造的固体电解质材料
公开(公告)号：US08268197B2
公开(公告)日：2012-09-18
申请号：US12271829
申请日：2008-11-14
申请人： Mohit Singh , Ilan Gur , Hany Basam Eitouni , Nitash Pervez Balsara
发明人： Mohit Singh , Ilan Gur , Hany Basam Eitouni , Nitash Pervez Balsara
IPC分类号： H01B1/12 , B32B7/04
CPC分类号： H01M10/0565 , H01B1/122 , H01M2/16 , H01M2/1686 , H01M6/181 , H01M10/052 , H01M2300/0082 , H01M2300/0088 , Y10T428/31511 , Y10T428/31515 , Y10T428/31536 , Y10T428/31573 , Y10T428/31576 , Y10T428/31587 , Y10T428/31663
摘要： The present invention relates generally to electrolyte materials. According to an embodiment, the present invention provides for a solid polymer electrolyte material that is ionically conductive, mechanically robust, and can be formed into desirable shapes using conventional polymer processing methods. An exemplary polymer electrolyte material has an elastic modulus in excess of 1×106 Pa at 90 degrees C. and is characterized by an ionic conductivity of at least 1×10−5 Scm-1 at 90 degrees C. An exemplary material can be characterized by a two domain or three domain material system. An exemplary material can include material components made of diblock polymers or triblock polymers. Many uses are contemplated for the solid polymer electrolyte materials. For example, the present invention can be applied to improve Li-based batteries by means of enabling higher energy density, better thermal and environmental stability, lower rates of self-discharge, enhanced safety, lower manufacturing costs, and novel form factors.
摘要翻译：本发明一般涉及电解质材料。根据一个实施方案，本发明提供了一种固体聚合物电解质材料，其是离子导电的，机械牢固的，并且可以使用常规的聚合物加工方法形成所需的形状。示例性的聚合物电解质材料在90℃下具有超过1×10 6 Pa的弹性模量，其特征在于在90℃下的离子电导率至少为1×10 -5 Scm-1。通过两个领域或三个域名材料系统。示例性材料可以包括由二嵌段聚合物或三嵌段聚合物制成的材料组分。考虑到固体聚合物电解质材料的许多用途。例如，本发明可以用于通过实现更高的能量密度，更好的热和环境稳定性，更低的自放电速率，更高的安全性，更低的制造成本和新的外形因素来改进Li-基电池。

7. 发明申请

US20110281173A1 MULTIPLE ELECTROLYTE ELECTROCHEMICAL CELLS 有权
标题翻译：多电解电化学电池
公开(公告)号：US20110281173A1
公开(公告)日：2011-11-17
申请号：US13128232
申请日：2009-11-06
申请人： Mohit Singh , Ilan Gur , Hany Basam Eitouni , Nitash Pervez Balsara
发明人： Mohit Singh , Ilan Gur , Hany Basam Eitouni , Nitash Pervez Balsara
IPC分类号： H01M10/0562
CPC分类号： H01M10/0565 , H01M2/16 , H01M10/052 , H01M10/0566 , H01M2300/0094 , Y02E60/122
摘要： Electrode assemblies for use in electrochemical cells are provided. The negative electrode assembly comprises negative electrode active material and an electrolyte chosen specifically for its useful properties in the negative electrode. These properties include reductive stability and ability to accommodate expansion and contraction of the negative electrode active material. Similarly, the positive electrode assembly comprises positive electrode active material and an electrolyte chosen specifically for its useful properties in the positive electrode. These properties include oxidative stability and the ability to prevent dissolution of transition metals used in the positive electrode active material. A third electrolyte can be used as separator between the negative electrode and the positive electrode.
摘要翻译：提供了用于电化学电池的电极组件。负极组件包括负极活性材料和专门用于其在负极中的有用特性的电解质。这些性质包括还原稳定性和适应负极活性物质的膨胀和收缩的能力。类似地，正电极组件包括正电极活性材料和专门用于其在正电极中的有用特性的电解质。这些性质包括氧化稳定性和防止在正极活性物质中使用的过渡金属溶解的能力。第三电解质可以用作负极和正极之间的隔板。

8. 发明申请

US20110033755A1 PROTECTED LITHIUM METAL ELECTRODES FOR RECHARGEABLE BATTERIES 审中-公开
标题翻译：用于可充电电池的保护的锂金属电极
公开(公告)号：US20110033755A1
公开(公告)日：2011-02-10
申请号：US12988474
申请日：2009-04-21
申请人： Hany Basam Eitouni , Mohit Singh , Nitash Pervez Balsara , William Hudson , Ilan R. Gur
发明人： Hany Basam Eitouni , Mohit Singh , Nitash Pervez Balsara , William Hudson , Ilan R. Gur
IPC分类号： H01M10/052 , H01M4/40 , H01M10/0565 , H01M10/056 , H01M4/04 , B05D7/00 , B29C47/06
CPC分类号： H01M10/0565 , H01M4/134 , H01M4/366 , H01M4/386 , H01M4/387 , H01M4/405 , H01M10/052 , H01M10/058 , H01M2300/0094
摘要： It has long been recognized that replacing the Li intercalated graphitic anode with a lithium foil can dramatically improve energy density due to the dramatically higher capacity of metallic lithium. However, lithium foil is not electrochemically stable in the presence of typical lithium ion battery electrolytes and thus a simple replacement of graphitic anodes with lithium foils is not possible. It was found that diblock or triblock polymers that provide both ionic conduction and structural support can be used as a stable passivating layer on a lithium foil. This passivation scheme results in improved manufacture processing for batteries that use Li electrodes and in improved safety for lithium batteries during use.
摘要翻译：长期以来，已经认识到用锂箔替代Li插层石墨阳极可以显着提高能量密度，这是由于金属锂的容量显着提高。然而，在典型的锂离子电池电解质的存在下，锂箔不是电化学稳定的，因此用锂箔简单地代替石墨阳极是不可能的。发现提供离子传导和结构支持的二嵌段或三嵌段聚合物可以用作锂箔上的稳定的钝化层。这种钝化方案导致改进了使用锂电极的电池的制造处理，并且在使用期间改善了锂电池的安全性。

9. 发明授权

US09324985B2 Block copolymer battery separator 有权
标题翻译：嵌段共聚物电池隔膜
公开(公告)号：US09324985B2
公开(公告)日：2016-04-26
申请号：US14006576
申请日：2012-03-22
申请人： David Wong , Nitash Pervez Balsara
发明人： David Wong , Nitash Pervez Balsara
IPC分类号： C08J3/09 , H01M2/16 , H01M2/14
CPC分类号： H01M2/145 , H01M2/1653
摘要： The invention herein described is the use of a block copolymer/homopolymer blend for creating nanoporous materials for transport applications. Specifically, this is demonstrated by using the block copolymer poly(styrene-block-ethylene-block-styrene) (SES) and blending it with homopolymer polystyrene (PS). After blending the polymers, a film is cast, and the film is submerged in tetrahydrofuran, which removes the PS. This creates a nanoporous polymer film, whereby the holes are lined with PS. Control of morphology of the system is achieved by manipulating the amount of PS added and the relative size of the PS added. The porous nature of these films was demonstrated by measuring the ionic conductivity in a traditional battery electrolyte, 1M LiPF6 in EC/DEC (1:1 v/v) using AC impedance spectroscopy and comparing these results to commercially available battery separators.
摘要翻译：本文描述的本发明是使用嵌段共聚物/均聚物共混物来制备用于运输应用的纳米多孔材料。具体地说，这通过使用嵌段共聚物聚（苯乙烯 - 嵌段 - 乙烯 - 嵌段 - 苯乙烯）（SES）并将其与均聚物聚苯乙烯（PS）共混来证明。在混合聚合物之后，浇铸膜，并将膜浸没在四氢呋喃中，除去PS。这产生了纳米多孔聚合物膜，由此孔与PS衬里。通过控制添加的PS的量和加入的PS的相对大小来实现系统形态的控制。通过使用AC阻抗谱测量传统电池电解质，EC / DEC（1：1 v / v）中的1M LiPF 6，并将这些结果与市售的电池分离器进行比较，证明了这些膜的多孔性质。

10. 发明授权

US08563168B2 High elastic modulus polymer electrolytes 有权
标题翻译：高弹性模量聚合物电解质
公开(公告)号：US08563168B2
公开(公告)日：2013-10-22
申请号：US12225934
申请日：2007-04-03
申请人： Nitash Pervez Balsara , Mohit Singh , Hany Basam Eitouni , Enrique Daniel Gomez
发明人： Nitash Pervez Balsara , Mohit Singh , Hany Basam Eitouni , Enrique Daniel Gomez
IPC分类号： H01M6/04 , C08C19/42 , H01M6/00 , C08C19/00
CPC分类号： H01M10/0565 , C08F297/02 , C08L53/00 , G01N27/4166 , H01B1/122 , H01M10/052 , H01M10/443 , H01M2300/0082 , C08L2666/02
摘要： A polymer that combines high ionic conductivity with the structural properties required for Li electrode stability is useful as a solid phase electrolyte for high energy density, high cycle life batteries that do not suffer from failures due to side reactions and dendrite growth on the Li electrodes, and other potential applications. The polymer electrolyte includes a linear block copolymer having a conductive linear polymer block with a molecular weight of at least 5000 Daltons, a structural linear polymer block with an elastic modulus in excess of 1×107 Pa and an ionic conductivity of at least 1×10−5 Scm−1. The electrolyte is made under dry conditions to achieve the noted characteristics.
摘要翻译：将高离子电导率与Li电极稳定性所需的结构性质结合的聚合物可用作高能量密度的固相电解质，高循环寿命的电池，不会由于Li电极上的副反应和枝晶生长而发生故障，和其他潜在应用。聚合物电解质包括具有分子量至少为5000道尔顿的导电线性聚合物嵌段的直链嵌段共聚物，弹性模量超过1×10 7 Pa的离子电导率至少为1×10 5 -5 Scm-1。在干燥条件下制备电解质以达到所述特征。

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