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    • 1. 发明授权
    • Photochromic optical article
    • 光致变色光学制品
    • US07452611B2
    • 2008-11-18
    • US10229773
    • 2002-08-28
    • William P. BlackburnMichael B. LevesqueKevin W. SeybertJeanine A. ConklinNancyanne Gruchacz
    • William P. BlackburnMichael B. LevesqueKevin W. SeybertJeanine A. ConklinNancyanne Gruchacz
    • B32B27/08G02C7/02
    • G02B5/23Y10T428/31507Y10T428/31551Y10T428/31855Y10T428/31873
    • Describes a photochromic plastic article, e.g., an ophthalmic photochromic article, such as a lens, in which the article includes (1) a polymeric substrate, such as a thermoset or thermoplastic substrate, (2) a photochromic polymeric coating appended to at least one surface of the substrate, the photochromic polymeric coating containing a photochromic amount of at least one organic photochromic material, e.g., spirooxazine, naphthopyran and/or fulgide, and (3) a radiation-cured, acrylate-based film coherently appended to the photochromic coating, the acrylate-based film being (a) resistant to removal by aqueous solutions of inorganic caustic, e.g., potassium hydroxide, (b) compatible with organo silane-containing abrasion-resistant coating, and (c) harder than said photochromic coating. Describes also the aforedescribed photochromic article having an abrasion-resistant coating affixed to the radiation-cured acrylate-based film, e.g., an abrasion-resistant coating comprising an organo silane; and a photochromic article having an antireflective coating affixed to the abrasion-resistant coating.
    • 描述光致变色塑料制品,例如眼睛光致变色制品,例如透镜,其中制品包括(1)聚合物基底,例如热固性或热塑性基底,(2)附着于至少一个的光致变色聚合物涂层 所述光致变色聚合物涂层含有光致变色量的至少一种有机光致变色材料,例如螺恶嗪,萘并吡喃和/或抗体,和(3)辐射固化的丙烯酸酯基膜,其相干地附着到光致变色涂层 丙烯酸酯类膜是(a)耐除去无机苛性碱的水溶液,例如氢氧化钾,(b)与有机硅烷的耐磨涂层相容,和(c)比所述光致变色涂层更硬。 还描述了上述具有固化到辐射固化的丙烯酸酯基膜上的耐磨涂层的光致变色制品,例如包含有机硅烷的耐磨涂层; 以及具有附着在耐磨涂层上的抗反射涂层的光致变色制品。