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    • 1. 发明授权
    • Liquid crystalline diketopyrrolopyrroles
    • 液晶二酮吡咯并吡咯
    • US5969154A
    • 1999-10-19
    • US988419
    • 1997-12-10
    • Zhimin HaoAbul IqbalNancy TebaldiKlaus Praefcke
    • Zhimin HaoAbul IqbalNancy TebaldiKlaus Praefcke
    • C07D487/04C09K19/34C07D317/12C07D319/06
    • C07D487/04C09K19/3483
    • A liquid crystalline compound of formula ##STR1## wherein B and D are each independently of the other C.sub.6 -C.sub.24 alkyl, ##STR2## L is ##STR3## methyl or C.sub.10 -C.sub.18 alkyl, wherein R.sub.1 is C.sub.4 -C.sub.18 alkyl, with the proviso that when L is methyl, at least one of B and D is C.sub.6 -C.sub.24 alkyl;R2 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, cyano or nitro,R3, R4 and R5 are each independently of one another hydrogen, OR6, SR6, SeR6, --NHR6, --NR6R7, ##STR4## with the proviso that at least one of R3, R4 and R5 is not hydrogen, R6 is C.sub.7 -C.sub.37 alkyl, C.sub.7 -C.sub.37 alkylene or C.sub.5 -C.sub.18 alkyl which is interrupted by 1 to 6 hetero atoms selected from the group consisting of O, S and N,R7 is hydrogen or R9,R8 is hydrogen or C.sub.1 -C.sub.4 alkyl, andR9 is C.sub.1 -C.sub.12 alkyl, C.sub.2 -C.sub.12 alkylene or C.sub.3 -C.sub.12 alkyl which is interrupted by 1 to 6 hetero atoms selected from the group consisting of O, S and N.
    • 一种下式的液晶化合物,其中B和D各自独立于C 6 -C 24烷基,L是甲基或C 10 -C 18烷基,其中R 1是C 4 -C 18烷基,条件是当L是甲基时,B和 D是C 6 -C 24烷基; R 2是氢,C 1 -C 4烷基,C 1 -C 4烷氧基,卤素,氰基或硝基,R 3,R 4和R 5各自彼此独立地是氢,OR 6,SR 6,SeR 6,-NHR 6,-NR 6 R 7,条件是至少一个 的R 3,R 4和R 5不是氢,R 6是被1至6个选自O,S和N的杂原子间隔的C 7 -C 37烷基,C 7 -C 37亚烷基或C 5 -C 18烷基,R 7是氢或R 9, R8为氢或C1-C4烷基,R9为C1-C12烷基,C2-C12亚烷基或C3-C12烷基,其被1至6个选自O,S和N的杂原子间隔。