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    • 5. 发明授权
    • Charging method and charger for non-aqueous electrolyte secondary battery
    • 非水电解质二次电池充电方法及充电器
    • US08541986B2
    • 2013-09-24
    • US13122096
    • 2010-06-15
    • Tatsuki HiraokaMasaya UgajiTaisuke YamamotoKatsumi Kashiwagi
    • Tatsuki HiraokaMasaya UgajiTaisuke YamamotoKatsumi Kashiwagi
    • H02J7/00
    • H02J7/0086H01M10/0525H01M10/441H02J7/0013
    • In a charging method for a non-aqueous electrolyte secondary battery which includes a positive electrode including a lithium-containing composite oxide as an active material, a negative electrode including an alloy-formable negative electrode active material, and a non-aqueous electrolyte, a voltage of the secondary battery is detected. When the detected value is smaller than a predetermined voltage x, charging is performed at a comparatively small current value B. When the detected value is equal to or greater than the predetermined voltage x and smaller than a predetermined voltage z, charging is performed at a comparatively great current value A. When the detected value is equal to or greater than the predetermined voltage z and smaller than a predetermined voltage y, charging is performed at a comparatively small current value C. When the detected value is greater than the predetermined voltage y, constant-voltage charging is performed or charging is terminated. Here, x
    • 在包括含有作为活性物质的含锂复合氧化物的正极的非水电解质二次电池的充电方法中,包含合金成形性负极活性物质的负极和非水电解质, 检测到二次电池的电压。 当检测值小于预定电压x时,以比较小的电流值B进行充电。当检测值等于或大于预定电压x并小于预定电压z时,在 相对较大的电流值A.当检测值等于或大于预定电压z且小于预定电压y时,以相对较小的电流值C进行充电。当检测值大于预定电压y ,执行恒压充电或终止充电。 这里,x
    • 6. 发明授权
    • Negative electrode for non-aqueous electrolyte secondary battery, method for producing the same, and non-aqueous electrolyte secondary battery
    • 非水电解质二次电池用负极及其制造方法以及非水电解质二次电池
    • US08389156B2
    • 2013-03-05
    • US12303854
    • 2007-08-22
    • Katsumi KashiwagiKazuyoshi HondaMasaki HasegawaMasaya UgajiYasutaka KogetsuShuji Ito
    • Katsumi KashiwagiKazuyoshi HondaMasaki HasegawaMasaya UgajiYasutaka KogetsuShuji Ito
    • H01M4/02
    • H01M4/13H01M4/386H01M4/40H01M4/70H01M10/0525H01M2004/025H01M2004/027
    • This invention provides a negative electrode and a non-aqueous electrolyte secondary battery including the negative electrode. The negative electrode includes a Li-absorbing element as a negative electrode active material, is free from deformation, separation of the negative electrode active material layer from the negative electrode current collector, and deposition of lithium on the negative electrode current collector, and is excellent in cycle characteristic, large-current discharge characteristic, and low-temperature discharge characteristic.The negative electrode of this invention includes: a current collector having depressions and protrusions on a surface in the thickness direction thereof; and a negative electrode active material layer that includes a plurality of columns containing a negative electrode active material that absorbs and releases lithium ions, the columns being grown outwardly from the surface of the current collector. The negative electrode of this invention is characterized in that the columns are grown at an inclination angle relative to the direction perpendicular to the surface of the current collector, and that the inclination angle of the columns changes reversibly depending on absorption and release of lithium ions by the negative electrode active material.
    • 本发明提供一种负极和含有负极的非水电解质二次电池。 负极包括作为负极活性物质的Li吸收元件,没有变形,负极活性物质层与负极集电体分离,并且在负极集电体上沉积锂,并且优异 循环特性,大电流放电特性和低温放电特性。 本发明的负极包括:在其厚度方向的表面上具有凹陷和突起的集电器; 以及包含吸收和释放锂离子的负极活性物质的多个列的负极活性物质层,所述列从集电体的表面向外生长。 本发明的负极的特征在于,柱相对于与集电体的表面垂直的方向以倾斜角度生长,并且柱的倾斜角随着锂离子的吸收和释放而可逆地变化 负极活性物质。
    • 10. 发明授权
    • Non-aqueous electrolyte secondary battery
    • 非水电解质二次电池
    • US08067115B2
    • 2011-11-29
    • US12030528
    • 2008-02-13
    • Takayuki ShiraneKaoru InoueMasaya UgajiMasato FujikawaToshitada Sato
    • Takayuki ShiraneKaoru InoueMasaya UgajiMasato FujikawaToshitada Sato
    • H01M4/13H01M4/58
    • H01M10/0525H01M4/13H01M4/131H01M4/485H01M2004/027H01M2300/004
    • A non-aqueous electrolyte secondary battery comprising at least a negative electrode having a current collector provided thereon with convex portions and columnar bodies formed on the convex portions, each of the columnar bodies comprising n stages (where n≧2) of overlaid columnar body portions alternately tilted to different orientations along a longitudinal direction of the current collector, a positive electrode having a positive electrode current collector provided on both surfaces thereof with a positive electrode mixture layer containing a positive electrode active material capable of inserting and extracting lithium ions reversibly, and a separator interposed between the positive electrode and the negative electrode in a confronting manner, wherein tip portions of the columnar body portions at the uppermost stage of the columnar bodies on the negative electrode are tilted toward a trailing end of winding direction.
    • 本发明提供一种非水电解质二次电池,其至少包括具有集电体的至少具有凸部的集电体和形成在所述凸部上的柱状体的负极,每个所述柱状体包括重叠的柱状体部的n个阶段(n≥2) 交替地沿着集电体的纵向方向倾斜到不同的取向,具有正极集电体的正电极在其两个表面上设置有包含能够可逆地插入和提取锂离子的正极活性材料的正电极混合物层,以及 以相对的方式插入在正极和负极之间的隔板,其中在负极上的柱状体的最上段的柱状体部的末端部朝向卷绕方向的后端倾斜。