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1. 发明申请

US20140155663A1 ENHANCED PROCESS FOR THE HYDROCONVERSION OF HEAVY OILS THROUGH EBULLATED-BED SYSTEMS 审中-公开
标题翻译：通过EBULLED-BED系统对重油进行加氢处理的增强方法
公开(公告)号：US20140155663A1
公开(公告)日：2014-06-05
申请号：US14089470
申请日：2013-11-25
申请人： Giacomo RISPOLI , Giuseppe BELLUSSI , Nicoletta PANARITI , Lorenzo TAGLIABUE
发明人： Giacomo RISPOLI , Giuseppe BELLUSSI , Nicoletta PANARITI , Lorenzo TAGLIABUE
IPC分类号： C10G65/12 , C10G3/00
CPC分类号： C10G65/12 , C10G1/06 , C10G3/46 , C10G3/49 , C10G3/50 , C10G3/56 , C10G45/02 , C10G45/58 , C10G47/00 , C10G47/24 , C10G49/22 , C10G2300/1014 , C10G2300/1037 , C10G2300/4081 , Y02P30/20
摘要： Process for the hydroconversion of heavy oils, selected from crude oils, heavy crude oils, bitumens from tar sands, distillation residues, distillation heavy cuts, distillation deasphalted residues, vegetable oils, oils from coal and oil shale, oils from the thermodecomposition of waste material, polymers, biomasses, comprising sending the heavy oil to a hydroconversion area, effected in one or more ebullated bed reactors, wherein hydrogen is introduced, in the presence of a suitable heterogeneous, supported, hydroconversion catalyst, in addition to a suitable hydrogenation catalyst, nano-dispersed in said heavy oil, and sending the stream coming from the hydroconversion area to a separation area, in which the separated liquid fraction, containing the nano-dispersed catalyst, is recycled to the ebullated bed reactor(s).
摘要翻译：选自原油，重质原油，来自焦油砂的沥青，蒸馏残渣，蒸馏重馏分，蒸馏脱沥青残渣，植物油，煤和油页岩油的重油加氢转化的方法，来自废料的热分解的油聚合物，生物质，包括在合适的非均相负载的加氢转化催化剂的存在下，将一种或多种沸腾床反应器中的氢气引入到加氢转化区域中，将重油送入加氢转化区域，纳米分散在所述重油中，并将来自加氢转化区域的料流送至分离区域，其中将分离的含有纳米分散催化剂的液体馏分循环到沸腾床反应器中。

2. 发明申请

US20060157385A1 Process for the conversion of heavy charges such as heavy crude oils and distillation residues 有权
标题翻译：用于重质原油和蒸馏残渣转化的方法
公开(公告)号：US20060157385A1
公开(公告)日：2006-07-20
申请号：US11311147
申请日：2005-12-20
申请人： Romolo Montanari , Mario Marchionna , Sergio Rosi , Nicoletta Panariti , Alberto Delbianco
发明人： Romolo Montanari , Mario Marchionna , Sergio Rosi , Nicoletta Panariti , Alberto Delbianco
IPC分类号： C10G65/02
CPC分类号： C10G65/18 , C10G67/049 , C10G2300/1033 , C10G2300/107 , C10G2300/1077 , C10G2300/206 , C10G2300/207 , C10G2300/4081 , C10G2300/44 , C10G2300/706
摘要： Heavy hydrocarbon charges are converted in a deasphalting section in the presence of solvents and obtaining two streams, one consisting of deasphalted oil and the other one containing asphaltenes, mixing the deasphalted oil stream with a hydrogenation catalyst and passing the thus obtained mixture to a hydroprocessing section containing hydrogen or hydrogen/H2S, mixing the stream consisting of asphaltenes discharged from the deasphalting section with an appropriate hydrogenation catalyst and passing the obtained mixture to a second hydroprocessing section where it is reacted with hydrogen or a mixture of hydrogen and H2S, passing both the stream containing the reaction product with dispersed catalyst from the hydroprocessing section and the stream containing the reaction product with dispersed catalyst from the second hydroprocessing section, to one or more distillation or flash stages, whereby the more volatile fractions are separated from the distillation residue (tar) or from the liquid discharged from the flash unit, sending the distillation residue (tar) or the liquid discharged from the flash unit, containing the catalyst in the dispersed phase, with a high content of metal sulphides, produced by demetallization of the charge, to a second deasphalting section thereby obtaining deasphalted oil and asphaltenes.
摘要翻译：在溶剂存在下，在脱沥青部分中转化重质烃装料，得到两股流，一种由脱沥青油组成，另一种含有沥青质，将脱沥青油料流与氢化催化剂混合，将得到的混合物通入加氢处理段包含氢或氢/ H 2 S，将由脱沥青部分排出的沥青质组成的料流与合适的氢化催化剂混合，并将所得混合物通入第二加氢处理部分，在其中与氢或氢和H 2 S的混合物，将含有分散催化剂的反应产物的物流从加氢处理段和含有分散催化剂的反应产物的物流从第二加氢处理段送入一个或多个蒸馏或闪蒸阶段，由此将更多的挥发性馏分与蒸馏残余物分离 e（焦油）或从闪蒸装置排出的液体，将含有分散相中的催化剂的闪蒸装置排出的蒸馏残余物（焦油）或含有高含量金属硫化物的液体，通过脱金属从而获得脱沥青油和沥青质。

3. 发明授权

US5932090A Process for the conversion of heavy crude oils and distillation residues to distillates 失效
标题翻译：将重质原油和蒸馏残余物转化为馏出物的方法
公开(公告)号：US5932090A
公开(公告)日：1999-08-03
申请号：US640506
申请日：1996-05-01
申请人： Mario Marchionna , Alberto DelBianco , Nicoletta Panariti
发明人： Mario Marchionna , Alberto DelBianco , Nicoletta Panariti
IPC分类号： B01J31/04 , C10G7/00 , C10G47/20 , C10G47/26 , C10G67/04 , C10G45/00
CPC分类号： C10G47/26 , C10G67/049
摘要： The process for the conversion of heavy crude oils or distillation residues to distillates comprises the following steps:mixing the heavy crude oil or distillation residue with a suitable hydrogenation catalyst and sending the mixture obtained to a hydrotreating reactor introducing hydrogen or a mixture of hydrogen and H.sub.2 S;sending the stream containing the hydrotreating reaction product and the catalyst in slurry phase to a distillation zone where the most volatile fractions are separated;sending the high-boiling fraction obtained in the distillation step to a deasphaltation step obtaining two streams, one consisting of deasphalted oil (DAO), the other consisting of asphaltenes, catalyst in slurry phase, possibly coke and rich in metals coming from the initial charge;recycling at least 60%, preferably at least 80% of the stream consisting of asphaltenes, catalyst in slurry phase, optionally coke and rich in metals, to the hydrotreatment zone.
摘要翻译：将重质原油或蒸馏残余物转化为馏出物的方法包括以下步骤：将重质原油或蒸馏残余物与合适的氢化催化剂混合并将所得混合物送入加氢处理反应器中，引入氢气或氢气和H 2 S的混合物 ; 将含有加氢处理反应产物和催化剂的料流以淤浆相送入蒸馏区，其中最易挥发的馏分被分离; 将在蒸馏步骤中获得的高沸点馏分送至脱沥青步骤，得到两条流，一条由脱沥青油（DAO），另一组成沥青质，浆料相中的催化剂，可能的焦炭和富含金属的初始进料 ; 回收至少60％，优选至少80％的由沥青质组成的物流，浆料相中的催化剂，任选的焦炭和富含金属的物流到加氢处理区。

4. 发明授权

US08123932B2 Process for the conversion of heavy feedstocks such as heavy crude oils and distillation residues 有权
标题翻译：用于转化重质原料如重质原油和蒸馏残余物的方法
公开(公告)号：US08123932B2
公开(公告)日：2012-02-28
申请号：US10538886
申请日：2003-12-12
申请人： Romolo Montanari , Mario Marchionna , Nicoletta Panariti , Alberto Delbianco , Sergio Rosi
发明人： Romolo Montanari , Mario Marchionna , Nicoletta Panariti , Alberto Delbianco , Sergio Rosi
IPC分类号： C10G45/00
CPC分类号： C10G67/049 , C10G2300/1033 , C10G2300/107 , C10G2300/1077 , C10G2300/205 , C10G2300/206 , C10G2300/207 , C10G2300/4081 , C10G2300/44 , C10G2400/02 , C10G2400/06
摘要： A process for the conversion of heavy feedstocks using hydrotreatment, distillation or flash, and deasphalting that includes mixing a heavy feedstock with a hydrogenation catalyst and subjecting the thus-formed mixture to a hydrotreatment reactor for reaction with one or more of hydrogen and hydrogen sulfide to form a first product stream; subjecting the first product stream to a distillation or flash to form a plurality of distillate fractions; and recycling heavies from the distillation residue and/or tar by deasphalting in the presence of a solvent; where the hydrotreatment reaction product is pre-separated under high pressure to form light and heavy fractions and sending the heavy fraction to the distillation and/or flash.
摘要翻译：用于使用加氢处理，蒸馏或闪蒸转化重质原料的方法和脱沥青，其包括将重质原料与氢化催化剂混合并将由此形成的混合物经受加氢处理反应器与氢气和硫化氢中的一种或多种反应，形成第一个产品流; 对第一产物流进行蒸馏或闪蒸以形成多个馏出物馏分; 并在溶剂存在下通过脱沥青从蒸馏残余物和/或焦油中回收重质物; 其中加氢处理反应产物在高压下预分离以形成轻馏分和重馏分，并将重馏分送入蒸馏和/或闪蒸。

5. 发明授权

US07255795B2 Process for selectively removing molybdenum from liquid mixtures containing it together with vanadium 有权
标题翻译：从含有钒的液体混合物中选择性除去钼的方法
公开(公告)号：US07255795B2
公开(公告)日：2007-08-14
申请号：US10478501
申请日：2002-05-14
申请人： Emilio Sentimenti , Nicoletta Panariti
发明人： Emilio Sentimenti , Nicoletta Panariti
IPC分类号： C02F1/62 , C02F101/20
CPC分类号： C22B34/34 , C01G39/003 , C01G39/06 , C22B3/0031 , C22B34/22 , Y02P10/234 , Y10S210/912
摘要： Process for selectively removing molybdenum from liquid mixtures containing it, in a quantity greater than (200) mg/l, together with vanadium characterized in that it comprises the following steps: bringing the liquid mixture to a pH of less than (3); adding a solution of an alkaline xanthate to the solution so that the molar ratio molybdenum/alkaline xanthate ranges from (¼) to (⅛), maintaining the pH constant by means of the addition of an inorganic acid; stirring the mixture causing the precipitation of the molybdenum present in the mixture.
摘要翻译：从含有它的液体混合物中选择性地除去钼的方法，其量大于（200）mg / l，与钒一起，其特征在于其包括以下步骤：使液体混合物的pH低于（3）; 向溶液中加入碱性黄原酸盐溶液，使得钼/碱金黄酸盐的摩尔比范围为（¼）至（1/8），通过加入无机酸保持pH恒定; 搅拌混合物导致存在于混合物中的钼沉淀。

6. 发明申请

US20060272982A1 Process for the conversion of heavy charge stocks such as heavy crude oils and distillation residues 审中-公开
标题翻译：重质原油（如重质原油和蒸馏残渣）的转化工艺
公开(公告)号：US20060272982A1
公开(公告)日：2006-12-07
申请号：US11311134
申请日：2005-12-20
申请人： Romolo Montanari , Mario Marchionna , Sergio Rosi , Nicoletta Panariti , Alberto Delbianco
发明人： Romolo Montanari , Mario Marchionna , Sergio Rosi , Nicoletta Panariti , Alberto Delbianco
IPC分类号： C10C3/00 , C10G1/00
CPC分类号： C10G67/049 , C10G2300/1033 , C10G2300/107 , C10G2300/1077 , C10G2300/206 , C10G2300/207 , C10G2300/4081 , C10G2300/44
摘要： Process for the conversion of heavy charge stocks selected from heavy and extra-heavy crude oils, distillation residues, heavy oils from catalytic treatment, thermal tars, bitumens from oil sands, carbons of different origins and other high boiling charges of a hydrocarbon origin known as “black oils”, by means of the combined used of at least the three following process units: solvent deasphalting (SDA), hydroconversion with slurry phase catalysts (HT), distillation or flash (D), characterized in that it comprises the following steps: sending the heavy charge stock to a deasphalting section (SDA) in the presence of solvents, obtaining two streams, one consisting of deasphalted oil (DAO), the other containing asphaltenes; mixing the stream consisting of deasphalted oil (DAO) with a suitable hydrogenation catalyst precursor and sending the mix obtained to a hydrotreating reactor (HT), introducing, into the same reactor, hydrogen or a mix containing hydrogen and H2S; sending the stream containing the product of the hydrotreatment reaction and the catalyst in dispersed phase to one or more distillation or flash (D) steps, by means of which the most volatile fractions are separated, among which the gases produced in the hydrotreatment reaction, from the distillation residue (tar) or from the liquid coming from the flash unit; recycling of at least a portion of the distillation residue (tar) or the liquid coming from the flash unit, containing catalyst in dispersed phase, rich in metal sulphides produced by de-metallization of the charge and possibly coke, to the hydrotreating section (HT).
摘要翻译：将重质原油，超重原油，蒸馏残渣，来自催化处理的重油，热焦油，油砂沥青，不同来源的碳和其他烃源头的其他高沸点电荷称重的重质原料转化的方法通过组合使用至少三个以下工艺单元：溶剂脱沥青（SDA），用浆料相催化剂（HT），蒸馏或闪蒸（D）加氢转化，“黑油”，其特征在于它包括以下步骤：在溶剂存在下将沉重的原料送到脱沥青部分（SDA），得到两条流，一条由脱沥青油（DAO）组成，另一条含有沥青质; 将由脱沥青油（DAO）组成的料流与合适的氢化催化剂前体混合并将得到的混合物送入加氢处理反应器（HT），将相同的反应器中的氢气或含有氢气和H 2 SUB> S; 将含有分散相中的加氢处理反应产物和催化剂的物流送入一个或多个蒸馏或闪蒸（D）步骤，通过该步骤分离最挥发性馏分，其中在加氢处理反应中产生的气体从蒸馏残渣（焦油）或来自闪光单元的液体; 回收至少一部分蒸馏残余物（焦油）或来自闪蒸单元的液体，其含有分散相中的催化剂，富含金属硫化物，通过电荷的去金属化和可能的焦化产生至加氢处理部分（HT））。

7. 发明申请

US20140197070A1 PROCESS FOR THE CONVERSION OF HEAVY CHARGES SUCH AS HEAVY CRUDE OILS AND DISTILLATION RESIDUES 审中-公开
标题翻译：重金属转换的过程如重油原油和蒸馏残留物
公开(公告)号：US20140197070A1
公开(公告)日：2014-07-17
申请号：US14083237
申请日：2013-11-18
申请人： Mario MARCHIONNA , Alberto DELBIANCO , Nicoletta PANARITI , Romolo MONTANARI , Sergio ROSI , Sebastiano CORRERA
发明人： Mario MARCHIONNA , Alberto DELBIANCO , Nicoletta PANARITI , Romolo MONTANARI , Sergio ROSI , Sebastiano CORRERA
IPC分类号： C10G67/04
CPC分类号： C10G67/0454 , C10G67/00 , C10G2300/1033 , C10G2300/107 , C10G2300/1077 , C10G2300/205 , C10G2300/206 , C10G2300/207 , C10G2300/4081 , C10G2300/44 , Y02P30/20
摘要： A process for converting a heavy charge such as a heavy crude oil, a tar from oil sand and a distillation residue, by combining a hydroconversion with catalysts in slurry phase process, a distillation or flash process, and a deasphalting process, wherein the three processes operate on mixed streams consisting of fresh charge and recycled streams.
摘要翻译：一种通过在淤浆相方法中组合加氢转化与催化剂，蒸馏或闪蒸过程和脱沥青方法来转化重质原油，来自油砂的焦油和蒸馏残余物的重质装料的方法，其中三种方法操作由新鲜电荷和再循环流组成的混合流。

8. 发明申请

US20130112593A1 PROCESS FOR THE CONVERSION OF HEAVY CHARGE STOCKS SUCH AS HEAVY CRUDE OILS AND DISTILLATION RESIDUES 审中-公开
标题翻译：重型货物转换的过程如重油原油和蒸馏残留物
公开(公告)号：US20130112593A1
公开(公告)日：2013-05-09
申请号：US13490647
申请日：2012-06-07
申请人： Romolo MONTANARI , Mario Marchionna , Sergio Rosi , Nicoletta Panariti , Alberto Delbianco
发明人： Romolo MONTANARI , Mario Marchionna , Sergio Rosi , Nicoletta Panariti , Alberto Delbianco
IPC分类号： C10G7/12
CPC分类号： C10G67/049 , C10G2300/1033 , C10G2300/107 , C10G2300/1077 , C10G2300/206 , C10G2300/207 , C10G2300/4081 , C10G2300/44
摘要： Process for the conversion of heavy charge stocks selected from heavy and extra-heavy crude oils, distillation residues, heavy oils from catalytic treatment, thermal tars, bitumens from oil sands, carbons of different origins and other high boiling charges of a hydrocarbon origin known as “black oils”, using at least the following process units: solvent deasphalting (SDA), hydroconversion with slurry phase catalysts (HT), distillation or flash (D), which process includes:solvent deasphalting, thereby forming a deasphthalted oil (DAO), as described;hydrotreating the DAO in the presence of a hydrogenation catalyst precursor and hydrogen or hydrogen and H2S, as described;sending the product therefrom to distillation or flash (D) step(s), and separating the most volatile fractions from the distillation residue (tar) or from the liquid coming from the flash unit, as described;recycling at least a portion of the tar or the liquid, to the hydrotreating section, as described.
摘要翻译：将重质原油，超重原油，蒸馏残渣，来自催化处理的重油，热焦油，油砂沥青，不同来源的碳和其他烃源头的其他高沸点电荷称重的重质原料转化的方法至少使用以下处理单元：溶剂脱沥青（SDA），用浆料相催化剂（HT），蒸馏或闪蒸（D）加氢转化的“黑油”，该方法包括：溶剂脱沥青，从而形成脱油（DAO），如所描述的; 在加氢催化剂前体和氢气或氢气和H 2 S的存在下加氢处理DAO，如上所述; 将产物从其中蒸馏或闪蒸（D）步骤，并从蒸馏残余物（焦油）中或从闪蒸装置的液体中分离出最挥发性的馏分，如所述; 将至少一部分焦油或液体再循环到加氢处理部分，如所述。

9. 发明授权

US08057660B2 Process for the total conversion of heavy feedstocks to distillates 有权
标题翻译：将重质原料总量转化为馏出物的方法
公开(公告)号：US08057660B2
公开(公告)日：2011-11-15
申请号：US12375615
申请日：2007-07-27
申请人： Mario Marchionna , Salvatore Meli , Luigi Patron , Alberto Delbianco , Nicoletta Panariti
发明人： Mario Marchionna , Salvatore Meli , Luigi Patron , Alberto Delbianco , Nicoletta Panariti
IPC分类号： C10G45/00
CPC分类号： C10G67/049 , C10G2300/1033 , C10G2300/107 , C10G2300/1077 , C10G2300/205 , C10G2300/206 , C10G2300/207 , C10G2300/4081 , C10G2300/44 , C10G2400/02 , C10G2400/06
摘要： Process for the conversion of heavy feedstocks selected from heavy crude oils, distillation residues from crude oil or catalytic treatment, “visbreaker tars”, “thermal tars”, bitumens from “oil sands” liquids from coals of different origins and other high boiling feedstocks of a hydrocarbon origin.
摘要翻译：将重质原油，原油蒸馏残渣或催化处理的重质原料转化为不同来源的煤的“油砂”液体和其他高沸点原料的“脱蜡剂焦油”，“热焦油” 烃类来源。

10. 发明申请

US20110253594A1 PROCESS FOR THE CONVERSION OF HEAVY CHARGES SUCH AS HEAVY CRUDE OILS AND DISTILLATION RESIDUES 审中-公开
标题翻译：重金属转换的过程如重油原油和蒸馏残留物
公开(公告)号：US20110253594A1
公开(公告)日：2011-10-20
申请号：US13169950
申请日：2011-06-27
申请人： Mario MARCHIONNA , Alberto Delbianco , Nicoletta Panariti , Romolo Montanari , Sergio Rosi , Sebastiano Correra
发明人： Mario MARCHIONNA , Alberto Delbianco , Nicoletta Panariti , Romolo Montanari , Sergio Rosi , Sebastiano Correra
IPC分类号： C10G3/00
CPC分类号： C10G67/0454 , C10G67/00 , C10G2300/1033 , C10G2300/107 , C10G2300/1077 , C10G2300/205 , C10G2300/206 , C10G2300/207 , C10G2300/4081 , C10G2300/44 , Y02P30/20
摘要： Process for the conversion of heavy charges such as heavy crude oils, tars from oil sands and distillation residues, by the combined use of the following three process units: hydroconversion with catalysts in slurry phase (HT), distillation or flash (D), deasphalting (SDA), characterized in that the three units operate on mixed streams consisting of fresh charge and recycled streams, by the use of the following steps: sending at least one fraction of the heavy charge to a deasphalting section (SDA) in the presence of hydrocarbon solvents obtaining two streams, one consisting of deasphalted oil (DAO), the other of asphalts; mixing the asphalt with a suitable hydrogenation catalyst and optionally with the remaining fraction of heavy charge not sent to the deasphalting section and sending the mixture obtained to a hydro-treatment reactor (HT) into which hydrogen or a mixture of hydrogen and H2S is charged; sending the stream containing the hydro-treatment reaction product and the catalyst in dispersed phase to one or more distillation or flash steps (D) whereby the most volatile fractions are separated, among which the gases produced in the hydro-treatment reaction; recycling at least 60% by weight, preferably at least 80%, more preferably at least 95%, of the distillation residue (tar) or liquid leaving the flash unit, containing the catalyst in dispersed phase, rich in metallic sulfides produced by demetallation of the charge and possibly coke, to the deasphalting zone.
摘要翻译：通过组合使用以下三个工艺单元，将重质原油，来自油砂和蒸馏残余物的焦油转化为重质装料的方法：用浆液相（HT），蒸馏或闪蒸（D）中的催化剂进行加氢转化，脱沥青（SDA），其特征在于，三个单元通过使用以下步骤在由新鲜电荷和再循环流组成的混合流中操作：将至少一部分重电荷发送到脱沥青部分（SDA），存在烃溶剂获得两股，一种由脱沥青油（DAO），另一种沥青组成; 将沥青与合适的氢化催化剂混合，并且任选地将剩余部分的重质进料混合物送入脱沥青部分，并将得到的混合物送入氢气或氢气与H 2 S的混合物的氢化反应器（HT）中; 将含有分散相中的加氢处理反应产物和催化剂的物流送至一个或多个蒸馏或快速步骤（D），由此分离出最挥发性馏分，其中在加氢处理反应中产生的气体; 回收至少60重量％，优选至少80％，更优选至少95％的蒸馏残余物（焦油）或离开闪蒸单元的液体，其含有分散相中的催化剂，富含金属硫化物，其通过脱金属该充电并可能焦化到脱沥青区。

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