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    • 2. 发明授权
    • Composite polyester/PVA barrier films
    • 复合聚酯/ PVA阻隔膜
    • US5773092A
    • 1998-06-30
    • US852534
    • 1997-05-07
    • Michel PrissetteDidier Veyrat
    • Michel PrissetteDidier Veyrat
    • B32B27/08B29C55/12B29K29/00B29K67/00B29L9/00B32B27/30B32B27/36B32B33/00C08J5/18C08J7/04C09D129/04B05D3/02B05D1/28B05D5/00
    • C08J7/047C09D129/04C08J2367/02C08J2429/00Y10T428/24355Y10T428/24364Y10T428/24967Y10T428/24975Y10T428/31786Y10T428/31797
    • Polyester-based, biaxially oriented composite films having good transparency and gas-barrier properties, exhibiting excellent resistance to mechanical shock and being easily recyclable, comprise a polyester base film (for example shaped from polyethylene terephthalate) 5 .mu.m to 50 .mu.m in thickness, coated on at least one of its two face surfaces with a layer of polyvinyl alcohol having a number-average degree of polymerization equal to or greater than 350 and a thickness less than or equal to 0.3 .mu.m, the mean roughness Rz of the base film being less than or equal to 0.30 .mu.m on the at least one face surface of the film onto which a polyvinyl alcohol layer is coated and said at least one coated face surface comprising, on average, not more than 20 peaks of a height equal to or greater than 1 micrometer and not more than 150 peaks of a height ranging from 0.4 to 1 micrometer, per square millimeter, and such composite films exhibiting a permeability to oxygen, measured at 23.degree. C. at 50% relative humidity, less than or equal to 3 cm.sup.3 /m.sup.2 /24 h.
    • 具有良好透明性和阻气性的聚酯系双轴取向复合膜,具有优异的耐机械冲击性和易于回收利用的聚酯基膜,例如由聚对苯二甲酸乙二醇酯形成的厚度为50μm〜50μm的聚酯基膜 在其两个表面中的至少一个表面上涂覆数均聚合度等于或大于350且厚度小于或等于0.3μm的聚乙烯醇层,基底的平均粗糙度Rz 在其上涂覆有聚乙烯醇层的膜的至少一个表面上具有小于或等于0.30μm的膜,并且所述至少一个涂覆的表面平均包含不超过20个高度相等的峰 至高于1微米且不超过150个高度范围为0.4至1微米/平方毫米的峰,以及在23℃下测量的表现出对氧的渗透性的复合膜a t 50%相对湿度,小于或等于3 cm3 / m2 / 24小时。
    • 3. 发明授权
    • Composite polyester/PVA barrier films
    • 复合聚酯/ PVA阻隔膜
    • US5658676A
    • 1997-08-19
    • US414382
    • 1995-03-31
    • Michel PrissetteDidier Veyrat
    • Michel PrissetteDidier Veyrat
    • B32B27/08B29C55/12B29K29/00B29K67/00B29L9/00B32B27/30B32B27/36B32B33/00C08J5/18C08J7/04C09D129/04D06N7/04
    • C08J7/047C09D129/04C08J2367/02C08J2429/00Y10T428/24355Y10T428/24364Y10T428/24967Y10T428/24975Y10T428/31786Y10T428/31797
    • Polyester-based, biaxially oriented composite films having good transparency and gas-barrier properties, exhibiting excellent resistance to mechanical shock and being easily recyclable, comprise a polyester base film (for example shaped from polyethylene terephthalate) 5 .mu.m to 50 .mu.m in thickness, coated on at least one of its two face surfaces with a layer of polyvinyl alcohol having a number-average degree of polymerization equal to or greater than 350 and a thickness less than or equal to 0.3 .mu.m, the mean roughness Rz of the base film being less than or equal to 0.30 .mu.m on the at least one face surface of the film onto which a polyvinyl alcohol layer is coated and said at least one coated face surface comprising, on average, not more than 20 peaks of a height equal to or greater than 1 micrometer and not more than 150 peaks of a height ranging from 0.4 to 1 micrometer, per square millimeter, and such composite films exhibiting a permeability to oxygen, measured at 23.degree. C. at 50% relative humidity, less than or equal to 3 cm.sup.3 /m.sup.2 /24 h.
    • 具有良好透明性和阻气性的聚酯系双轴取向复合膜,具有优异的耐机械冲击性和易于回收利用的聚酯基膜,例如由聚对苯二甲酸乙二醇酯形成的厚度为50μm〜50μm的聚酯基膜 在其两个表面中的至少一个表面上涂覆数均聚合度等于或大于350且厚度小于或等于0.3μm的聚乙烯醇层,基底的平均粗糙度Rz 在其上涂覆有聚乙烯醇层的膜的至少一个表面上具有小于或等于0.30μm的膜,并且所述至少一个涂覆的表面平均包含不超过20个高度相等的峰 至高于1微米且不超过150个高度范围为0.4至1微米/平方毫米的峰,以及在23℃下测量的表现出对氧的渗透性的复合膜a t 50%相对湿度,小于或等于3 cm3 / m2 / 24小时。