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1. 发明授权

US4459348A Multi-layer elements suitable for the production of printing plates and relief plates 失效
标题翻译：适用于生产印版和浮雕板的多层元件
公开(公告)号：US4459348A
公开(公告)日：1984-07-10
申请号：US498711
申请日：1983-05-27
申请人： Mong-Jon Jun , Peter Richter , Helmut Barzynski
发明人： Mong-Jon Jun , Peter Richter , Helmut Barzynski
IPC分类号： G03F7/09 , G03C1/93 , G03F7/11 , G03F7/30 , G03C1/78
CPC分类号： G03F7/11 , G03C1/93 , Y10S430/106
摘要： A multi-layer element for the production of printing plates and relief plates which is based on an elastomeric polymer binder and is firmly anchored to a polyester base by means of an adhesive layer. The adhesive layer consists of a thermally hardened mixture which is insoluble in aromatic hydrocarbon solvents or aliphatic halohydrocarbon solvents and contains (c1) from 90 to 40% by weight, based on the sum of (c1) and (c2), of an hydroxyl-containing polyurethane, hydroxyl-containing epoxy, hydroxyl-containing phenoxy resin, polyester-ol or polyether-ol resin which has been hardened and crosslinked with isocyanate, and which has from about 4 to 20% by weight, based on the non-crosslinked and hardenable resin, of free OH groups before hardening and crosslinking with isocyanate, and (c2) from 10 to 60% by weight, based on the sum of (c1) and (c2), of an OH-free polycarbonate which is compatible with the resin (c1) before the latter is hardened and crosslinked.
摘要翻译：一种用于生产基于弹性体聚合物粘合剂并且通过粘合剂层牢固地锚固到聚酯基底的印刷版和凸版的多层元件。粘合剂层由热固化的混合物组成，其不溶于芳烃溶剂或脂族卤代烃溶剂，并且含有（c1）基于（c1）和（c2）之和的90至40重量％含有羟基的环氧树脂，含羟基的苯氧基树脂，聚酯 - 醇或聚醚 - 醇树脂，其已经被异氰酸酯硬化和交联，并且基于未交联和/或交联的约4至20重量％硬化和与异氰酸酯交联之前的游离OH基的可硬化树脂，和（c2）基于（c1）和（c2）之和为10至60重量％的与OH 树脂（c1）在其后硬化和交联。

2. 发明授权

US4421840A Photopolymerizable recording material containing a diisocyanate modified nylon binder 失效
标题翻译：含有二异氰酸酯改性尼龙粘合剂的可光聚合记录材料
公开(公告)号：US4421840A
公开(公告)日：1983-12-20
申请号：US329111
申请日：1981-12-09
申请人： August Lehner , Heinz U. Werther , Dieter Naegele , Werner Lenz , Mong-Jon Jun , Horst Reimann , Albrecht Eckell
发明人： August Lehner , Heinz U. Werther , Dieter Naegele , Werner Lenz , Mong-Jon Jun , Horst Reimann , Albrecht Eckell
IPC分类号： C08G18/60 , C08G18/67 , G03F7/037 , G03C1/78
CPC分类号： G03F7/037 , C08G18/603 , C08G18/67 , C08G18/6705 , Y10S430/107
摘要： A photopolymerizable recording material for the preparation of relief plates comprises a base and a photopolymerizable layer, which layer contains, as the binder, a substantially linear, high molecular weight, thermoplastic diisocyanate-modified nylon which is solid at room temperature and which possesses quaternary and/or quaternizable nitrogen atoms and also possesses photopolymerizable double bonds in side branches.
摘要翻译：用于制备浮雕板的可光聚合记录材料包括基材和可光聚合层，该层含有作为粘合剂的基本上线性，高分子量的热塑性二异氰酸酯改性尼龙，其在室温下是固体，并且具有季和 /或可季铵化的氮原子，并且在侧枝中也具有可光聚合的双键。

3. 发明授权

US4320188A Photopolymerizable compositions containing elastomers and photo-curable elements made therefrom 失效
标题翻译：含有由其制成的弹性体和可光固化元件的光聚合组合物
公开(公告)号：US4320188A
公开(公告)日：1982-03-16
申请号：US197790
申请日：1980-10-17
申请人： Gerhard Heinz , Peter Richter , Mong-Jon Jun
发明人： Gerhard Heinz , Peter Richter , Mong-Jon Jun
IPC分类号： C08F2/00 , C08F2/48 , C08F16/12 , C08F16/14 , C08F20/10 , C08F20/18 , C08F287/00 , C08F297/00 , C08F297/04 , G03F7/033 , G03C1/68
CPC分类号： C08F287/00 , G03F7/033 , Y10S430/106 , Y10S430/111
摘要： Photopolymerizable compositions based on an elastomeric styrene-diene block polymer, one or more photopolymerizable olefinically unsaturated monomers and one or more photopolymerization initiators exhibit improved properties if they contain, as an essential constituent, an elastomeric block copolymer of the general structure A-B-C, where A is a thermoplastic, non-elastomeric polymer block based on styrene compounds and having a second order transition point above +25.degree. C., B is an elastomeric polymer block based on butadiene and/or isoprene and having a second order transition point below -20.degree. C. and C is a polymer block, different from B, having a second order transition point of from -30.degree. C. to +15.degree. C., C being either a homopolymer or copolymer block based on butadiene or isoprene or a random copolymer block based on conjugated dienes and styrene compounds. The photopolymerizable compositions may be used, inter alia, for the production of photo-curable adhesives, resilient and flexible sheet material and, in particular, flexographic relief printing plates.
摘要翻译：基于弹性体苯乙烯 - 二烯嵌段聚合物，一种或多种光聚合性烯属不饱和单体和一种或多种光聚合引发剂的光聚合组合物如果含有一般结构ABC的弹性体嵌段共聚物作为必要成分，则表现出改进的性能，其中A为基于苯乙烯化合物的热塑性非弹性体聚合物嵌段，并且具有高于+ 25℃的二级转变点，B是基于丁二烯和/或异戊二烯并且具有低于-20℃的二级转变点的弹性体聚合物嵌段 C.和C是不同于B的聚合物嵌段，其二级转变点为-30℃至+ 15℃，C为基于丁二烯或异戊二烯的均聚物或共聚物嵌段或无规共聚物基于共轭二烯和苯乙烯化合物的嵌段。可光聚合组合物尤其可用于制备光固化粘合剂，弹性和柔性片材，特别是柔性版印刷版。

4. 发明授权

US4198241A Photopolymerizable composition for the manufacture of printing plates and relief plates 失效
标题翻译：用于制造印版和浮雕板的光聚合组合物
公开(公告)号：US4198241A
公开(公告)日：1980-04-15
申请号：US907007
申请日：1978-05-18
申请人： Bernd Bronstert , Werner Kuesters , Mong-Jon Jun , Guenter Wallbillich
发明人： Bernd Bronstert , Werner Kuesters , Mong-Jon Jun , Guenter Wallbillich
IPC分类号： G03C1/00 , C08F2/00 , C08F2/50 , G03F7/004 , G03F7/031 , G03C1/68
CPC分类号： G03F7/031
摘要： A photopolymerizable composition for the manufacture of printing plates and relief plates, based on a mixture, containing a photoinitiator, of photopolymerizable olefinically unsaturated monomers and a polymeric binder, contains up to 0.1% by weight of an etherified thioanthraquinone for improving the relief image in the production of relief plates.The composition advantageously also contains a small amount of an organic tertiary amine or of an aromatic .alpha.-ketocarboxylic acid or its ester and/or of an inhibitor, e.g. the salt of an organic N-nitrosohydroxylamine.
摘要翻译：用于制造基于含有光引发剂的可光聚合的烯属不饱和单体和聚合物粘合剂的混合物的印刷板和浮雕板的可光聚合组合物含有至多0.1重量％的醚化硫蒽醌，用于改进在生产浮雕板。该组合物有利地还含有少量的有机叔胺或芳族α-酮羧酸或其酯和/或抑制剂，例如，有机N-亚硝基羟胺的盐。

5. 发明授权

US4007209A Acetals which act as photoinitiators 失效
标题翻译：充当光引发剂的缩醛
公开(公告)号：US4007209A
公开(公告)日：1977-02-08
申请号：US557046
申请日：1975-03-10
申请人： Eckhard Hickmann , Martin Fischer , Otto Volkert , Mong-Jon Jun
发明人： Eckhard Hickmann , Martin Fischer , Otto Volkert , Mong-Jon Jun
IPC分类号： G03F7/031 , C07D309/08
CPC分类号： C07C49/84 , C07C45/71 , G03F7/031
摘要： The invention relates to special acetals of benzoin compounds which act as photoinitiators, and to a technically simple manufacturing process involving the reaction of an appropriate .alpha.- or .beta.-hydroxyketone with an .alpha.,.beta.-olefinically unsaturated ether in the presence of an acid catalyst. The acetals are particularly suitable for use as photoinitiators in the preparation of photopolymer printing plates.
摘要翻译：本发明涉及用作光引发剂的苯偶姻化合物的特殊缩醛，以及涉及在酸催化剂存在下使合适的α-或β-羟基酮与α，β-烯属不饱和醚反应的技术上简单的制备方法。缩醛特别适用于制备光聚合物印版的光引发剂。

6. 发明授权

US4590144A Photopolymerizable recording material and the production of relief plates using this recording material 失效
标题翻译：可光聚合记录材料，并使用该记录材料生产浮雕板
公开(公告)号：US4590144A
公开(公告)日：1986-05-20
申请号：US630833
申请日：1984-07-13
申请人： Gunnar Schornick , Mong-Jon Jun , Axel Sanner , August Lehner , Werner Lenz , Peter Richter , Albrecht Eckell
发明人： Gunnar Schornick , Mong-Jon Jun , Axel Sanner , August Lehner , Werner Lenz , Peter Richter , Albrecht Eckell
IPC分类号： G03F7/035 , C08F299/06 , C08G18/67 , G03F7/027 , G03F7/032 , G03C1/70 , G03C1/71 , G03F7/10
CPC分类号： G03F7/032 , C08F299/065 , C08G18/6705 , C08G18/675 , Y10S430/107
摘要： A photopolymerizable recording material for the production of relief plates comprises a photopolymerizable layer which can be developed in an alcoholic solution and contains a mixture of a photoinitiator, a photopolymerizable monomer and a linear, high molecular weight polyurethane which possesses activated double bonds in side branches, and is prepared using a polyether-diol from the group comprising the polyethylene glycols, propylene glycols and ethylene glycol/propylene glycol co-condensates.
摘要翻译：用于制备浮雕板的可光聚合记录材料包括可在醇溶液中显影并含有光引发剂，可光聚合单体和在侧枝中具有活化双键的线性高分子量聚氨酯的混合物的光聚合层，并且使用来自包含聚乙二醇，丙二醇和乙二醇/丙二醇共缩合物的组的聚醚二醇制备。

7. 发明授权

US4606994A Process for producing photo-cured printing plates possessing a defined hardness 失效
标题翻译：制造具有规定硬度的光固化印版的方法
公开(公告)号：US4606994A
公开(公告)日：1986-08-19
申请号：US726286
申请日：1985-04-23
申请人： Karl H. Illers , Mong-Jon Jun , Gunnar Schornick
发明人： Karl H. Illers , Mong-Jon Jun , Gunnar Schornick
IPC分类号： G03F7/16 , G03C7/00
CPC分类号： G03F7/168
摘要： Photocured layers possessing a defined controllable hardness are produced by exposing a layer of a photopolymerizable or photocrosslinkable mixture, which contains a partially crystalline polymeric binder possessing olefinic double bonds capable of undergoing polymerization, to actinic light, by a method in which the photocurable layer, prior to exposure to actinic light, is subjected to a heat treatment in which the partially crystalline parts of the polymeric binder are partially or completely fused.
摘要翻译：具有确定的可控硬度的光固化层通过将可光聚合或可光交联的混合物层（其含有具有能够进行聚合的具有烯属双键的部分结晶聚合物粘合剂）暴露于光化学光，通过以下方法曝光：光可固化层，先前曝光于光化性光，经受热处理，其中聚合物粘合剂的部分结晶部分部分或完全熔合。

8. 发明授权

US4547454A Photosensitive multi-layer material and preparation of adhesive layers employed therein 失效
标题翻译：光敏多层材料及其中使用的粘合剂层的制备
公开(公告)号：US4547454A
公开(公告)日：1985-10-15
申请号：US650713
申请日：1984-11-14
申请人： Gerhard Hoffmann , Bernd Bronstert , Herbert Hahn , Mong-Jon Jun
发明人： Gerhard Hoffmann , Bernd Bronstert , Herbert Hahn , Mong-Jon Jun
IPC分类号： G03F7/09 , G03F7/11 , G03C1/78
CPC分类号： G03F7/11
摘要： A photosensitive multi-layer material comprising a base, which may or may not be provided with an adhesion-promoting layer, and a photopolymerizable layer, consisting of a mixture of a photoinitiator, a binder and a photopolymerizable monomer, possesses, between the base and the photopolymerizable layer, an adhesive layer of a hardened mixture of a binder and an etherified melamine-formaldehyde condensate, hardenable at 60.degree.-120.degree. C.
摘要翻译：包含可以具有粘合促进层的基底和由光引发剂，粘合剂和可光聚合单体的混合物组成的可光聚合层的光敏多层材料具有在基底和可光聚合层，粘合剂和醚化的三聚氰胺 - 甲醛缩合物的硬化混合物的粘合剂层，在60-120℃下可硬化。

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