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    • 3. 发明授权
    • Foundry binder compositions and mixes that contain a divalent sulfur compound
    • 铸造粘合剂组合物和含有二价硫化合物的混合物
    • US06426374B1
    • 2002-07-30
    • US09627993
    • 2000-07-28
    • Michael J. Skoglund
    • Michael J. Skoglund
    • B22C122
    • B22C1/14B22C1/22
    • This invention relates to foundry binder compositions that contain a divalent sulfur compound, and/or foundry mixes where the aggregate contains a divalent sulfur compound. The foundry binders and foundry mixes are used to make foundry shapes, e.g. molds and cores. The presence of sulfur in the foundry shape facilitates the removal of foundry shapes (particularly internal cores) from the metal casting which is made by pouring molten metal into a casting assembly in which the foundry shapes are arranged. The invention also relates to a method of preparing foundry shapes, the shapes prepared, a method of making a metal casting, and metal castings by this process.
    • 本发明涉及含有二价硫化合物的铸造粘合剂组合物和/或其中骨料含有二价硫化合物的铸造混合物。 铸造粘合剂和铸造混合物用于制造铸造形状,例如 模具和核心。 铸造形状中的硫的存在有助于从通过将熔融金属浇注到其中布置有铸造形状的铸造组件而制成的金属铸件中去除铸造形状(特别是内部芯)。 本发明还涉及通过该方法制备铸造形状,制备的形状,制造金属铸造的方法和金属铸件的方法。
    • 6. 发明授权
    • Water-borne acrylic emulsion pressure sensitive latex adhesive
composition
    • 水性丙烯酸乳液压敏乳胶胶组成
    • US5416134A
    • 1995-05-16
    • US171196
    • 1993-12-21
    • Michael J. Skoglund
    • Michael J. Skoglund
    • C08K5/521C08L33/06C09J133/04C09J131/02
    • C08K5/521C09J133/04C08L33/062C08L33/064C09J2201/606
    • The present invention is directed to an aqueous emulsion acrylic pressure sensitive adhesive composition that excels in high performance applications. The inventive adhesive composition comprises in water:(I) a polymer system wherein the system is:(A) (a) a copolymer of between about 95 wt-% and 99.9 wt-% of a C.sub.4 -C.sub.18 alkyl (meth)acrylate monomer and between about 0.1 wt-% and 5 wt-% N-alkyl substituted or unsubstituted amide of (meth)acrylic acid, and(b) a homopolymer or copolymer of between about 0 wt-% and 99.8 wt-% of a C.sub.4 -C.sub.18 alkyl (meth)acrylate monomer and about 0.2 wt-% and 100 wt-% of an ethylenically unsaturated carboxylic acid; or(B) (a) a copolymer of between about 90 wt-% and 99.8 wt-% of a C.sub.4 -C.sub.18 alkyl (meth)acrylate monomer and about 0.2 wt-% and 10 wt-% of an ethylenically unsaturated carboxylic acid; and(b) a homopolymer or copolymer of between about 0 wt-% and 99.1 wt-% of a C.sub.4 -C.sub.18 alkyl (meth)acrylate monomer and between about 0.1 wt-% and 100 wt-% N-alkyl substituted or unsubstituted amide of (meth)acrylic acid, or(C) an interpenetrating polymer network emulsion of:(a) a copolymer of a C.sub.4 -C.sub.18 alkyl (meth)acrylate monomer and about 0.2 wt-% and 10 wt-% of an ethylenically unsaturated carboxylic acid, and(b) a copolymer of a C.sub.4 -C.sub.18 alkyl (meth)acrylate monomer and between about 0.1 wt-% and 5 wt-% N-alkyl substituted or unsubstituted amide of (meth)acrylic acid,wherein at least one of (A)(a) or (A)(b) is an aqueous emulsion copolymer made by emulsion polymerization and at least one of (B)(a) or (B)(b) is an aqueous emulsion copolymer made by emulsion polymerization; and(II) a surfactant. Advantageously, the emulsion copolymer(s) includes up to 25% by weight of styrene or other aromatic monomer(s).
    • 本发明涉及一种在高性能应用中优异的水性乳液丙烯酸压敏粘合剂组合物。 本发明的粘合剂组合物在水中包含:(I)聚合物体系,其中该体系为:(A)(a)约95重量%至99.9重量%的(甲基)丙烯酸C 4 -C 18烷基酯单体 和约0.1重量%至5重量%的N-烷基取代或未取代的(甲基)丙烯酸酰胺,和(b)约0重量%至99.8重量%的C4- C18烷基(甲基)丙烯酸酯单体和约0.2wt%和100wt%的烯属不饱和羧酸; 或(B)(a)约90重量%至99.8重量%的(甲基)丙烯酸C 4 -C 18烷基酯单体和约0.2重量%和10重量%的烯属不饱和羧酸的共聚物; 和(b)约0重量%至99.1重量%的(甲基)丙烯酸C 4 -C 18烷基酯单体和约0.1重量%至100重量%的N-烷基取代或未取代的酰胺之间的均聚物或共聚物 的(甲基)丙烯酸,或(C)互穿聚合物网络乳液,其:(a)(甲基)丙烯酸C 4 -C 18烷基酯单体和约0.2重量%至10重量%的烯属不饱和羧酸的共聚物 酸和(b)(甲基)丙烯酸C 4 -C 18烷基酯单体和约0.1重量%至5重量%的N-烷基取代或未取代的(甲基)丙烯酸酰胺的共聚物,其中至少一种 (A)(a)或(A)(b)是通过乳液聚合制备的水性乳液共聚物,(B)(a)或(B)(b)中的至少一种是通过乳液聚合制备的水乳液共聚物; 和(II)表面活性剂。 有利地,乳液共聚物包括至多25重量%的苯乙烯或其它芳族单体。