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1. 发明授权

US4344867A Hydroprocessing catalysts 失效
标题翻译：加氢催化剂
公开(公告)号：US4344867A
公开(公告)日：1982-08-17
申请号：US65958
申请日：1979-08-13
申请人： Neville L. Cull , Willard H. Sawyer
发明人： Neville L. Cull , Willard H. Sawyer
IPC分类号： B01J23/85 , C10G49/04 , B01J21/04 , B01J23/88 , B01J27/04
CPC分类号： C10G49/04 , B01J23/85
摘要： A catalyst comprising Group VIB and Group VIII metal components and a support prepared by treating alpha alumina monohydrate with an acid solution comprising a hydrolyzable metal salt, such as zirconium nitrate.
摘要翻译：包含VIB族和VIII族金属组分的催化剂和通过用包含可水解金属盐如硝酸锆的酸溶液处理α氧化铝一水合物制备的载体。

2. 发明授权

US4277373A Alumina-aluminum fluorophosphate-containing catalysts 失效
标题翻译：含氧化铝 - 含氟磷酸铝的催化剂
公开(公告)号：US4277373A
公开(公告)日：1981-07-07
申请号：US66940
申请日：1979-08-16
申请人： Willard H. Sawyer , Neville L. Cull
发明人： Willard H. Sawyer , Neville L. Cull
IPC分类号： B01J29/14 , C10G49/08 , B01J27/14 , B01J29/06
CPC分类号： B01J29/146 , C10G49/08
摘要： A catalyst is provided which comprises an ultrastable Y-type crystalline aluminosilicate zeolite, an alumina-aluminum fluorophosphate and a hydrogenation component. Hydrocarbon hydroprocessing processes utilizing the catalyst are also provided.
摘要翻译：提供了一种催化剂，其包括超稳定的Y型结晶硅铝酸盐沸石，氧化铝 - 铝氟磷酸盐和氢化组分。还提供了利用催化剂的烃加氢处理方法。

3. 发明授权

US4255288A Zirconia-containing catalysts 失效
标题翻译：含氧化锆的催化剂
公开(公告)号：US4255288A
公开(公告)日：1981-03-10
申请号：US65768
申请日：1979-08-13
申请人： Neville L. Cull , Willard H. Sawyer
发明人： Neville L. Cull , Willard H. Sawyer
IPC分类号： B01J29/16 , C10G49/08 , B01J29/10
CPC分类号： B01J29/166 , C10G49/08
摘要： A catalyst comprising an ultrastable Y-type crystalline aluminosilicate zeolite, alumina, zirconia and a hydrogenation component is prepared by specified methods. The catalysts are suitable as hydrocarbon hydroprocessing catalysts.
摘要翻译：通过特定方法制备包含超稳定Y型结晶硅铝酸盐沸石，氧化铝，氧化锆和氢化组分的催化剂。催化剂适用作烃加氢催化剂。

4. 发明授权

US4498975A Phosphorus-containing catalyst and catalytic cracking process utilizing the same 失效
标题翻译：含磷催化剂及其催化裂化工艺
公开(公告)号：US4498975A
公开(公告)日：1985-02-12
申请号：US569239
申请日：1984-01-09
申请人： Lloyd A. Pine , Neville L. Cull
发明人： Lloyd A. Pine , Neville L. Cull
IPC分类号： B01J29/08 , C10G11/05
CPC分类号： B01J29/08 , C10G11/05
摘要： A phosphorus-containing low alkali metal content zeolitic catalyst made from a clay starting material is provided. The catalyst is obtained by contacting a partially cation exchanged calcined zeolite-containing catalyst with a dihydrogen phosphate anion or a dihydrogen phosphite anion. A hydrocarbon catalytic cracking process utilizing the phosphorus-containing catalyst is also provided.
摘要翻译：提供由粘土起始材料制成的含磷低碱金属含量沸石催化剂。催化剂是通过将部分阳离子交换的含煅烧沸石的催化剂与磷酸二氢盐或二氢亚磷酸根阴离子接触而获得的。还提供了利用含磷催化剂的烃催化裂化方法。

5. 发明授权

US4251496A Process for the removal of SO.sub.x and NO.sub.x from gaseous mixture containing the same 失效
标题翻译：从含有它们的气态混合物中除去SOx和NOx的方法
公开(公告)号：US4251496A
公开(公告)日：1981-02-17
申请号：US22924
申请日：1979-03-22
申请人： John M. Longo , Neville L. Cull
发明人： John M. Longo , Neville L. Cull
IPC分类号： B01D53/60 , B01D53/00
CPC分类号： B01D53/60
摘要： A combination process is provided in which a gaseous mixture comprising SO.sub.x and NO.sub.x is reacted with cerium oxide at a temperature ranging from about 500.degree. C. to about 700.degree. C. to form cerium oxysulfate and a gas which is at least partially desulfurized. The latter is contacted with cerium oxysulfate at a temperature ranging from about 500.degree. C. to about 700.degree. C. in the presence of ammonia at net oxidizing conditions to reduce the NO.sub.x content of the gaseous mixture. The process may be conducted in one reaction zone or in a plurality of reaction zones. The cerium oxide reactant may be regenerated by reacting cerium oxysulfate with a reducing gas such as hydrogen.
摘要翻译：提供了一种组合方法，其中包含SO x和NO x的气体混合物在约500℃至约700℃的温度下与氧化铈反应以形成硫酸氧铈和至少部分脱硫的气体。在氨的存在下，后者在硫酸氧化条件下，在约500℃至约700℃的温度范围内与硫酸氧硫酸盐接触，以降低气态混合物的NOx含量。该方法可在一个反应区或多个反应区中进行。氧化铈反应物可以通过硫代硫酸镍与还原气体如氢气反应来再生。

6. 发明授权

US4085195A Sorbent preparation and process using same 失效
标题翻译：吸附剂的制备及使用方法
公开(公告)号：US4085195A
公开(公告)日：1978-04-18
申请号：US476669
申请日：1974-06-05
申请人： Neville L. Cull , Lloyd A. Pine , Dale D. Maness
发明人： Neville L. Cull , Lloyd A. Pine , Dale D. Maness
IPC分类号： B01D53/02 , B01D53/50 , B01J8/00 , C01B17/00
CPC分类号： B01D53/508 , B01D53/02 , B01D53/50 , Y10S502/517
摘要： Process for preparing surface impregnated catalysts and sorbents, and flue gas desulfurization process using the same. The sorbent is produced by pre-soaking a porous solid particulate carrier material in a polar organic liquid such as a C.sub.5 -C.sub.10 alcohol, immersing the carrier without drying in an impregnating solution for a time sufficient to permit the impregnating solution to penetrate to a controlled depth without totally impregnating the carrier, and drying and calcining the impregnated carrier, whereby a contact material having an inner zone of substantially unimpregnated carrier and an outer zone of carrier impregnated with active material is produced. Sulfur dioxide is removed from flue gas by contacting the flue gas with a sorbent thus prepared. The preferred carrier for flue gas desulfurization is alumina and the preferred active material is copper oxide.
摘要翻译：制备表面浸渍催化剂和吸附剂的方法，以及使用其的烟道气脱硫方法。吸附剂通过将多孔固体颗粒载体材料预浸泡在极性有机液体如C 5 -C 10醇中来制备，将载体浸没在浸渍溶液中而不干燥一段时间，足以允许浸渍溶液渗入受控的深度而不完全浸渍载体，并干燥和煅烧浸渍的载体，由此制备具有基本上未浸渍的载体的内部区域和浸渍有活性材料的载体的外部区域的接触材料。通过使烟道气与如此制备的吸附剂接触，从烟道气中除去二氧化硫。烟气脱硫的优选载体是氧化铝，优选的活性物质是氧化铜。

7. 发明授权

US4326947A Hydrocracking over alumina-aluminum fluorophosphate-containing catalysts 失效
标题翻译：在含氧化铝 - 含氟磷酸铝的催化剂上进行加氢裂化
公开(公告)号：US4326947A
公开(公告)日：1982-04-27
申请号：US213921
申请日：1980-12-08
申请人： Willard H. Sawyer , Neville L. Cull
发明人： Willard H. Sawyer , Neville L. Cull
IPC分类号： B01J29/14 , B01J29/16 , C10G49/08 , C10G45/12 , C10G47/08
CPC分类号： B01J29/166 , B01J29/146 , C10G49/08
摘要： A catalyst is provided which comprises an ultrastable Y-type crystalline aluminosilicate zeolite, an alumina-aluminum fluorophosphate and a hydrogenation component. Hydrocarbon hydroprocessing processes utilizing the catalyst are also provided.
摘要翻译：提供了一种催化剂，其包括超稳定的Y型结晶硅铝酸盐沸石，氧化铝 - 铝氟磷酸盐和氢化组分。还提供了利用催化剂的烃加氢处理方法。

8. 发明授权

US4233184A Aluminum phosphate-alumina compositions and catalysts comprising the same 失效
标题翻译：磷酸铝 - 氧化铝组合物及其组成的催化剂
公开(公告)号：US4233184A
公开(公告)日：1980-11-11
申请号：US4456
申请日：1979-01-18
申请人： Neville L. Cull
发明人： Neville L. Cull
IPC分类号： B01J27/16 , B01J35/10 , B01J27/14 , B01J31/12
CPC分类号： B01J27/16 , B01J35/1023 , B01J35/1042
摘要： High surface area aluminum phosphate-alumina compositions are prepared by reaction of a mixture comprising an aluminum alkoxide and an organic phosphate such as trialkyl or triaryl phosphate, in the presence of moist air to form a precipitate, separating the precipitate from the mixture, drying and calcining the precipitate and recovering a high surface area aluminum phosphate-alumina product which can be used as catalyst support or catalyst component, especially for hydrocarbon treating and conversion processes.
摘要翻译：通过在潮湿空气存在下，将包含烷氧基铝和有机磷酸酯如三烷基或三芳基磷酸酯的混合物反应制备高表面积的磷酸铝 - 氧化铝组合物以形成沉淀物，将沉淀物与混合物分离，干燥和煅烧沉淀并回收可用作催化剂载体或催化剂组分的高表面积的磷酸铝 - 氧化铝产品，特别是用于烃处理和转化过程。

9. 发明授权

US4152400A Method for treating sulfur dioxide with sorbent 失效
标题翻译：用吸附剂处理二氧化硫的方法
公开(公告)号：US4152400A
公开(公告)日：1979-05-01
申请号：US819049
申请日：1977-07-26
申请人： Martin O. Gernand , Dale D. Maness , Neville L. Cull
发明人： Martin O. Gernand , Dale D. Maness , Neville L. Cull
IPC分类号： B01D53/02 , B01D53/50 , B01D53/81 , B01D53/86 , B01J37/02 , B01J8/00 , C01B17/00
CPC分类号： B01D53/508 , B01D53/02 , B01D53/8628 , B01J37/0207
摘要： Process for preparing shaped base materials for use in solid catalysts for commercial processes. The solid contact material is prepared by pre-soaking a porous solid particulate carrier material in an organic liquid, immersing the carrier without drying in a dilute acid solution for a given time interval, washing, drying and calcining the impregnated carrier. After calcination, the carrier is impregnated with an active material.
摘要翻译：制备用于商业工艺的固体催化剂的成形基材的方法。固体接触材料通过将多孔固体颗粒载体材料预浸泡在有机液体中，将载体浸没在干燥酸性溶液中一定时间间隔，洗涤，干燥和煅烧浸渍的载体来制备。煅烧后，用活性物质浸渍载体。

10. 再颁专利

USRE29771E Flue gas desulfurization sorbent 失效
标题翻译：烟气脱硫吸附剂
公开(公告)号：USRE29771E
公开(公告)日：1978-09-19
申请号：US834528
申请日：1977-09-19
申请人： Neville L. Cull , Warren M. Smith
发明人： Neville L. Cull , Warren M. Smith
IPC分类号： B01D53/02 , C01B17/60
CPC分类号： B01D53/02 , C01B17/60
摘要： Sulfur dioxide is removed from gas mixtures such as flue gas containing the same by contacting the gas mixture with a solid sorbent comprising a porous gamma-alumina base, about 2 to 20 percent by weight (based on alumina) of a coating of a refractory oxide such as titanium dioxide, zirconium dioxide, or silica, and an active material, such as copper oxide, which is capable of selective removal of sulfur oxides from a gas mixture.

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