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    • 5. 发明授权
    • Preparation process of polyhydroxycarboxylic acid
    • 聚羟基羧酸的制备方法
    • US5770683A
    • 1998-06-23
    • US546311
    • 1995-10-20
    • Yasunori YoshidaMichihiko MiyamotoShoji ObuchiKan IdedaMasahiro Ohta
    • Yasunori YoshidaMichihiko MiyamotoShoji ObuchiKan IdedaMasahiro Ohta
    • C08G63/06C08G63/91
    • C08G63/912C08G63/06
    • A preparation process of polyhydroxycarboxylic acid comprising conducting dehydration polycondensation of hydroxycarboxylic acid or an oligomer of the same in a reaction mixture containing said hydroxycarboxylic acid or the oligomer of the same and an organic solvent substantially in the absence of water to give polyhydroxycarboxylic acid having an weight average molecular weight of 50,000 or more, successively mixing the reaction mixture containing said polyhydroxycarboxylic acid with at least one binder selected from the group consisting of (1) polyisocyanate compound, (2) polybasic acid anhydride, (3) cyclic imino ester, (4) cyclic imino ether, (5) aromatic hydroxycarboxylic acid, (6) polyamino compound, (7) polyhydric alcohol, (8) epoxy compound, (9) polyfunctional aziridine compound, (10) lactam, (11) lactone, and (12) diethylene glycol bischloroforate, and reacting to obtain polyhydroxycarboxylic acid having a weight average molecular weight of 100,000 or more the polyhydroxycarboxylic acid which is obtained by the process has a weight average molecular weight of 100,000 or more, has satisfactory mechanical strength in the form of molded articles and is useful as a degradable polymer for substituting medical materials and general purpose resins.
    • 一种聚羟基羧酸的制备方法,其包括在含有羟基羧酸或其低聚物的反应混合物中进行羟基羧酸或其低聚物的脱水缩聚,基本上不存在水,得到具有重量的多羟基羧酸 将(1)多异氰酸酯化合物,(2)多元酸酐,(3)环状亚氨基酯,(4)的多元酸酐,(4) )环状亚氨基醚,(5)芳族羟基羧酸,(6)聚氨基化合物,(7)多元醇,(8)环氧化合物,(9)多官能氮丙啶化合物,(10)内酰胺,(11)内酯和(12 )二甘醇双氯氟酸盐,并且反应得到重均分子量为100,000以上的聚羟基
      羧酸 通过该方法获得的氧酸的重均分子量为100,000以上,成型品的机械强度良好,作为用于代替医用材料和通用树脂的可降解聚合物是有用的。
    • 10. 发明授权
    • Polymide for high-temperature adhesive
    • Polymide用于高温胶粘剂
    • US4959440A
    • 1990-09-25
    • US6513
    • 1987-01-23
    • Shoji TamaiSaburo KawashimaYoshiho SonobeMasahiro OhtaHideaki OikawaAkihiro Yamaguchi
    • Shoji TamaiSaburo KawashimaYoshiho SonobeMasahiro OhtaHideaki OikawaAkihiro Yamaguchi
    • C08G73/00C08G73/10C09J179/08
    • C08G73/1071C08G73/105
    • This invention relates to a novel polyimide and describes method of its preparation, adhesives of the polyimide and the method for their application.The polyimide has recurring units of the formula ##STR1## (where the positions of two carbonyl radicals in a benzene ring are meta or para, and R is a tetra-valent radical selected from the group consisting of aliphatic radical having not less than two carbons, cyclo-aliphatic radical, monoaromatic radical, condensed polyaromatic radical, and non condensed polyaromatic radical wherein aromatic radicals are mutually connected with a bond or a crosslinking function).The polyimide can be prepared by reacting diamine with tetracarboxylic dianhydride in organic solvents and imidizing resultant polyamic acid.The diamine in use is ether diamine and includes 1,3-bis[4-(3-aminophenoxy)benzoyl]benzene and 1,4-bis[4-(3-aminophenoxy)benzoyl]benzene.Various tetracarboxylic dianhydrides can be used and particularly prefered are pyromellitic dianhydride and 3,3',4,4'-benzophenonetetracarboxylic dianhydride.
    • 本发明涉及一种新型聚酰亚胺及其制备方法,聚酰亚胺的粘合剂及其应用方法。 聚酰亚胺具有下式的重复单元:其中苯环中的两个羰基的位置是间位或对位的,R是选自以下的四价基团:具有式 不少于两个碳,环脂族基团,单芳族基团,缩合多芳族基团和非缩合多芳族基团,其中芳族基团与键或交联官能团相互连接)。 聚酰亚胺可以通过二胺与四羧酸二酐在有机溶剂中反应并酰亚胺化得到的聚酰胺酸来制备。 所用的二胺是醚二胺,包括1,3-双[4-(3-氨基苯氧基)苯甲酰]苯和1,4-双[4-(3-氨基苯氧基)苯甲酰基]苯。 可以使用各种四羧酸二酐,特别优选的是均苯四酸二酐和3,3',4,4'-二苯甲酮四羧酸二酐。