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    • 4. 发明申请
    • METHOD OF DESIGNING AND EXECUTING A WELL TREATMENT
    • 设计和执行治疗方法
    • US20100175877A1
    • 2010-07-15
    • US12712692
    • 2010-02-25
    • Michael D. ParrisKevin W. England
    • Michael D. ParrisKevin W. England
    • E21B43/16
    • C09K8/52C09K8/685C09K8/74C09K8/887E21B43/26
    • An apparatus and a method for treating a subterranean formation comprising designing a treatment that comprises a composition, wherein the design comprises a pressure influence on a viscosity of the composition, and performing the treatment, wherein the composition is not an energized fluid. An apparatus and a method wherein the viscosity is at least partially estimated based on experimental rheological data collected at pressures below about 500 psi and/or at a pressure that is about 1 atm to about 2,000 atm.An apparatus and a method for exposing a subterranean formation to a composition, comprising forming a composition comprising a polymer and a crosslinker, and pumping the composition into the subterranean formation, wherein the forming the composition comprises selecting the composition components in response to a pressure and temperature of the subterranean formation and experimentally derived behavior of the polymer and the crosslinker at the pressure, temperature, and pH of the subterranean formation. A method wherein the experimentally derived behavior of the polymer and the crosslinker is at least partially estimated based on experimental data at the pressure and temperature of the subterranean formation and/or wherein the pressure experienced by the composition being pumped into the subterranean formation is above 65 atm.
    • 一种用于处理地下地层的设备和方法,包括设计包含组合物的处理,其中所述设计包括对所述组合物的粘度的压力影响,并且进行所述处理,其中所述组合物不是带通的流体。 一种装置和方法,其中基于在低于约500psi的压力和/或约1atm至约2,000atm的压力下收集的实验流变学数据至少部分地估计粘度。 一种用于将地下地层暴露于组合物的装置和方法,包括形成包含聚合物和交联剂的组合物,并将组合物泵送到地层中,其中形成组合物包括响应于压力选择组合物组分, 地下地层的温度和地下地层的压力,温度和pH下的聚合物和交联剂的实验得到的行为。 基于在地层的压力和温度下的实验数据和/或其中被泵入地下地层的组合物经历的压力高于65的方法,其中至少部分地估计聚合物和交联剂的实验衍生行为的方法 atm。
    • 5. 发明授权
    • Method and composition of preparing polymeric fracturing fluids
    • 制备聚合物压裂液的方法和组成
    • US07497263B2
    • 2009-03-03
    • US11285440
    • 2005-11-22
    • Michael D. ParrisIsmail El Kholy
    • Michael D. ParrisIsmail El Kholy
    • E21B43/26
    • C09K8/68C09K8/685C09K8/88C09K8/887
    • In the presence of certain polyols, a guar gum or similar polysaccharide thickener solution is boron crosslinked before achievement of complete hydration of the thickener, without compromising the viscosity level achieved in a fracturing fluid by the time it is pumped into the wellbore and fractures the subterranean formation adjacent the wellbore. Methods continuously involve hydrating a polysaccharide thickener to an extent of 10% to 75%, but less than full hydration. Before 75% hydration is exceeded, a boron crosslinker is added. Upon addition of the boron crosslinker, the fluid is injected into the wellbore to stimulate hydrocarbon production. Because less time is needed for hydration, well site mixing equipment is down-sized smaller to achieve better efficiency and cost savings.
    • 在存在某些多元醇的情况下,瓜尔胶或类似的多糖增稠剂溶液在实现增稠剂的完全水合之前是交联的硼,而不损害在压裂液被泵入井眼中时达到的粘度水平,并破裂了地下 形成在井眼附近。 方法连续地将多糖增稠剂水合至10%至75%,但不足全水合。 在超过75%水合之前,加入硼交联剂。 加入硼交联剂后,将流体注入井眼以刺激烃的生产。 由于水合时间较短,井场混合设备规模较小,可实现更好的效率和成本节约。
    • 9. 发明授权
    • High temperature hydraulic fracturing fluid
    • 高温水力压裂液
    • US06227295B1
    • 2001-05-08
    • US09415400
    • 1999-10-08
    • Thomas O. MitchellMichael D. Parris
    • Thomas O. MitchellMichael D. Parris
    • E21B4326
    • C09K8/685Y10S507/903Y10S507/922
    • A fluid that is useful in stimulation operations, and in particular, in hydraulic fracturing treatments, comprises a carrier fluid; a solvatable, crosslinkable polymer; a cross-linking agent that does not cause substantial cross-linking of the polymer at temperatures less than about 105° F. and a pH of about 10 or greater; and an organic amine stabilizing agent that has a first pKa or a pH in water of at least about 9.5. One group of such amines has the formula H2N—(R1NH)n—H where R1 is C1-C4 alkyl and n is from 1-6. In one embodiment, the cross-linking agent is an organic zirconate, such as bis(hydroxyethyl)glycine zirconate. The organic zirconate is effective to cross-link the polymer when the composition is at a temperature of at least about 105° F., and a pH of about 10 or higher, preferably a pH in the range of about 10.5-12.
    • 在刺激操作中,特别是在水力压裂处理中有用的流体包括载体流体; 可溶解的可交联聚合物; 在低于约105°F的温度和约10或更大的pH的温度下不引起聚合物的实质交联的交联剂; 和具有至少约9.5的第一pKa或水中的pH的有机胺稳定剂。 一类这样的胺具有其中R 1是C 1 -C 4烷基,n是1-6。 在一个实施方案中,交联剂是有机锆酸酯,例如双(羟乙基)甘氨酸锆酸酯。 当组合物处于至少约105°F的温度和约10或更高的pH,优选约10.5-12的pH时,有机锆酸酯可有效交联聚合物。