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    • 3. 发明授权
    • Preparation of conjugated diene polymers modified with an organo-tin or
germanium halide
    • 用有机锡或卤化锗改性的共轭二烯聚合物的制备
    • US5064910A
    • 1991-11-12
    • US448332
    • 1989-12-11
    • Iwakazu HattoriMitsuhiko SakakibaraFumio TsutsumiMasao Yoshizawa
    • Iwakazu HattoriMitsuhiko SakakibaraFumio TsutsumiMasao Yoshizawa
    • C08C19/00C08F36/04
    • C08C19/00C08F36/04
    • A process for producing a modified conjugated diene polymer which comprises the steps of (I) polymerizing a conjugated diene in an inert organic solvent in the presence of a catalyst comprising (a) a lanthanum series rare earth element compound, (b) an organoaluminum compound represented by the general formula, AlR.sup.1 R.sup.2 R.sup.3 (wherein R.sup.1, R.sup.2 and R.sup.3 which may be same or different, are hydrogen atoms or hydrocarbon groups of 1 to 8 carbon atoms and at least one of R.sup.1, R.sup.2 and R.sup.3 is said hydrocarbon group) and, if necessary, at least one member selected from the group consisting of (c) a Lewis acid and/or (d) a Lewis base, and then (II) modifying the resulting reactive polymer with a modifying compound of the general formula, R.sup.4.sub.n MX.sub.4-n (wherein R.sup.4 is an alkyl group of 1 to 20 carbon atoms or an aryl group, M is a tin atom, X is a halogen atom, and n is an integer of 1 to 3).
    • 一种制备改性共轭二烯聚合物的方法,包括以下步骤:(I)在惰性有机溶剂中,在催化剂存在下使共轭二烯聚合,所述催化剂包含(a)镧系稀土元素化合物,(b)有机铝化合物 由通式表示的AlR1R2R3(其中R1,R2和R3可以相同或不同,为氢原子或碳原子数1〜8的烃基,R1,R2和R3中的至少一个为所述烃基) 必要时,选自(c)路易斯酸和/或(d)路易斯碱中的至少一种,然后(II)用下列通式的修饰化合物R4nMX4- n(其中,R 4为碳原子数1〜20的烷基或芳基,M为锡原子,X为卤素原子,n为1〜3的整数)。
    • 5. 发明授权
    • Modified conjugated diene polymer and process for production thereof
    • 改性共轭二烯聚合物及其制备方法
    • US4906706A
    • 1990-03-06
    • US90347
    • 1987-08-28
    • Iwakazu HattoriMitsuhiko SakakibaraFumio TsutsumiMasao Yoshizawa
    • Iwakazu HattoriMitsuhiko SakakibaraFumio TsutsumiMasao Yoshizawa
    • C08C19/00C08F36/04
    • C08C19/00C08F36/04
    • A process for producing a modified conjugated diene polymer which comprises the steps of (I) polymerizing a conjugated diene in an inert organic solvent in the presence of a catalyst comprising (a) a lanthanum series rare earth element compound, (b) an organoaluminum compound represented by the general formula, Alr.sup.1 R.sup.2 R.sup.3 (wherein R.sup.1, R.sup.2 and R.sup.3 which may be same or different, are hydrogen atoms or hydrocarbon groups of 1 to 8 carbon atoms and at least one of R.sup.1, R.sup.2 and R.sup.3 is said hydrocarbon group) and, if necessary, at least one member selected from the group consisting of (c) a Lewis acid and/or (d) a Lewis base, and then (II) modifying the resulting reactive polymer with a modifying compound selected from the group consisting of the following components (e), (f) and (g): (e) an organometal halide compound represented by the general formula, R.sub.n .sup.4 MX.sub.4-n (wherein R.sup.4 is an alkyl group of 1 to 20 carbon atoms or an aryl group, M is a tin or germanium atom, X is a halogen atom, and n is an integer of 1 to 3), (f) a heterocumulene compound or a three-membered heterocyclic compound having, in the molecule, a bond represented by the general formula, ##STR1## (wherein X.sup.1 is a carbon, nitrogen, oxygen or sulfur atom, Y is a carbon or sulfur atom, Z is a nitrogen, oxygen or sulfur atom, and X.sup.2 is a nitrogen, oxygen or sulfur atom), and (g) a halogen compound having, in the molecule, a bond represented by the general formula, ##STR2## (wherein Y.sup.1 is a nitrogen or oxygen atom and X is a halogen atom). Said modified conjugated diene polymer has excellent characteristics in wear resistance, heat generation, mechanical properties, etc.
    • 一种制备改性共轭二烯聚合物的方法,包括以下步骤:(I)在惰性有机溶剂中,在催化剂存在下使共轭二烯聚合,所述催化剂包含(a)镧系稀土元素化合物,(b)有机铝化合物 由通式Alr 1 R 2 R 3(其中可以相同或不同的R 1,R 2和R 3是氢原子或具有1至8个碳原子的烃基,并且R 1,R 2和R 3中的至少一个是所述烃基) 必要时选自(c)路易斯酸和/或(d)路易斯碱中的至少一种,然后(II)用选自以下的修饰化合物改性所得的反应性聚合物: 以下组分(e),(f)和(g):(e)由通式Rn4MX4-n(其中R4是1-20个碳原子的烷基或芳基)表示的有机金卤化物 是锡或锗原子,X是卤素原子,n是i 1至3的整数),(f)在分子中具有由通式表示的键的杂多烯烃化合物或三元杂环化合物,其中X1是碳,氮,氧或硫原子 Y为碳原子或硫原子,Z为氮,氧或硫原子,X2为氮,氧或硫原子),(g)分子中具有由通式 (其中Y1是氮原子或氧原子,X是卤素原子)。 所述改性共轭二烯聚合物在耐磨性,发热性,机械性能等方面具有优异的特性。